Hydrolysis of mechanically pre-treated cellulose catalyzed by solid acid SO42--TiO2 in water-ethanol solvent

doi:10.1016/j.cjche.2019.02.027

摘要/Abstract

摘要： An efficient catalyst SO₄^2--TiO₂ (ST) from industrial metatitanic acid has been successfully prepared to catalyze hydrolysis of ball-milling cellulose. The results show that the highest catalytic efficiency is obtained for ST calcined at 450℃ (ST-450) with the yield of 21.8% glucose, 13.0% 5-HMF and 4.2% furfural at 200℃ for 30 min. The ball milling of cellulose and solid acid catalyst significantly enhances the cellulose hydrolysis. The high Lewis to Brönsted acid sites ratio for ST-450 induced by bidentate ligands between SO₄^2-and TiO₂ benefits high organics yield, and high total acid sites contribute to the high cellulose conversion. The large pore volume of 0.29 cm₃·g^-1 and appropriate pore size of 7.35 nm of ST-450 also contribute to the high performance. High reaction temperature over 200℃ exhibits negative effect on glucose and 5-HMF yield due to undesired side reactions, while furfural product is stable in the reaction system. The bidentate ligands between SO₄^2-and TiO₂ are considered as active acid sites for cellulose hydrolysis in water-ethanol solvents.

关键词: Cellulose, Industrial metatitanic acid, Solid acid, TiO₂, Hydrolysis, Ball milling

Abstract: An efficient catalyst SO₄^2--TiO₂ (ST) from industrial metatitanic acid has been successfully prepared to catalyze hydrolysis of ball-milling cellulose. The results show that the highest catalytic efficiency is obtained for ST calcined at 450℃ (ST-450) with the yield of 21.8% glucose, 13.0% 5-HMF and 4.2% furfural at 200℃ for 30 min. The ball milling of cellulose and solid acid catalyst significantly enhances the cellulose hydrolysis. The high Lewis to Brönsted acid sites ratio for ST-450 induced by bidentate ligands between SO₄^2-and TiO₂ benefits high organics yield, and high total acid sites contribute to the high cellulose conversion. The large pore volume of 0.29 cm₃·g^-1 and appropriate pore size of 7.35 nm of ST-450 also contribute to the high performance. High reaction temperature over 200℃ exhibits negative effect on glucose and 5-HMF yield due to undesired side reactions, while furfural product is stable in the reaction system. The bidentate ligands between SO₄^2-and TiO₂ are considered as active acid sites for cellulose hydrolysis in water-ethanol solvents.

Key words: Cellulose, Industrial metatitanic acid, Solid acid, TiO₂, Hydrolysis, Ball milling

Xingyilong Zhang, Houfang Lu, Kejing Wu, Yingying Liu, Changjun Liu, Yingming Zhu, Bin Liang. Hydrolysis of mechanically pre-treated cellulose catalyzed by solid acid SO₄^2--TiO₂ in water-ethanol solvent[J]. 中国化学工程学报, 2020, 28(1): 136-142.

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Hydrolysis of mechanically pre-treated cellulose catalyzed by solid acid SO₄^2--TiO₂ in water-ethanol solvent

Hydrolysis of mechanically pre-treated cellulose catalyzed by solid acid SO₄^2--TiO₂ in water-ethanol solvent

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