Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O2 under catalyst-free and ultra-low temperature

doi:10.1016/j.cjche.2019.04.012

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (1): 266-270.DOI: 10.1016/j.cjche.2019.04.012

• Energy, Resources and Environmental Technology • 上一篇下一篇

Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O₂ under catalyst-free and ultra-low temperature

Libo Zhang¹, Bowen Xing¹, Bailian Deng¹, Tianfu Wang², Hui Ming¹

1 State Key Laboratory of Heavy Oil Processing, College of Engineering, China University of Petroleum-Beijing at Karamay, Karamay 834000, China;
2 The Key Laboratory of Plant Resources and Chemistry of Arid Zone, The Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, Urumqi 830011, China

收稿日期:2019-03-13 修回日期:2019-04-08 出版日期:2020-01-28 发布日期:2020-03-31
通讯作者: Libo Zhang, Hui Ming
基金资助:
Supported by the Research Foundation of China University of Petroleum, -Beijing at Karamay (YJ2018B02006), the Chinese Government "Thousand Talent" Program (Y42H291501).

Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O₂ under catalyst-free and ultra-low temperature

Libo Zhang¹, Bowen Xing¹, Bailian Deng¹, Tianfu Wang², Hui Ming¹

1 State Key Laboratory of Heavy Oil Processing, College of Engineering, China University of Petroleum-Beijing at Karamay, Karamay 834000, China;
2 The Key Laboratory of Plant Resources and Chemistry of Arid Zone, The Xinjiang Technical Institute of Physics & Chemistry, Chinese Academy of Sciences, Urumqi 830011, China

Received:2019-03-13 Revised:2019-04-08 Online:2020-01-28 Published:2020-03-31
Contact: Libo Zhang, Hui Ming
Supported by:
Supported by the Research Foundation of China University of Petroleum, -Beijing at Karamay (YJ2018B02006), the Chinese Government "Thousand Talent" Program (Y42H291501).

摘要/Abstract

摘要： Oxidation of petroleum-based byproduct dicyclopentadiene derived diformyltricyclodecanes (DFTD) to dicarboxyltriclodecanesacids (DCTDA) was conducted under catalyst-free and ultra-low temperature conditions with O₂ as oxidant. In the perspective of industry process, oxygen pressure and contents, solvent and raw material initial concentrations were screened to evaluate their influence on DCTDA generation. Results indicate that DFTD oxidation can occur rather easily under no-catalyst and ultra-low temperature conditions with O₂ as oxidant. Oxygen content and pressure had positive effect on DCTDA production, γ-valerolactone (GVL) behaved best on DFTD generation in dynamics, while methanol could be used as a protective solvent to preserve DFTD. Besides, the existence of water in solvent was not beneficial to DCTDA production because of poor DFTD compatibility with water. The mechanisms of O₂ and solvent influence on DCTDA generation were discussed. Meanwhile, the oxidation route of DFTD-Intermediate-DCTDA was proposed. The present work exhibits the valued potential of DFTD, which will have a positive effect on high added value of petroleum based by-products.

关键词: Diformyltricyclodecanes, Oxidation, Catalyst-free, Solvent, Oxidative route

Abstract: Oxidation of petroleum-based byproduct dicyclopentadiene derived diformyltricyclodecanes (DFTD) to dicarboxyltriclodecanesacids (DCTDA) was conducted under catalyst-free and ultra-low temperature conditions with O₂ as oxidant. In the perspective of industry process, oxygen pressure and contents, solvent and raw material initial concentrations were screened to evaluate their influence on DCTDA generation. Results indicate that DFTD oxidation can occur rather easily under no-catalyst and ultra-low temperature conditions with O₂ as oxidant. Oxygen content and pressure had positive effect on DCTDA production, γ-valerolactone (GVL) behaved best on DFTD generation in dynamics, while methanol could be used as a protective solvent to preserve DFTD. Besides, the existence of water in solvent was not beneficial to DCTDA production because of poor DFTD compatibility with water. The mechanisms of O₂ and solvent influence on DCTDA generation were discussed. Meanwhile, the oxidation route of DFTD-Intermediate-DCTDA was proposed. The present work exhibits the valued potential of DFTD, which will have a positive effect on high added value of petroleum based by-products.

Key words: Diformyltricyclodecanes, Oxidation, Catalyst-free, Solvent, Oxidative route

Libo Zhang, Bowen Xing, Bailian Deng, Tianfu Wang, Hui Ming. Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O₂ under catalyst-free and ultra-low temperature[J]. 中国化学工程学报, 2020, 28(1): 266-270.

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Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O₂ under catalyst-free and ultra-low temperature

Oxidation of petroleum-based byproducts diformyltricyclodecanes (DFTD) with O₂ under catalyst-free and ultra-low temperature

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