Busting the efficiency of SAPO-34 catalysts for the methanol-to-olefin conversion by post-synthesis methods

doi:10.1016/j.cjche.2020.05.028

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (8): 2022-2027.DOI: 10.1016/j.cjche.2020.05.028

Busting the efficiency of SAPO-34 catalysts for the methanol-to-olefin conversion by post-synthesis methods

Guoju Yang^1,2, Ji Han¹, Yujun Huang¹, Xiaoxin Chen¹, Valentin Valtchev³

1 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China;
2 International Center of Future Science, Jilin University, 2699 Qianjin Street, Changchun 130012, China;
3 Normandie Univ, ENSICAEN, UNICAEN, CNRS, Laboratoire Catalyse et Spectrochimie, 6 Marechal Juin, 14050 Caen, France

收稿日期:2020-04-22 修回日期:2020-05-22 出版日期:2020-08-28 发布日期:2020-09-19
通讯作者: Xiaoxin Chen, Valentin Valtchev
基金资助:
This work is supported by the National Natural Science Foundation of China (21971082) and the Jilin Province Science and Technology Development Plan (20190201229JC and 20200201096JC). G.Y thanks the China Postdoctoral Science Foundation (2018M640280 and 2019T120235) for supporting this work. And this work acknowledges the National 111 Project (B17020).

Busting the efficiency of SAPO-34 catalysts for the methanol-to-olefin conversion by post-synthesis methods

Guoju Yang^1,2, Ji Han¹, Yujun Huang¹, Xiaoxin Chen¹, Valentin Valtchev³

1 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, 2699 Qianjin Street, Changchun 130012, China;
2 International Center of Future Science, Jilin University, 2699 Qianjin Street, Changchun 130012, China;
3 Normandie Univ, ENSICAEN, UNICAEN, CNRS, Laboratoire Catalyse et Spectrochimie, 6 Marechal Juin, 14050 Caen, France

Received:2020-04-22 Revised:2020-05-22 Online:2020-08-28 Published:2020-09-19
Contact: Xiaoxin Chen, Valentin Valtchev
Supported by:
This work is supported by the National Natural Science Foundation of China (21971082) and the Jilin Province Science and Technology Development Plan (20190201229JC and 20200201096JC). G.Y thanks the China Postdoctoral Science Foundation (2018M640280 and 2019T120235) for supporting this work. And this work acknowledges the National 111 Project (B17020).

摘要/Abstract

摘要： As an effective non-petroleum based process for producing light olefins, the methanol-to-olefin (MTO) route has become an indispensable alternative to the industrial production of light olefins. The silicoaluminophosphate SAPO-34 zeolite (CHA-type structure) has proven to be an efficient industrial catalyst for the production of ethylene and propylene by the MTO reaction. However, the inherent structure and related diffusion limitations of SAPO-34 limit the mass transport and thus cause rapid deactivation of the catalyst. Fabrication of hierarchical SAPO-34 zeolite is one of the most effective strategies to address the intrinsic diffusion limitation. As simple, inexpensive, and efficient approach, the post-synthetic route has attracted considerable attention and widely used to introduce secondary meso-/macropores into the microporous SAPO-34 material. Significant effort has been dedicated to the development of post-synthesis strategies to prepare hierarchical SAPO-34 zeolite, thereby enhancing its catalytic performance in the MTO process. This mini-review addresses the post-synthesis preparation of hierarchical SAPO-34 catalysts and their MTO performance. Furthermore, some current problems and prospects of the post-synthesis route to hierarchical SAPO-34 catalysts are also revised. We expect this minireview to inspire the more efficient preparation of hierarchical SAPO-34 catalysts for the MTO process.

关键词: Zeolites, SAPO-34, Post-synthesis treatment, Hierarchical, MTO

Abstract: As an effective non-petroleum based process for producing light olefins, the methanol-to-olefin (MTO) route has become an indispensable alternative to the industrial production of light olefins. The silicoaluminophosphate SAPO-34 zeolite (CHA-type structure) has proven to be an efficient industrial catalyst for the production of ethylene and propylene by the MTO reaction. However, the inherent structure and related diffusion limitations of SAPO-34 limit the mass transport and thus cause rapid deactivation of the catalyst. Fabrication of hierarchical SAPO-34 zeolite is one of the most effective strategies to address the intrinsic diffusion limitation. As simple, inexpensive, and efficient approach, the post-synthetic route has attracted considerable attention and widely used to introduce secondary meso-/macropores into the microporous SAPO-34 material. Significant effort has been dedicated to the development of post-synthesis strategies to prepare hierarchical SAPO-34 zeolite, thereby enhancing its catalytic performance in the MTO process. This mini-review addresses the post-synthesis preparation of hierarchical SAPO-34 catalysts and their MTO performance. Furthermore, some current problems and prospects of the post-synthesis route to hierarchical SAPO-34 catalysts are also revised. We expect this minireview to inspire the more efficient preparation of hierarchical SAPO-34 catalysts for the MTO process.

Key words: Zeolites, SAPO-34, Post-synthesis treatment, Hierarchical, MTO

Guoju Yang, Ji Han, Yujun Huang, Xiaoxin Chen, Valentin Valtchev. Busting the efficiency of SAPO-34 catalysts for the methanol-to-olefin conversion by post-synthesis methods[J]. 中国化学工程学报, 2020, 28(8): 2022-2027.

参考文献

[1] M. Stocker, Methanol-to-hydrocarbons:Catalytic materials and their behavior, Microporous Mesoporous Mater. 29(1-2) (1999) 3-48.
[2] M. Yang, D. Fan, Y. Wei, P. Tian, Z. Liu, Recent progress in methanol-to-olefins (MTO) catalysts, Adv. Mater. 31(50) (2019) 1902181.
[3] C.D. Chang, A.J. Silvestri, The conversion of methanol and other O-compounds to hydrocarbons over zeolite catalysts, J. Catal. 47(2) (1977) 249-259.
[4] P. Tian, Y.X. Wei, M. Ye, Z.M. Liu, Methanol to olefins (MTO):From fundamentals to commercialization, ACS Catal. 5(3) (2015) 1922-1938.
[5] J. Yu, R. Xu, Rational approaches toward the design and synthesis of zeolitic inorganic open-framework materials, Acc. Chem. Res. 43(9) (2010) 1195-1204.
[6] Z. Wang, J. Yu, R. Xu, Needs and trends in rational synthesis of zeolitic materials, Chem. Soc. Rev. 41(5) (2012) 1729-1741.
[7] Y. Li, J. Yu, New stories of zeolite structures:Their descriptions, determinations, predictions, and evaluations, Chem. Rev. 114(14) (2014) 7268-7316.
[8] B.M. Weckhuysen, J. Yu, Recent advances in zeolite chemistry and catalysis, Chem. Soc. Rev. 44(20) (2015) 7022-7024.
[9] Y. Li, L. Li, J.H. Yu, Applications of zeolites in sustainable chemistry, Chem 3(6) (2017) 928-949.
[10] Q. Sun, Z. Xie, J. Yu, The state-of-the-art synthetic strategies for SAPO-34 zeolite catalysts in methanol-to-olefin conversion, Natl. Sci. Rev. 5(4) (2018) 542-558.
[11] G. Yang, S.A. Akhade, X. Chen, Y. Liu, M.-S. Lee, V.-A. Glezakou, R. Rousseau, J.A. Lercher, The nature of hydrogen adsorption on platinum in the aqueous phase, Angew. Chem., Int. Ed. 58(11) (2019) 3527-3532.
[12] G. Yang, J. Han, Z. Qiu, X. Chen, Z. Feng, J. Yu, An amino acid-assisted approach to fabricate nanosized hierarchical TS-1 zeolites for efficient oxidative desulfurization, Inorg. Chem. Front. 7(10) (2020) 1975-1980.
[13] B.M. Lok, C.A. Messina, R.L. Patton, R.T. Gajek, T.R. Cannan, E.M. Flanigen, Silicoaluminophosphate molecular sieves:another new class of microporous crystalline inorganic solids, J. Am. Chem. Soc. 106(20) (1984) 6092-6093.
[14] D. Chen, K. Moljord, A. Holmen, A methanol to olefins review:Diffusion, coke formation and deactivation SAPO type catalysts, Microporous Mesoporous Mater. 164(2012) 239-250.
[15] S. Gao, S. Xu, Y. Wei, Q. Qiao, Z. Xu, X. Wu, M. Zhang, Y. He, S. Xu, Z. Liu, Insight into the deactivation mode of methanol-to-olefins conversion over SAPO-34:Coke, diffusion, and acidic site accessibility, J. Catal. 367(2018) 306-314.
[16] R. Bai, Y. Song, Y. Li, J. Yu, Creating hierarchical pores in zeolite catalysts, Trends Chem. 1(6) (2019) 601-611.
[17] J. Pérez-Ramírez, C.H. Christensen, K. Egeblad, C.H. Christensen, J.C. Groen, Hierarchical zeolites:Enhanced utilisation of microporous crystals in catalysis by advances in materials design, Chem. Soc. Rev. 37(11) (2008) 2530-2542.
[18] V. Valtchev, G. Majano, S. Mintova, J. Pérez-Ramírez, Tailored crystalline microporous materials by post-synthesis modification, Chem. Soc. Rev. 42(1) (2013) 263-290.
[19] F. Schmidt, S. Paasch, E. Brunner, S. Kaskel, Carbon templated SAPO-34 with improved adsorption kinetics and catalytic performance in the MTO-reaction, Microporous Mesoporous Mater. 164(2012) 214-221.
[20] A.Z. Varzaneh, J. Towfighi, S. Sahebdelfar, Carbon nanotube templated synthesis of metal containing hierarchical SAPO-34 catalysts:Impact of the preparation method and metal avidities in the MTO reaction, Microporous Mesoporous Mater. 236(2016) 1-12.
[21] Y. Liu, L. Wang, J. Zhang, F. Chen, M. Anpo, Preparation of macroporous SAPO-34 microspheres by a spray drying method using polystyrene spheres as hard template, Res. Chem. Intermed. 37(8) (2011) 949-959.
[22] Q. Sun, N. Wang, D. Xi, M. Yang, J. Yu, Organosilane surfactant-directed synthesis of hierarchical porous SAPO-34 catalysts with excellent MTO performance, Chem. Commun. 50(49) (2014) 6502-6505.
[23] F. Wang, L. Sun, C. Chen, Z. Chen, Z. Zhang, G. Wei, X. Jiang, Polyethyleneimine templated synthesis of hierarchical SAPO-34 zeolites with uniform mesopores, RSC Adv. 4(86) (2014) 46093-46096.
[24] K. Egeblad, C.H. Christensen, M. Kustova, C.H. Christensen, Templating mesoporous zeolites, Chem. Mater. 20(3) (2008) 946-960.
[25] Y. Jiao, L. Forster, S. Xu, H. Chen, J. Han, X. Liu, Y. Zhou, J. Liu, J. Zhang, J. Yu, Creation of Al-enriched mesoporous ZSM-5 nanoboxes with high catalytic activity:Converting tetrahedral extra-framework Al into framework sites by post treatment, Angew. Chem., Int. Ed. (2020)https://doi.org/10.1002/ange.202002416.
[26] Y. Jiao, A.-L. Adedigba, Q. He, P. Miedziak, G. Brett, N.F. Dummer, M. Perdjon, J. Liu, G.J. Hutchings, Inter-connected and open pore hierarchical TS-1 with controlled framework titanium for catalytic cyclohexene epoxidation, Catal. Sci. Technol. 8(8) (2018) 2211-2217.
[27] R. Zhang, P. Zhong, H. Arandiyan, Y. Guan, J. Liu, N. Wang, Y. Jiao, X. Fan, Using ultrasound to improve the sequential post-synthesis modification method for making mesoporous Y zeolites, Front. Chem. Sci. Eng. 14(2) (2020) 275-287.
[28] S. van Donk, A.H. Janssen, J.H. Bitter, K.P. de Jong, Generation, characterization, and impact of mesopores in zeolite catalysts, Catal. Rev. 45(2) (2003) 297-319.
[29] V. Valtchev, S. Mintova, Hierarchical zeolites, MRS Bull. 41(9) (2016) 689-693.
[30] Z. Qin, J.-P. Gilson, V. Valtchev, Mesoporous zeolites by fluoride etching, Curr. Opin. Chem. Eng. 8(2015) 1-6.
[31] F. Thibault-Starzyk, I. Stan, S. Abelló, A. Bonilla, K. Thomas, C. Fernandez, J.-P. Gilson, J. Pérez-Ramírez, Quantification of enhanced acid site accessibility in hierarchical zeolites-The accessibility index, J. Catal. 264(1) (2009) 11-14.
[32] D. Verboekend, J. Pérez-Ramírez, Design of hierarchical zeolite catalysts by desilication, Catal. Sci. Technol. 1(6) (2011) 879-890.
[33] S. Ren, G. Liu, X. Wu, X. Chen, M. Wu, G. Zeng, Z. Liu, Y. Sun, Enhanced MTO performance over acid treated hierarchical SAPO-34, Chin. J. Catal. 38(1) (2017) 123-130.
[34] Y. Qiao, M. Yang, B. Gao, L. Wang, P. Tian, S. Xu, Z. Liu, Creation of hollow SAPO-34 single crystals via alkaline or acid etching, Chem. Commun. 52(33) (2016) 5718-5721.
[35] Z. Liu, S. Ren, X. Yu, X. Chen, G. Wang, X. Wu, G. Yu, M. Qiu, C. Yang, Y. Sun, Meltingassisted solvent-free synthesis of hierarchical SAPO-34 with enhanced methanol to olefins (MTO) performance, Catal. Sci. Technol. 8(2) (2018) 423-427.
[36] W. Jin, B. Wang, P. Tuo, C. Li, L. Li, H. Zhao, X. Gao, B. Shen, Selective desilication, mesopores formation, and MTO reaction enhancement via citric acid treatment of zeolite SAPO-34, Ind. Eng. Chem. Res. 57(12) (2018) 4231-4236.
[37] S. Abello, A. Bonilla, J. Perez-Ramirez, Mesoporous ZSM-5 zeolite catalysts prepared by desilication with organic hydroxides and comparison with NaOH leaching, Appl. Catal., A 364(1-2) (2009) 191-198.
[38] D. Verboekend, M. Milina, J. Pérez-Ramírez, Hierarchical silicoaluminophosphates by postsynthetic modification:Influence of topology, composition, and silicon distribution, Chem. Mater. 26(15) (2014) 4552-4562.
[39] X. Liu, S. Ren, G. Zeng, G. Liu, P. Wu, G. Wang, X. Chen, Z. Liu, Y. Sun, Coke suppression in MTO over hierarchical SAPO-34 zeolites, RSC Adv. 6(34) (2016) 28787-28791.
[40] Y. Pan, G. Chen, G. Yang, X. Chen, J. Yu, Efficient post-synthesis of hierarchical SAPO-34 zeolites via organic amine etching under hydrothermal conditions and their enhanced MTO performance, Inorg. Chem. Front. 6(5) (2019) 1299-1303.
[41] V. Valtchev, E. Balanzat, V. Mavrodinova, I. Diaz, J. El Fallah, J.-M. Goupil, High energy ion irradiation-induced ordered macropores in zeolite crystals, J. Am. Chem. Soc. 133(46) (2011) 18950-18956.
[42] Z. Qin, L. Lakiss, J.-P. Gilson, K. Thomas, J. Goupil, C. Fernandez, V. Valtchev, Chemical equilibrium controlled etching of MFI-type zeolite and its influence on zeolite structure, acidity, and catalytic activity, Chem. Mater. 25(14) (2013) 2759-2766.
[43] Z. Qin, G. Melinte, J.-P. Gilson, M. Jaber, K. Bozhilov, P. Boullay, S. Mintova, O. Ersen, V. Valtchev, The mosaic structure of zeolite crystals, Angew. Chem., Int. Ed. 128(48) (2016) 15273-15276.
[44] Z. Qin, K.A. Cychosz, G. Melinte, H. El Siblani, J.-P. Gilson, M. Thommes, C. Fernandez, S. Mintova, O. Ersen, V. Valtchev, Opening the cages of Faujasite-type zeolite, J. Am. Chem. Soc. 139(48) (2017) 17273-17276.
[45] J. Přech, K.N. Bozhilov, J. El Fallah, N. Barrier, V. Valtchev, Fluoride etching opens the structure and strengthens the active sites of the layered ZSM-5 zeolite, Microporous Mesoporous Mater. 280(2019) 297-305.
[46] Z. Qin, L. Hafiz, Y. Shen, S.V. Daele, P. Boullay, V. Ruaux, S. Mintova, J.-P. Gilson, V. Valtchev, Defect-engineered zeolite porosity and accessibility, J. Mater. Chem. A 8(7) (2020) 3621-3631.
[47] Z. Qin, L. Pinard, M.A. Benghalem, T.J. Daou, G. Melinte, O. Ersen, S. Asahina, J.-P. Gilson, V. Valtchev, Preparation of single-crystal "house-of-cards"-like ZSM-5 and their performance in ethanol-to-hydrocarbon conversion, Chem. Mater. 31(13) (2019) 4639-4648.
[48] V. Babić, L. Tang, Z. Qin, L. Hafiz, J.-P. Gilson, Comparative study of zeolite L etching with ammonium fluoride and ammonium bifluoride solutions, Adv. Mater. Interfaces (2020)https://doi.org/10.1002/admi.20200034.
[49] K.-G. Haw, S. Moldovan, L. Tang, Z. Qin, Q. Fang, S. Qiu, V. Valtchev, A sponge-like small pore zeolite with great accessibility to the micropores, Inorg. Chem. Front. (2020)https://doi.org/10.1039/D1030QI00261E.
[50] X. Chen, A. Vicente, Z. Qin, V. Ruaux, J.-P. Gilson, V. Valtchev, The preparation of hierarchical SAPO-34 crystals via post-synthesis fluoride etching, Chem. Commun. 52(17) (2016) 3512-3515.
[51] X. Chen, D. Xi, Q. Sun, N. Wang, Z. Dai, D. Fan, V. Valtchev, J. Yu, A top-down approach to hierarchical SAPO-34 zeolites with improved selectivity of olefin, Microporous Mesoporous Mater. 234(2016) 401-408.

Busting the efficiency of SAPO-34 catalysts for the methanol-to-olefin conversion by post-synthesis methods

Busting the efficiency of SAPO-34 catalysts for the methanol-to-olefin conversion by post-synthesis methods

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Baoyu Liu, Feng Xiong, Jianwen Zhang, Manna Wang, Yi Huang, Yanxiong Fang, Jinxiang Dong. Enhanced ortho-selective t–butylation of phenol over sulfonic acid functionalized mesopore MTW zeolites[J]. 中国化学工程学报, 2023, 60(8): 1-7.
[2]	Wenwen Zhang, Zhigang Xue, Liyun Cui, Haoliang Gao, Di Zhao, Rongfei Zhou, Weihong Xing. Synthesis of an IMF zeolite membrane for the separation of xylene isomer[J]. 中国化学工程学报, 2023, 60(8): 205-211.
[3]	Shuang Qiu, Yonghou Xiao, Haoran Wu, Shengnan Lu, Qidong Zhao, Gaohong He. One-pot synthesis of bimetallic CeCu-SAPO-34 for high-efficiency selective catalytic reduction of nitrogen oxides with NH₃ at low temperature[J]. 中国化学工程学报, 2023, 56(4): 193-202.
[4]	Lianlian Zhao, Fufu Di, Xiaonan Wang, Sumbal Farid, Suzhen Ren. Constructing a hollow core-shell structure of RuO₂ wrapped by hierarchical porous carbon shell with Ru NPs loading for supercapacitor[J]. 中国化学工程学报, 2023, 55(3): 93-100.
[5]	Lijian Shi, Yaping Zhang, Yujia Tong, Wenlong Ding, Weixing Li. Plant-inspired biomimetic hybrid PVDF membrane co-deposited by tea polyphenols and 3-amino-propyl-triethoxysilane for high-efficiency oil-in-water emulsion separation[J]. 中国化学工程学报, 2023, 53(1): 170-180.
[6]	Yaling Li, Hao Ai, Liangzhi Qiao, Yinghong Wang, Kaifeng Du. Fabrication and characterization of hierarchical porous Ni²⁺ doped hydroxyapatite microspheres and their enhanced protein adsorption capacity[J]. 中国化学工程学报, 2022, 45(5): 238-247.
[7]	Mingdong Sun, Zhengyun Bian, Weiwei Cui, Xiaolong Zhao, Shu Dong, Xuebin Ke, Yu Zhou, Jun Wang. Pyrolyzing soft template-containing poly(ionic liquid) into hierarchical N-doped porous carbon for electroreduction of carbon dioxide[J]. 中国化学工程学报, 2022, 43(3): 192-201.
[8]	Tianlei Wang, Zhikang Xu, Yuanyuan Yue, Tinghai Wang, Minggui Lin, Haibo Zhu. Bimetallic PtSn nanoparticles confined in hierarchical ZSM-5 for propane dehydrogenation[J]. 中国化学工程学报, 2022, 41(1): 384-391.
[9]	Huaiqing An, Hua Li, Jibin Zhou, Jinling Zhang, Tao Zhang, Mao Ye, Zhongmin Liu. Kinetics of steam regeneration of SAPO-34 zeolite catalyst in methanol-to-olefins (MTO) process[J]. 中国化学工程学报, 2021, 35(7): 231-238.
[10]	Guoju Yang, Ji Han, Yue Liu, Ziyi Qiu, Xiaoxin Chen. The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions[J]. 中国化学工程学报, 2020, 28(9): 2227-2234.
[11]	Yuhong Kang, Xianyong Wei, Guanghui Liu, Miao Mu, Xiangrong Ma, Yong Gao, Zhimin Zong. CO₂-hierarchical activated carbon prepared from coal gasification residue: Adsorption equilibrium, isotherm, kinetic and thermodynamic studies for methylene blue removal[J]. 中国化学工程学报, 2020, 28(6): 1694-1700.
[12]	Peipei Li, Dazhi Zhang, Yunhui Xu, Caihua Ni, Gang Shi, Xinxin Sang. Nitrogen-doped hierarchical porous carbon from polyaniline/silica self-aggregates for supercapacitor[J]. 中国化学工程学报, 2019, 27(3): 709-716.
[13]	Nasim Ghorbani, Gholamreza Moradi. Oxidative desulfurization of model and real oil samples using Mo supported on hierarchical alumina-silica: Process optimization by Box-Behnken experimental design[J]. 中国化学工程学报, 2019, 27(11): 2759-2770.
[14]	Rashid Ur Rehman, Qingnan Song, Li Peng, Yang Chen, Xuehong Gu. Hydrophobic modification of SAPO-34 membranes for improvement of stability under wet condition[J]. 中国化学工程学报, 2019, 27(10): 2397-2406.
[15]	Zhiguo Yan, Sai Tang, Xumiao Zhou, Li Yang, Xingqing Xiao, Houyang Chen, Yuanhang Qin, Wei Sun. All-silica zeolites screening for capture of toxic gases from molecular simulation[J]. Chinese Journal of Chemical Engineering, 2019, 27(1): 174-181.