The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions

doi:10.1016/j.cjche.2020.06.026

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (9): 2227-2234.DOI: 10.1016/j.cjche.2020.06.026

• Review • 下一篇

The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions

Guoju Yang^1,2, Ji Han¹, Yue Liu³, Ziyi Qiu¹, Xiaoxin Chen¹

1 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;
2 International Center of Future Science, Jilin University, Changchun 130012, China;
3 Department of Chemistry and Catalysis Research Center, Technische Universit?t München, Lichtenbergstrasse 4, 85747 Garching, Germany

收稿日期:2020-05-27 修回日期:2020-06-12 出版日期:2020-09-28 发布日期:2020-10-21
通讯作者: Xiaoxin Chen
基金资助:
This work is supported by the National Natural Science Foundation of China (21971082) and the Jilin Province Science and Technology Development Plan (20200201096JC and 20190201229JC). G.J. Yang thanks the China Postdoctoral Science Foundation (2019T120235 and 2018M640280) for supporting this work. This work acknowledges the 111 Project (B17020) and the collaboration in the framework of joint Sino-French international laboratory "Zeolites".

The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions

Guoju Yang^1,2, Ji Han¹, Yue Liu³, Ziyi Qiu¹, Xiaoxin Chen¹

1 State Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun 130012, China;
2 International Center of Future Science, Jilin University, Changchun 130012, China;
3 Department of Chemistry and Catalysis Research Center, Technische Universit?t München, Lichtenbergstrasse 4, 85747 Garching, Germany

Received:2020-05-27 Revised:2020-06-12 Online:2020-09-28 Published:2020-10-21
Contact: Xiaoxin Chen
Supported by:
This work is supported by the National Natural Science Foundation of China (21971082) and the Jilin Province Science and Technology Development Plan (20200201096JC and 20190201229JC). G.J. Yang thanks the China Postdoctoral Science Foundation (2019T120235 and 2018M640280) for supporting this work. This work acknowledges the 111 Project (B17020) and the collaboration in the framework of joint Sino-French international laboratory "Zeolites".

摘要/Abstract

摘要： With the increasingly stringent standards for limiting sulfide content in liquid fuels, oxidative desulfurization (ODS) has become a promising ultra-deep desulfurization process in fuel desulfurization. TS-1 zeolites show great potential as catalysts for ODS reactions, due to its remarkable oxidation activity at low temperatures and pressure. However, the inherent microporous structure of conventional TS-1 zeolites restricts the mass transportation and renders the active sites in the microporous space of TS-1 zeolites inaccessible for bulky aromatic organosulfur compounds. Fabrication of hierarchical TS-1 zeolites by incorporating meso-/macropores into microporous TS-1 zeolites is an effective strategy to improve mass transportability. In recent years, abundant efforts have been dedicated to developing synthetic strategies of hierarchical TS-1 zeolite, thereby improving its catalytic performance in the ODS process. This mini-review addresses the synthetic methods of hierarchical TS-1 catalysts and their catalytic performance in the ODS reactions. In addition, some current problems and prospects of synthesis routes for constructing hierarchical TS-1 catalysts have also been revised. We expect this mini-review to shed light on the more efficient preparation strategies of hierarchical TS-1 zeolites for the ODS process.

关键词: Zeolites, TS-1, Synthesis, Hierarchical, ODS

Abstract: With the increasingly stringent standards for limiting sulfide content in liquid fuels, oxidative desulfurization (ODS) has become a promising ultra-deep desulfurization process in fuel desulfurization. TS-1 zeolites show great potential as catalysts for ODS reactions, due to its remarkable oxidation activity at low temperatures and pressure. However, the inherent microporous structure of conventional TS-1 zeolites restricts the mass transportation and renders the active sites in the microporous space of TS-1 zeolites inaccessible for bulky aromatic organosulfur compounds. Fabrication of hierarchical TS-1 zeolites by incorporating meso-/macropores into microporous TS-1 zeolites is an effective strategy to improve mass transportability. In recent years, abundant efforts have been dedicated to developing synthetic strategies of hierarchical TS-1 zeolite, thereby improving its catalytic performance in the ODS process. This mini-review addresses the synthetic methods of hierarchical TS-1 catalysts and their catalytic performance in the ODS reactions. In addition, some current problems and prospects of synthesis routes for constructing hierarchical TS-1 catalysts have also been revised. We expect this mini-review to shed light on the more efficient preparation strategies of hierarchical TS-1 zeolites for the ODS process.

Key words: Zeolites, TS-1, Synthesis, Hierarchical, ODS

Guoju Yang, Ji Han, Yue Liu, Ziyi Qiu, Xiaoxin Chen. The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions[J]. 中国化学工程学报, 2020, 28(9): 2227-2234.

Guoju Yang, Ji Han, Yue Liu, Ziyi Qiu, Xiaoxin Chen. The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions[J]. Chinese Journal of Chemical Engineering, 2020, 28(9): 2227-2234.

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The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions

The synthetic strategies of hierarchical TS-1 zeolites for the oxidative desulfurization reactions

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