SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2022, Vol. 50 ›› Issue (10): 292-300.DOI: 10.1016/j.cjche.2022.05.022

• Catalysis, Kinetics and Reaction Engineering • 上一篇    下一篇

Microinterface intensification in hydrogenation and air oxidation processes

Hongliang Qian2, Hongzhou Tian1, Guoqiang Yang1, Gaodong Yang1, Lei Li1, Feng Zhang1, Zheng Zhou1, Weihua Huang3, Yufu Chen3, Zhibing Zhang1   

  1. 1 School of Chemistry & Chemical Engineering, Nanjing University, Nanjing 210046, China;
    2 Department of Pharmaceutical Engineering, China Pharmaceutical University, Nanjing 211198, China;
    3 Nanjing Institute of Microinterfacial Reaction Engineering, Nanjing 210008, China
  • 收稿日期:2022-03-18 修回日期:2022-05-13 出版日期:2022-10-28 发布日期:2023-01-04
  • 通讯作者: Feng Zhang,E-mail:zf@nju.edu.cn;Zhibing Zhang,E-mail:zbzhang@nju.edu.cn
  • 基金资助:
    The authors are grateful to the financial support of National Natural Science Foundation of China (No. 91634104, 21776122 and 22178391), National Key Research & Development Program of China (No. 2018YFB0604605), Jiangsu Science and Technology Plan Project (No. BM2018007).

Microinterface intensification in hydrogenation and air oxidation processes

Hongliang Qian2, Hongzhou Tian1, Guoqiang Yang1, Gaodong Yang1, Lei Li1, Feng Zhang1, Zheng Zhou1, Weihua Huang3, Yufu Chen3, Zhibing Zhang1   

  1. 1 School of Chemistry & Chemical Engineering, Nanjing University, Nanjing 210046, China;
    2 Department of Pharmaceutical Engineering, China Pharmaceutical University, Nanjing 211198, China;
    3 Nanjing Institute of Microinterfacial Reaction Engineering, Nanjing 210008, China
  • Received:2022-03-18 Revised:2022-05-13 Online:2022-10-28 Published:2023-01-04
  • Contact: Feng Zhang,E-mail:zf@nju.edu.cn;Zhibing Zhang,E-mail:zbzhang@nju.edu.cn
  • Supported by:
    The authors are grateful to the financial support of National Natural Science Foundation of China (No. 91634104, 21776122 and 22178391), National Key Research & Development Program of China (No. 2018YFB0604605), Jiangsu Science and Technology Plan Project (No. BM2018007).

摘要: Hydrogenations and air oxidations usually have low apparent reaction rate, generally controlled by mass transfer rate, and widely exist in the modern chemical manufacturing process. The key to increase the mass transfer rate is the reduction of the liquid film resistance 1/kLa. In this work, the original concept of microinterface intensification for mass transfer and then for these reactions has been proposed. We derived the regulation model and set up the mathematical calculation method of micron-scale gas-liquid interface structure on mass transfer and reaction, designed the mechanical energy exchange device that can produce gas-liquid microinterface system on a large scale, and established the OMIS system which is able on line to measure the diameter and distribution of millions of microbubbles, interface area a and mass transfer film thickness δM, as well as developed a series of microinterface intensified reactor systems (MIRs) for the applications of hydrogenation and air oxidation processes. It is believed that this research will provide an up-to-date development for the intensification of hydrogenation and air oxidation reactions.

关键词: Hydrogenation and oxidation, Microinterface intensification, Mass transfer coefficient, Structure-effect regulation, Online measurement

Abstract: Hydrogenations and air oxidations usually have low apparent reaction rate, generally controlled by mass transfer rate, and widely exist in the modern chemical manufacturing process. The key to increase the mass transfer rate is the reduction of the liquid film resistance 1/kLa. In this work, the original concept of microinterface intensification for mass transfer and then for these reactions has been proposed. We derived the regulation model and set up the mathematical calculation method of micron-scale gas-liquid interface structure on mass transfer and reaction, designed the mechanical energy exchange device that can produce gas-liquid microinterface system on a large scale, and established the OMIS system which is able on line to measure the diameter and distribution of millions of microbubbles, interface area a and mass transfer film thickness δM, as well as developed a series of microinterface intensified reactor systems (MIRs) for the applications of hydrogenation and air oxidation processes. It is believed that this research will provide an up-to-date development for the intensification of hydrogenation and air oxidation reactions.

Key words: Hydrogenation and oxidation, Microinterface intensification, Mass transfer coefficient, Structure-effect regulation, Online measurement