Synthesis of waterborne polyurethane-humic acid cross-linked biomass porous materials for the adsorption of methylene blue

doi:10.1016/j.cjche.2023.08.012

中国化学工程学报 ›› 2024, Vol. 67 ›› Issue (3): 27-38.DOI: 10.1016/j.cjche.2023.08.012

Synthesis of waterborne polyurethane-humic acid cross-linked biomass porous materials for the adsorption of methylene blue

Shanghong Ma^1,2, Jianbo Qu^1,2, Haitao Zhang^1,2, Xiubin Cui^1,2, Peng Ye^1,2, Qingfei Hu^1,2, Mingzhen Chao^1,2

1 State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China;
2 Faculty of Light Industry, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China

收稿日期:2023-03-30 修回日期:2023-07-15 出版日期:2024-03-28 发布日期:2024-06-01
通讯作者: Jianbo Qu,E-mail address:qujianbo396@sohu.com;Haitao Zhang,E-mail address:zhanghaitao@qlu.edu.cn.
基金资助:
The work was supported by the National Natural Science Foundation of China (21704047); the Natural Science Foundation of Shandong Province (ZR2017BB078, ZR2021QE137); the Foundation of State Key Laboratory of Biobased Material and Green Papermaking (ZZ20190407); and the Major scientific and technological innovation projects of Shandong Province (2019JZZY020230).

Synthesis of waterborne polyurethane-humic acid cross-linked biomass porous materials for the adsorption of methylene blue

Shanghong Ma^1,2, Jianbo Qu^1,2, Haitao Zhang^1,2, Xiubin Cui^1,2, Peng Ye^1,2, Qingfei Hu^1,2, Mingzhen Chao^1,2

1 State Key Laboratory of Biobased Material and Green Papermaking, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China;
2 Faculty of Light Industry, Qilu University of Technology, Shandong Academy of Sciences, Jinan 250353, China

Received:2023-03-30 Revised:2023-07-15 Online:2024-03-28 Published:2024-06-01
Contact: Jianbo Qu,E-mail address:qujianbo396@sohu.com;Haitao Zhang,E-mail address:zhanghaitao@qlu.edu.cn.
Supported by:
The work was supported by the National Natural Science Foundation of China (21704047); the Natural Science Foundation of Shandong Province (ZR2017BB078, ZR2021QE137); the Foundation of State Key Laboratory of Biobased Material and Green Papermaking (ZZ20190407); and the Major scientific and technological innovation projects of Shandong Province (2019JZZY020230).

摘要/Abstract

摘要： A series of adsorbent materials (WPU-HA_x-y) with a three-dimensional porous structure, green sustainability, and excellent performance were prepared and evaluated for the removal of methylene blue using nontoxic and environmentally friendly waterborne polyurethane as the matrix material and humic acid, a biomass material, as the functional material. The newly synthesized adsorbents were characterized by infrared spectroscopy, scanning electron microscopy, specific surface area, and thermogravimetric. The effects of contact time (0e8 h), starting concentration (10e100 mg·L^-1), pH (3e11), solution temperature (30-60 ℃), and coexisting ions (Ca²⁺, Na⁺, K⁺, Mg²⁺) on the performance were investigated. Pseudo-first-order, pseudo-second-order, elovich, and intra-particle diffusion models were used to analyze the adsorption kinetics; the Langmuir, Freundlich, Temkin, and DubineRadushkovich adsorption isotherms were evaluated; and the adsorption behavior of the adsorbent materials was found to be more appropriate for the pseudo-second-order model for chemical pollutant removal than the Langmuir model, which depends on monolayer adsorption. WPU-HA₂-3 stood out with a maximum adsorption capacity of 813.0081 mg·g^-1 fitted to the pseudo-second-order and 309.2832 mg·g^-1 fitted to the Langmuir model, showing superior adsorption performance and regenerability.

关键词: Porous media, Bioenergy, Sustainability, Waste water

Abstract: A series of adsorbent materials (WPU-HA_x-y) with a three-dimensional porous structure, green sustainability, and excellent performance were prepared and evaluated for the removal of methylene blue using nontoxic and environmentally friendly waterborne polyurethane as the matrix material and humic acid, a biomass material, as the functional material. The newly synthesized adsorbents were characterized by infrared spectroscopy, scanning electron microscopy, specific surface area, and thermogravimetric. The effects of contact time (0e8 h), starting concentration (10e100 mg·L^-1), pH (3e11), solution temperature (30-60 ℃), and coexisting ions (Ca²⁺, Na⁺, K⁺, Mg²⁺) on the performance were investigated. Pseudo-first-order, pseudo-second-order, elovich, and intra-particle diffusion models were used to analyze the adsorption kinetics; the Langmuir, Freundlich, Temkin, and DubineRadushkovich adsorption isotherms were evaluated; and the adsorption behavior of the adsorbent materials was found to be more appropriate for the pseudo-second-order model for chemical pollutant removal than the Langmuir model, which depends on monolayer adsorption. WPU-HA₂-3 stood out with a maximum adsorption capacity of 813.0081 mg·g^-1 fitted to the pseudo-second-order and 309.2832 mg·g^-1 fitted to the Langmuir model, showing superior adsorption performance and regenerability.

Key words: Porous media, Bioenergy, Sustainability, Waste water

Shanghong Ma, Jianbo Qu, Haitao Zhang, Xiubin Cui, Peng Ye, Qingfei Hu, Mingzhen Chao. Synthesis of waterborne polyurethane-humic acid cross-linked biomass porous materials for the adsorption of methylene blue[J]. 中国化学工程学报, 2024, 67(3): 27-38.

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Synthesis of waterborne polyurethane-humic acid cross-linked biomass porous materials for the adsorption of methylene blue

Synthesis of waterborne polyurethane-humic acid cross-linked biomass porous materials for the adsorption of methylene blue

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