Strong water-resistant Co-Mn solid solution derived from bimetallic metal–organic frameworks for catalytic destruction of toluene

doi:10.1016/j.cjche.2024.06.027

中国化学工程学报 ›› 2024, Vol. 75 ›› Issue (11): 142-151.DOI: 10.1016/j.cjche.2024.06.027

Strong water-resistant Co-Mn solid solution derived from bimetallic metal–organic frameworks for catalytic destruction of toluene

Juan Lei¹, Ying Huang^2,3, Baobao Bai^2,3, Xiaoli Ren¹, Lijun Cheng¹, Shuang Wang²

1. Department of Environmental and Safety Engineering, Taiyuan Institute of Technology, Taiyuan 030018, China;
2. College of Environment and Ecology, Taiyuan University of Technology, Jinzhong 030600, China;
3. Shanxi Key Laboratory of Compound Air Pollutions Identification and Control, Taiyuan University of Technology, Jinzhong 030600, China

收稿日期:2024-04-16 修回日期:2024-06-12 接受日期:2024-06-13 出版日期:2024-11-28 发布日期:2024-08-23
通讯作者: Shuang Wang,E-mail:wangshuang@tyut.edu.cn
基金资助:
The authors acknowledge the financial support of the National Natural Science Foundation of China (22408252, 22078215), Natural Science Foundation for Youths of Shanxi Province (202103021223347), Taiyuan Institute of Technology Talent Introduction Research funding Project (2022KJ010), and Shanxi Province Science and Technology Major Special Plan “Reveal The List and Take Charge” Project (202201090301014).

Strong water-resistant Co-Mn solid solution derived from bimetallic metal–organic frameworks for catalytic destruction of toluene

Juan Lei¹, Ying Huang^2,3, Baobao Bai^2,3, Xiaoli Ren¹, Lijun Cheng¹, Shuang Wang²

1. Department of Environmental and Safety Engineering, Taiyuan Institute of Technology, Taiyuan 030018, China;
2. College of Environment and Ecology, Taiyuan University of Technology, Jinzhong 030600, China;
3. Shanxi Key Laboratory of Compound Air Pollutions Identification and Control, Taiyuan University of Technology, Jinzhong 030600, China

Received:2024-04-16 Revised:2024-06-12 Accepted:2024-06-13 Online:2024-11-28 Published:2024-08-23
Contact: Shuang Wang,E-mail:wangshuang@tyut.edu.cn
Supported by:
The authors acknowledge the financial support of the National Natural Science Foundation of China (22408252, 22078215), Natural Science Foundation for Youths of Shanxi Province (202103021223347), Taiyuan Institute of Technology Talent Introduction Research funding Project (2022KJ010), and Shanxi Province Science and Technology Major Special Plan “Reveal The List and Take Charge” Project (202201090301014).

摘要/Abstract

摘要： The construction of Co-Mn mixed-metal oxide catalysts derived from bimetallic metal-organic frameworks (MOFs) has great significance for catalytic destruction of toluene. Hence, a series of Co_aMn_bO_x-MOFs with different physicochemical properties were successfully synthesized via pyrolysis of Co—Mn bimetallic MOFs. Attributing to the higher specific surface area, more active sites (Co³⁺ and Mn³⁺), stronger reducibility, and abundant defect sites, the as-prepared Co₁Mn₁O_x-MOFs displayed an optimal catalytic performance, especially the excellent water vapor resistance. The result of the in situ diffuse reflectance infrared Fourier transform spectroscopy demonstrated that toluene can be degraded at relatively low temperatures (＜100 ℃). Benzyl alcohol, benzaldehyde, benzoic acid, and maleic anhydride were the main intermediate products in toluene degradation process. This work reveals the value of bimetallic MOFs derived Co—Mn oxides for toluene oxidation and presents a novel avenue for designing mixed-metal oxide catalysts with potential applications in volatile organic compounds (VOCs) catalytic oxidation.

关键词: Co-Mn oxide catalyst, Bimetallic metal-organic frameworks (MOFs), Catalytic oxidation, Water-resistant

Abstract: The construction of Co-Mn mixed-metal oxide catalysts derived from bimetallic metal-organic frameworks (MOFs) has great significance for catalytic destruction of toluene. Hence, a series of Co_aMn_bO_x-MOFs with different physicochemical properties were successfully synthesized via pyrolysis of Co—Mn bimetallic MOFs. Attributing to the higher specific surface area, more active sites (Co³⁺ and Mn³⁺), stronger reducibility, and abundant defect sites, the as-prepared Co₁Mn₁O_x-MOFs displayed an optimal catalytic performance, especially the excellent water vapor resistance. The result of the in situ diffuse reflectance infrared Fourier transform spectroscopy demonstrated that toluene can be degraded at relatively low temperatures (＜100 ℃). Benzyl alcohol, benzaldehyde, benzoic acid, and maleic anhydride were the main intermediate products in toluene degradation process. This work reveals the value of bimetallic MOFs derived Co—Mn oxides for toluene oxidation and presents a novel avenue for designing mixed-metal oxide catalysts with potential applications in volatile organic compounds (VOCs) catalytic oxidation.

Key words: Co-Mn oxide catalyst, Bimetallic metal-organic frameworks (MOFs), Catalytic oxidation, Water-resistant

Juan Lei, Ying Huang, Baobao Bai, Xiaoli Ren, Lijun Cheng, Shuang Wang. Strong water-resistant Co-Mn solid solution derived from bimetallic metal–organic frameworks for catalytic destruction of toluene[J]. 中国化学工程学报, 2024, 75(11): 142-151.

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Strong water-resistant Co-Mn solid solution derived from bimetallic metal–organic frameworks for catalytic destruction of toluene

Strong water-resistant Co-Mn solid solution derived from bimetallic metal–organic frameworks for catalytic destruction of toluene

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