Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K

›› 2011, Vol. 19 ›› Issue (2): 217-222.

Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K

龚行楚, 王珊珊, 瞿海斌

Department of Chinese Medicine Science and Engineering, College of Pharmaceutical Sciences, Zhejiang University, Hangzhou 310058, China

收稿日期:2010-07-14 修回日期:2010-11-16 出版日期:2011-04-28 发布日期:2011-04-28
通讯作者: QU Haibin,E-mail:quhb@zju.edu.cn
基金资助:
Supported by the National Science and Technology Major Project (2009ZX09313-036);the China Postdoctoral Science Foundation (20090461360);the Zhejiang Provincial Education Department Projects (Y200907556)

Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K

GONG Xingchu, WANG Shanshan, QU Haibin

Department of Chinese Medicine Science and Engineering, College of Pharmaceutical Sciences, Zhejiang University, Hangzhou 310058, China

Received:2010-07-14 Revised:2010-11-16 Online:2011-04-28 Published:2011-04-28
Supported by:
Supported by the National Science and Technology Major Project (2009ZX09313-036);the China Postdoctoral Science Foundation (20090461360);the Zhejiang Provincial Education Department Projects (Y200907556)

摘要/Abstract

摘要： Experimental data on the solubility of D-glucose,D-fructose and sucrose in the mixed solvents composed of water and ethanol from 273.2 to 293.2 K were determined.The solubility of D-glucose,D-fructose and sucrose decreased as the ethanol content increased in the mixed solvent.The solubility of D-glucose,D-fructose and sucrose decreased with decreasing equilibrium temperature.The modified UNIQUAC model,SUNIFAC model and mS-UNIFAC model were applied to predict the solid-liquid equilibria.The prediction results were compared and discussed.Better prediction accuracy was generated using the modified UNIQUAC model.

关键词: glucose, fructose, sucrose, ethanol, solid-liquid equilibria

Abstract: Experimental data on the solubility of D-glucose,D-fructose and sucrose in the mixed solvents composed of water and ethanol from 273.2 to 293.2 K were determined.The solubility of D-glucose,D-fructose and sucrose decreased as the ethanol content increased in the mixed solvent.The solubility of D-glucose,D-fructose and sucrose decreased with decreasing equilibrium temperature.The modified UNIQUAC model,SUNIFAC model and mS-UNIFAC model were applied to predict the solid-liquid equilibria.The prediction results were compared and discussed.Better prediction accuracy was generated using the modified UNIQUAC model.

Key words: glucose, fructose, sucrose, ethanol, solid-liquid equilibria

龚行楚, 王珊珊, 瞿海斌. Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K[J]. , 2011, 19(2): 217-222.

GONG Xingchu, WANG Shanshan, QU Haibin. Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K[J]. , 2011, 19(2): 217-222.

参考文献

1 Bouchard, A., Hofland, G.W., Witkamp, G., “Properties of sugar, polyol, and polysaccharide water-ethanol solutions”, J. Chem. Eng. Data, 52, 1838-1842 (2007).
2 Flood, A.E., Puagsa, S., “Refractive index, viscosity and solubility at 30℃, and density at 25℃ for the system fructose+glucose+ethanol+water”, J. Chem. Eng. Data, 45, 902-907 (2000).
3 Flood, A.E., Addai-Mensah, J., Johns, M.R., White, E.T., “Refractive index, viscosity and solubility in the system fructose+ethanol+water at 30, 40, and 50℃”, J. Chem. Eng. Data, 41, 418-421 (1996).
4 Macedo, E.A., Peres, A.M., “Thermodynamics of ternary mixtures containing sugars. SLE of D-fructose in pure and mixed solvents. Comparison between modified UNIQUAC and modified UNIFAC”, Ind. Eng. Chem. Res., 40, 4633-4640 (2001).
5 Peres, A.M., Macedo, E.A., “Phase equilibria of D-glucose and sucrose in mixed solvent mixtures:Comparison of UNIQUAC-based models”, Carbohydr. Res., 303, 135-151 (1997).
6 Alves, L.A., Almeida e Silva, J.B., Giulietti, M., “Solubility of D-glucose in water and ethanol/water mixtures”, J. Chem. Eng. Data, 52, 2166-2170 (2007).
7 Bockstanz, G.L., Buffa, M., Lira, C.T., “Solubilities of α-anhydrous glucose in ethanol/water mixtures”, J. Chem. Eng. Data, 34, 426-429 (1989).
8 Peres, A.M., Macedo, E.A., “Solid-liquid equilibrium of sugars in mixed solvents”, Entropie, 202/203, 71-75 (1997).
9 Wei, D.W., Pei, Y.H., Zhang, C., Yan, F., “Measurement and correlation of solid-liquid equilibria of phenyl salicylate with C 4 alcohols”, Chin. J. Chem. Eng., 17, 140-144 (2009).
10 Xia, Q., Ma, P.S., “Measurement and correlation for solubility of dimethyl-2,6-naphthalene dicarboxylate in organic solvents”, Chin. J. Chem. Eng., 15, 215-220 (2007).
11 Mao, Z.B., Sun, X.B., Luan, X.H., Wang, Y., Liu, G.J., “Measurement and correlation of solubilities of adipic acid in different solvents”, Chin. J. Chem. Eng., 17, 473-477 (2009).
12 Zhou, C.R., Shi, X.H., Wang, H.F., Gao, Y.G., Jiang, D.G., “Solid-liquid equilibria of trans-1,2-cyclohexanediol+butyl acetate+water ternary system”, Chin. J. Chem. Eng., 15, 449-452 (2007).
13 Gong, X.C., Lu, Y.C., Luo, G.S., “Phase equilibrium calculations in mixtures containing caprolactam with a UNIFAC model”, Chin. J. Chem. Eng., 18, 286-291 (2010).
14 Peres, A. M., Macedo, E. A., “Thermodynamic properties of sugars in aqueous solutions:Correlation and prediction using a modified UNIQUAC model”, Fluid Phase Equilib., 123, 71-95 (1996).
15 Spiliotis, N., Tassios, D., “A UNIFAC model for phase equilibrium calculations in aqueous and nonaqueous sugar solutions”, Fluid Phase Equilib., 173, 39-55 (2000).
16 Magnussen, T., Rasmussen, P., Fredenslund, A., “UNIFAC parameter table for prediction of liquid-liquid equlibria”, Ind. Eng. Chem. Process Des. Dev., 20, 331-339 (1981).
17 Tsavas, P., Voutsas, E., Magoulas, K., Tassios, D., “Phase equilibrium calculations in aqueous and nonaqueous mixtures of sugars and sugar derivatives with a group-contribution model”, Ind. Eng. Chem. Res., 43, 8391-8399 (2004).
18 Larsen, B., Rasmussen, P., Fredenslund, A., “Modified UNIFAC group-contribution model for prediction of phase equilibria and heats of mixing”, Ind. Eng. Chem. Res., 26, 2274-2286 (1987).
19 Fredenslund, A., Jones, R.L., Prausnitz, J.M., “Group-contribution estimation of activity coefficients in nonideal liquid mixtures”, AIChE J., 21, 1086-1099 (1975).

[1]	Tingjun Fu, Ran Wang, Kun Ren, Liangliang Zhang, Zhong Li. Intensified shape selectivity and alkylation reaction for the two-step conversion of methanol aromatization to p-xylene[J]. 中国化学工程学报, 2023, 59(7): 240-250.
[2]	Yi Wu, Pengfei Song, Ningyan Li, Yanan Jiang, Yuan Liu. Molybdenum tailored Co⁰/Co²⁺ active pairs on a perovskite-type oxide for direct ethanol synthesis from syngas[J]. 中国化学工程学报, 2023, 59(7): 279-289.
[3]	Pengcheng Zou, Kai Wang. Methanolysis of amides under high-temperature and high-pressure conditions with a continuous tubular reactor[J]. 中国化学工程学报, 2023, 58(6): 170-178.
[4]	Jiaxin Wu, Chenxiao Wang, Xianliang Meng, Haichen Liu, Ruizhi Chu, Guoguang Wu, Weisong Li, Xiaofeng Jiang, Deguang Yang. Enhancement of catalytic and anti-carbon deposition performance of SAPO-34/ZSM-5/quartz films in MTA reaction by Si/Al ratio regulation[J]. 中国化学工程学报, 2023, 56(4): 314-324.
[5]	Xinhai Zhou, Dawei Zhou, Xinhui Bao, Yang Zhang, Jie Zhou, Fengxue Xin, Wenming Zhang, Xiujuan Qian, Weiliang Dong, Min Jiang, Katrin Ochsenreither. Production of palmitoleic acid by oleaginous yeast Scheffersomyces segobiensis DSM 27193 using systematic dissolved oxygen regulation strategy[J]. 中国化学工程学报, 2023, 53(1): 324-331.
[6]	Tianqi Fang, Mengyuan Liu, Zhaozhe Li, Li Xiong, Dongpei Zhang, Kexin Meng, Xiaolei Qu, Guangyu Zhang, Xin Jin, Chaohe Yang. Hydrothermal conversion of fructose to lactic acid and derivatives: Synergies of metal and acid/base catalysts[J]. 中国化学工程学报, 2023, 53(1): 381-401.
[7]	Yao Zhong, Cuiying Huang, Lijie Li, Qiang Deng, Jun Wang, Zheling Zeng, Shuguang Deng. Postsynthetic acid modification of amino-tagged metal-organic frameworks: Structure-functionrelationship for catalytic 5-hydroxymethylfurfural synthesis[J]. 中国化学工程学报, 2022, 49(9): 245-252.
[8]	Xing Su, Ning Qiao, Bao-Chang Sun. A route for the study on mass transfer enhancement by adding particles in liquid phase[J]. 中国化学工程学报, 2022, 48(8): 158-165.
[9]	Siyue Ren, Xiao Feng. Emergy evaluation of aromatics production from methanol and naphtha[J]. 中国化学工程学报, 2022, 46(6): 134-141.
[10]	Xiangjun Li, Shujun Li, Xiaoping Wang, Muhammad Asif Nawaz, Dianhua Liu. Polyoxymethylene dimethyl ethers synthesis from methanol and formaldehyde solution over one-pot synthesized spherical mesoporous sulfated zirconia[J]. 中国化学工程学报, 2022, 46(6): 161-172.
[11]	Lijuan He, Cuimei Zhi, Lixia Ling, Riguang Zhang, Baojun Wang. Syngas to ethanol on MoCu(2 1 1) surface: Effect of promoter Mo on C—O bond breaking and C—C bond formation[J]. 中国化学工程学报, 2022, 45(5): 78-89.
[12]	Youwei Yang, Jingyu Zhang, Yueqi Gao, Busha Assaba Fayisa, Antai Li, Shouying Huang, Jing Lv, Yue Wang, Xinbin Ma. Highly dispersed nickel boosts catalysis by Cu/SiO₂ in the hydrogenation of CO₂-derived ethylene carbonate to methanol and ethylene glycol[J]. 中国化学工程学报, 2022, 43(3): 77-85.
[13]	Yihan Yin, Aoqian Qiu, Hongxia Gao, Yanqing Na, Zhiwu Liang. Experimental study of the mass transfer behavior of carbon dioxide absorption into ternary phase change solution in a packed tower[J]. 中国化学工程学报, 2022, 43(3): 135-142.
[14]	Wanqiao Liang, Jihuan Huang, Penny Xiao, Ranjeet Singh, Jining Guo, Leila Dehdari, Gang Kevin Li. Amine-immobilized HY zeolite for CO₂ capture from hot flue gas[J]. 中国化学工程学报, 2022, 43(3): 335-342.
[15]	Xia Zhan, Xueying Zhao, Zhongyong Gao, Rui Ge, Juan Lu, Luying Wang, Jiding Li. Breakthroughs on tailoring membrane materials for ethanol recovery by pervaporation[J]. 中国化学工程学报, 2022, 52(12): 19-36.

Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K

Solid-Liquid Equilibria of D-Glucose,D-Fructose and Sucrose in the Mixture of Ethanol and Water from 273.2 K to 293.2 K

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价