Evaluation of substrates for zinc negative electrode in acid PbO2-Zn single flow batteries

doi:10.1016/j.cjche.2016.01.001

Chinese Journal of Chemical Engineering ›› 2016, Vol. 24 ›› Issue (4): 529-534.DOI: 10.1016/j.cjche.2016.01.001

• 第25届中国过程控制会议专栏 • 上一篇下一篇

Evaluation of substrates for zinc negative electrode in acid PbO₂-Zn single flow batteries

Junli Pan^1,2, Yuehua Wen², Jie Cheng², Junqing Pan¹, Shouli Bai¹, Yusheng Yang^1,2

1 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
2 Research Institute of Chemical Defence, Beijing 100191, China

收稿日期:2015-03-24 修回日期:2015-12-14 出版日期:2016-04-28 发布日期:2016-05-27
通讯作者: Yuehua Wen, Junqing Pan
基金资助:
Supported by the National Basic Research Program (973 Program) of China (2010CB227201), the State Key Program of National Natural Science of China (21236003), the National Natural Science Foundation of China (21476022), the Fundamental Research Funds for the Central Universities (JD1515 and YS1406), Beijing Higher Education Young Elite Teacher Project (YETP0509).

Evaluation of substrates for zinc negative electrode in acid PbO₂-Zn single flow batteries

Junli Pan^1,2, Yuehua Wen², Jie Cheng², Junqing Pan¹, Shouli Bai¹, Yusheng Yang^1,2

1 State Key Laboratory of Chemical Resource Engineering, Beijing University of Chemical Technology, Beijing 100029, China;
2 Research Institute of Chemical Defence, Beijing 100191, China

Received:2015-03-24 Revised:2015-12-14 Online:2016-04-28 Published:2016-05-27
Contact: Yuehua Wen, Junqing Pan
Supported by:
Supported by the National Basic Research Program (973 Program) of China (2010CB227201), the State Key Program of National Natural Science of China (21236003), the National Natural Science Foundation of China (21476022), the Fundamental Research Funds for the Central Universities (JD1515 and YS1406), Beijing Higher Education Young Elite Teacher Project (YETP0509).

摘要/Abstract

摘要： An investigationwas performed on the suitability of carbonmaterials,metallic lead and its alloys as substrates for zinc negative electrode in acid PbO₂-Zn single flow batteries. The zinc deposition process was carried out in the medium of 1 mol·L^-1 H₂SO₄ at room temperature. No maximum current appears on the potentiostatic current transients for the zinc deposition on lead and its alloys.With increasing overpotential, the progressive nucleation turns to be a 3D-instantaneous nucleation process for the resin-graphite composite. Hydrogen evolution on the graphite composite is effectively suppressedwith the doping of a polymer resin. The hydrogen evolution reaction on the lead is relatively weak, while on the lead alloys, it becomes serious to a certain degree. Although the exchange current density of zinc deposition and dissolution process on the graphite composite is relatively low, the zinc corrosion is weakened to a great extent. With the increase of deposition time, zinc deposits are more compact. The cyclings of zinc galvanostatic charge-discharge on the graphite composite provide more than 90% of coulombic and 80% of energy efficiencies, and exhibit superior cycling stability during the first 10 cycles.

关键词: Acid single flow battery, Zinc negative electrode, Electro-deposition, Substrate

Abstract: An investigationwas performed on the suitability of carbonmaterials,metallic lead and its alloys as substrates for zinc negative electrode in acid PbO₂-Zn single flow batteries. The zinc deposition process was carried out in the medium of 1 mol·L^-1 H₂SO₄ at room temperature. No maximum current appears on the potentiostatic current transients for the zinc deposition on lead and its alloys.With increasing overpotential, the progressive nucleation turns to be a 3D-instantaneous nucleation process for the resin-graphite composite. Hydrogen evolution on the graphite composite is effectively suppressedwith the doping of a polymer resin. The hydrogen evolution reaction on the lead is relatively weak, while on the lead alloys, it becomes serious to a certain degree. Although the exchange current density of zinc deposition and dissolution process on the graphite composite is relatively low, the zinc corrosion is weakened to a great extent. With the increase of deposition time, zinc deposits are more compact. The cyclings of zinc galvanostatic charge-discharge on the graphite composite provide more than 90% of coulombic and 80% of energy efficiencies, and exhibit superior cycling stability during the first 10 cycles.

Key words: Acid single flow battery, Zinc negative electrode, Electro-deposition, Substrate

Junli Pan, Yuehua Wen, Jie Cheng, Junqing Pan, Shouli Bai, Yusheng Yang. Evaluation of substrates for zinc negative electrode in acid PbO₂-Zn single flow batteries[J]. Chinese Journal of Chemical Engineering, 2016, 24(4): 529-534.

Junli Pan, Yuehua Wen, Jie Cheng, Junqing Pan, Shouli Bai, Yusheng Yang. Evaluation of substrates for zinc negative electrode in acid PbO₂-Zn single flow batteries[J]. Chin.J.Chem.Eng., 2016, 24(4): 529-534.

参考文献

[1] C. Ponce de León, A. Frías-Ferrer, J. González-García, D.A. Szánto, F.C. Walsh, Redox flow cells for energy conversion, J. Power Sources 160(2006) 716-732.

[2] A. Hazza, D. Pletcher, R. Wills, A novel flow battery: A lead acid battery based on an electrolyte with soluble lead(ii), Phys. Chem. Chem. Phys. 6(2004) 1773-1778.

[3] J. Cheng, L. Zhang, Y.S. Yang, Y.H. Wen, G.P. Cao, X.D.Wang, Preliminary study of single flow zinc-nickel battery, Electrochem. Commun. 9(2007) 2639-2642.

[4] T.I. Evans, R.E. White, A review of mathematical modeling of the zinc/bromine flow cell and battery, J. Electrochem. Soc. 134(1987) 2725-2733.

[5] D. Loftus, J. Roberts, R.Weaver, S. Leach, L. Nanis, Diffusivity in zinc chloride-potassium chloride electrolyte, J. Electrochem. Soc. 130(1983) 332-334.

[6] G. Nikiforidis, L. Berlouis, D. Hall, D. Hodgson, Evaluation of carbon composite materials for the negative electrode in the zinc-cerium redox flow cell, J. Power Sources 206(2012) 497-503.

[7] F. Yu,M.Y. Zhu, X.G. Wang, G.Wang, P.R. Qi, D. Chen, B. Dai, Clean energy and energy storage research-The 2nd international conference on clean energy sciences, Energy Storage Sci. Technol. 3(2014) 457-470.

[8] A. Hazza, D. Pletcher, R.Wills, A novel flow battery-A lead acid battery based on an electrolyte with soluble lead(II), J. Power Sources 149(2005) 103-111.

[9] C. Xu, B. Li, H. Du, F. Kang, Energetic zinc ion chemistry: The rechargeable zinc ion battery, Angew. Chem. 51(2012) 933-935.

[10] D. Xu, B. Li, C.Wei, Y.B. He, H. Du, X. Chu, X. Qin, Q.H. Yang, F. Kang, Preparation and characterization of MnO₂/acid-treated CNT Nanocomposites for energy storage with zinc ions, Electrochim. Acta 133(2014) 254-261.

[11] C. Wei, C. Xu, B. Li, H. Du, F. Kang, Preparation and characterization of manganese dioxides with nano-sized tunnel structures for zinc ion storage, J. Phys. Chem. Solids 73(2012) 1487-1491.

[12] M.H. Alfaruqi, J. Gim, S. Kim, J. Song, J. Jo, S. Kim, V.Mathew, J. Kim, Enhanced reversible divalent zinc storage in a structurally stable α-MnO₂ nanorod electrode, J. Power Sources 288(2015) 320-327.

[13] J.X. Yu, H.X. Yang, X.P. Ai, X.M. Zhu, A study of calcium zincate as negative electrode materials for secondary batteries, J. Power Sources 103(2001) 93-97.

[14] S. Tong, T. Zhang, C.A. Ma, Oxygen evolution behavior of PTFE-F-PbO₂ electrode in H₂SO₄ solution, Chin. J. Chem. Eng. 16(2008) 885-889.

[15] X. Hong, R. Zhang, S. Tong, C.A. Ma, Preparation of TiPTFE-F-PbO₂ electrode with a long life from the sulfamic acid bath and its application in organic degradation, Chin. J. Chem. Eng. 19(2011) 1033-1038.

[16] J. Pan, Y. Wen, J. Cheng, J. Pan, Z. Bai, Y. Yang, Zinc deposition and dissolution in sulfuric acid onto a graphite-resin composite electrode as the negative electrode reactions in acidic zinc-based redox flow batteries, J. Appl. Electrochem. 43(2013) 541-551.

[17] P.K. Leung, Q. Xu, T.S. Zhao, High-potential zinc-lead dioxide rechargeable cells, Electrochim. Acta 79(2012) 117-125.

[18] B.C. Tripathy, S.C. Das, P. Singh, G.T. Hefter, V.N. Misra, Zinc electrowinning from acidic sulphate solutions part IV: Effects of perfluorocarboxylic acids, J. Electroanal. Chem. 565(2004) 49-56.

[19] C. Cachet, R. Wiart, Influence of a perfluorinated surfactant on the mechanism of zinc deposition in acidic electrolytes, Electrochim. Acta 44(1999) 4743-4751.

[20] S. Han, B. Qiu, Z.Wei, Y. Xia, Z. Liu, Surface structural conversion and electrochemical enhancement by heat treatment of chemical pre-delithiation processed lithium-rich layered cathode material, J. Power Sources 268(2014) 683-691.

[21] Q.B. Zhang, Y. Hua, Effect of Mn²⁺ ions on the electrodeposition of zinc from acidic sulphate solutions, Hydrometallurgy 99(2009) 249-254.

[22] A.E. Alvarez, D.R. Salinas, Nucleation and growth of Zn on HOPG in the presence of gelatine as additive, J. Electroanal. Chem. 566(2004) 393-400.

Evaluation of substrates for zinc negative electrode in acid PbO₂-Zn single flow batteries

Evaluation of substrates for zinc negative electrode in acid PbO₂-Zn single flow batteries

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Bee Huah Lim, Edy Herianto Majlan, Ahmad Tajuddin, Teuku Husaini, Wan Ramli Wan Daud, Nabilah Afiqah Mohd Radzuan, Md. Ahsanul Haque. Comparison of catalyst-coated membranes and catalyst-coated substrate for PEMFC membrane electrode assembly: A review[J]. 中国化学工程学报, 2021, 33(5): 1-16.
[2]	Nanhua Wu, Xiaohua Lu, Rong An, Xiaoyan Ji. Thermodynamic analysis and modification of Gibbs–Thomson equation for melting point depression of metal nanoparticles[J]. 中国化学工程学报, 2021, 29(3): 198-205.
[3]	Chi Ma, Le Sang, Xiaonan Duan, Jiabin Yin, Jisong Zhang. An efficient method for enhancing adhesion and uniformity of Al₂O₃ coatings on nickel micro-foam used in micropacked beds[J]. 中国化学工程学报, 2021, 39(11): 162-172.
[4]	Xiaoli Xue, Zhimin Zong, Guanghui Liu, Xianyong Wei. Mild oxidative degradation of spent auricularia auricular substrate and molecular composition of carboxylic acids in the resulting soluble portion[J]. 中国化学工程学报, 2020, 28(2): 548-555.
[5]	Xinlei Wei, Pingping Han, Chun You. Facilitation of cascade biocatalysis by artificial multi-enzyme complexes—A review[J]. 中国化学工程学报, 2020, 28(11): 2799-2809.
[6]	Hongyong Zhao, Lizhong Feng, Xiaoli Ding, Xiaoyao Tan, Yuzhong Zhang. Gas permeation properties of a metallic ion-cross-linked PIM-1 thin-film composite membrane supported on a UV-cross-linked porous substrate[J]. Chinese Journal of Chemical Engineering, 2018, 26(12): 2477-2486.
[7]	Jie Li, Mingjie Wei, Yong Wang. Substrate matters:The influences of substrate layers on the performances of thin-film composite reverse osmosis membranes[J]. Chinese Journal of Chemical Engineering, 2017, 25(11): 1676-1684.
[8]	Weixin Zhang, Yingmeng Zhang, Zeheng Yang, Gongde Chen, Guo Ma, QiangWang. In-situ design and construction of lithium-ion battery electrodes on metal substrates with enhanced performances: A brief review[J]. Chinese Journal of Chemical Engineering, 2016, 24(1): 48-52.
[9]	Zongkuan Liu, Lei Zhang, Yonghong Liu, Yanling He. Anaerobic biodegradation of RDX and HMX with different co-substrates[J]. Chinese Journal of Chemical Engineering, 2015, 23(4): 704-709.
[10]	彭春龙, 黄俊, 胡升, 赵伟睿, 姚善泾, 梅乐和. A Two-stage pH and Temperature Control with Substrate Feeding Strategy for Production of Gamma-aminobutyric Acid by Lactobacillus brevis CGMCC 1306[J]. Chinese Journal of Chemical Engineering, 2013, 21(10): 1190-1194.
[11]	彭赵旭, 彭永臻, 桂丽娟, 刘旭亮. Competition for Single Carbon Source Between Denitrification and Phosphorus Release in Sludge under Anoxic Condition[J]. , 2010, 18(3): 472-477.
[12]	赵旭辉, 杨灵芳, 左禹, 熊金平. Hydroxyapatite Coatings on Titanium Prepared by Electrodeposition in a Modified Simulated Body Fluid[J]. , 2009, 17(4): 667-671.
[13]	闻建平, 李红梅, 白静, 姜岩. 白假丝酵母PDY-07厌氧生物降解4-氯酚的研究[J]. , 2006, 14(6): 790-795.
[14]	XIAOMeitian(肖美添),HUANGYayan(黄雅燕),MENGChun(孟春)andGUOYanghao(郭养浩). Kinetics of Asymmetric Reduction of Phenylglyoxylic Acid to R-(－)-Mandelic Acid by Saccharomyces Cerevisiae FD11b[J]. , 2006, 14(1): 73-80.
[15]	冀秀玲, 张金利, 李(韦华), 韩振亭, 王一平. 基质穿膜作用对苯酚生物降解动力学的影响[J]. , 2003, 11(2): 151-155.