Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C4mim][HSO4] ionic liquid

›› 2016, Vol. 24 ›› Issue (9): 1166-1170.

• Catalysis, Kinetics and Reaction Engineering • 上一篇下一篇

Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C₄mim][HSO₄] ionic liquid

DanfengWang, Zhicheng He, Zhimin Wu, Ying Tan, Yongfei Li, Yuejin Liu

College of Chemical Engineering, Xiangtan University, Xiangtan 411105, Hunan, China

收稿日期:2015-10-08 修回日期:2016-01-19 出版日期:2016-09-28 发布日期:2016-11-11
通讯作者: Zhimin Wu,E-mail address:xdwuzm@163.com;Yuejin Liu,E-mail address:xdlyj@163.com
基金资助:
Supported by the National Natural Science Foundation of China (21276217).

Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C₄mim][HSO₄] ionic liquid

DanfengWang, Zhicheng He, Zhimin Wu, Ying Tan, Yongfei Li, Yuejin Liu

College of Chemical Engineering, Xiangtan University, Xiangtan 411105, Hunan, China

Received:2015-10-08 Revised:2016-01-19 Online:2016-09-28 Published:2016-11-11
Supported by:
Supported by the National Natural Science Foundation of China (21276217).

摘要/Abstract

摘要： The effects of N-methylimidazole cation[C_nmim] with different alkyl chain lengths, the types of cations and anions of ionic liquids and the reaction parameters on the catalytic activity and the selectivity for 4,4'-bisphenol F were investigated. The hydrogen bonding between the hydroxyl of phenol and the C2-position hydrogen of imidazole moiety in hydrophilic imidazole-based ionic liquid has important influence on the selectivity for 4,4'-bisphenol F, and under the conditions of the molar ratio of phenol/[C₄mim] [HSO₄] 1:1, reaction temperature 65℃ and the theoretical molar ratio of phenol/formaldehyde 2:1, the selectivity for 4,4'-bisphenol F reached 69.1%. Compared with the high phenol/formaldehyde ratio reported in literatures, the low molar ratio of phenol/formaldehyde and the low reaction temperature can greatly reduce energy consumption, and has important significance for industrial application.

关键词: 4,4'-Bisphenol F, Phenol, Formaldehyde, 1-Butyl-3-methylimidazolium hydrogen, sulfate

Abstract: The effects of N-methylimidazole cation[C_nmim] with different alkyl chain lengths, the types of cations and anions of ionic liquids and the reaction parameters on the catalytic activity and the selectivity for 4,4'-bisphenol F were investigated. The hydrogen bonding between the hydroxyl of phenol and the C2-position hydrogen of imidazole moiety in hydrophilic imidazole-based ionic liquid has important influence on the selectivity for 4,4'-bisphenol F, and under the conditions of the molar ratio of phenol/[C₄mim] [HSO₄] 1:1, reaction temperature 65℃ and the theoretical molar ratio of phenol/formaldehyde 2:1, the selectivity for 4,4'-bisphenol F reached 69.1%. Compared with the high phenol/formaldehyde ratio reported in literatures, the low molar ratio of phenol/formaldehyde and the low reaction temperature can greatly reduce energy consumption, and has important significance for industrial application.

Key words: 4,4'-Bisphenol F, Phenol, Formaldehyde, 1-Butyl-3-methylimidazolium hydrogen, sulfate

中图分类号:

10.1016/j.cjche.2016.02.005

DanfengWang, Zhicheng He, Zhimin Wu, Ying Tan, Yongfei Li, Yuejin Liu. Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C₄mim][HSO₄] ionic liquid[J]. , 2016, 24(9): 1166-1170.

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Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C₄mim][HSO₄] ionic liquid

Highly selective synthesis for 4, 4'-bisphenol F from phenol and formaldehyde catalyzed with [C₄mim][HSO₄] ionic liquid

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