One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6

doi:10.1016/j.cjche.2018.02.031

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (6): 1270-1277.DOI: 10.1016/j.cjche.2018.02.031

One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6

Chongwen Jiang^1,2, Jundong Zhu¹, Bing Wang¹, Lu Li¹, Hong Zhong^1,2

1 College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;
2 Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources, Central South University, Changsha 410083, China

收稿日期:2017-10-13 修回日期:2018-02-07 出版日期:2018-06-28 发布日期:2018-08-03
通讯作者: Chongwen Jiang,E-mail address:jcwcsu@csu.edu.cn
基金资助:
Supported by the National Natural Science Foundation of China (21476267), the China-Japan International Cooperation Project (2013DFG50150) and the Hunan Provincial Science and Technology Department Plan Project (2016TP1007).

One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6

Chongwen Jiang^1,2, Jundong Zhu¹, Bing Wang¹, Lu Li¹, Hong Zhong^1,2

1 College of Chemistry and Chemical Engineering, Central South University, Changsha 410083, China;
2 Hunan Provincial Key Laboratory of Efficient and Clean Utilization of Manganese Resources, Central South University, Changsha 410083, China

Received:2017-10-13 Revised:2018-02-07 Online:2018-06-28 Published:2018-08-03
Contact: Chongwen Jiang,E-mail address:jcwcsu@csu.edu.cn
Supported by:
Supported by the National Natural Science Foundation of China (21476267), the China-Japan International Cooperation Project (2013DFG50150) and the Hunan Provincial Science and Technology Department Plan Project (2016TP1007).

摘要/Abstract

摘要： Zirconium doped mesoporous KIT-6 samples with different Si/Zr ratios were synthesized by the direct hydrothermal method. Various characterization techniques confirm that highly distributed ZrO₂ nanoparticles and multicoordinated Zr⁴⁺ species are incorporated in the mesoporous composites. One-pot synthesis of 5-hydroxymethylfurfura(HMF) from glucose was examined in the presence of Zr-KIT-6(20) the molar ratio of Si to Zr is 20 under aqueous system. The effects of temperature, reaction time, catalyst dosage and biphasic solvent system on the conversion of glucose and the HMF yield were investigated. It was found that the glucose conversion and the HMF yield have been improved from 54.8% to 79.0% and from 19.5% to 34.5% in the biphasic MIBK-water system, respectively. Both the acidity of Zr-KIT-6(20) and the biphasic MIBK-water system are responsible for the improved performance of glucose dehydration to HMF.

关键词: Glucose, One-pot, Dehydration, 5-HMF, Hydrothermal, Mesoporous KIT-6

Abstract: Zirconium doped mesoporous KIT-6 samples with different Si/Zr ratios were synthesized by the direct hydrothermal method. Various characterization techniques confirm that highly distributed ZrO₂ nanoparticles and multicoordinated Zr⁴⁺ species are incorporated in the mesoporous composites. One-pot synthesis of 5-hydroxymethylfurfura(HMF) from glucose was examined in the presence of Zr-KIT-6(20) the molar ratio of Si to Zr is 20 under aqueous system. The effects of temperature, reaction time, catalyst dosage and biphasic solvent system on the conversion of glucose and the HMF yield were investigated. It was found that the glucose conversion and the HMF yield have been improved from 54.8% to 79.0% and from 19.5% to 34.5% in the biphasic MIBK-water system, respectively. Both the acidity of Zr-KIT-6(20) and the biphasic MIBK-water system are responsible for the improved performance of glucose dehydration to HMF.

Key words: Glucose, One-pot, Dehydration, 5-HMF, Hydrothermal, Mesoporous KIT-6

Chongwen Jiang, Jundong Zhu, Bing Wang, Lu Li, Hong Zhong. One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6[J]. Chinese Journal of Chemical Engineering, 2018, 26(6): 1270-1277.

Chongwen Jiang, Jundong Zhu, Bing Wang, Lu Li, Hong Zhong. One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6[J]. Chin.J.Chem.Eng., 2018, 26(6): 1270-1277.

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One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6

One-pot synthesis of 5-hydroxymethylfurfural from glucose over zirconium doped mesoporous KIT-6

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