Stimuli-responsive emulsions: Recent advances and potential applications

doi:10.1016/j.cjche.2021.11.002

中国化学工程学报 ›› 2022, Vol. 41 ›› Issue (1): 193-209.DOI: 10.1016/j.cjche.2021.11.002

Stimuli-responsive emulsions: Recent advances and potential applications

Xue-hui Ge, Liangji Mo, Anhe Yu, Chenzi Tian, Xiaoda Wang, Chen Yang, Ting Qiu

Engineering Research Center of Reactive Distillation, Fujian Province University, College of Chemical Engineering, Fuzhou University, Fuzhou 350108, China;Qingyuan Innovation Laboratory, Quanzhou 362801, China

收稿日期:2021-06-28 修回日期:2021-11-06 出版日期:2022-01-28 发布日期:2022-02-25
通讯作者: Chen Yang,E-mail address:cyang@fzu.edu.cn;Ting Qiu,E-mail address:tingqiu@fzu.edu.cn
基金资助:
This work was supported by the National Natural Science Foundation of China (21908026), the Fujian Province science and technology guidance project (2021Y0007) and Key Program of Qingyuan Innovation Laboratory (00221004).

Stimuli-responsive emulsions: Recent advances and potential applications

Xue-hui Ge, Liangji Mo, Anhe Yu, Chenzi Tian, Xiaoda Wang, Chen Yang, Ting Qiu

Engineering Research Center of Reactive Distillation, Fujian Province University, College of Chemical Engineering, Fuzhou University, Fuzhou 350108, China;Qingyuan Innovation Laboratory, Quanzhou 362801, China

Received:2021-06-28 Revised:2021-11-06 Online:2022-01-28 Published:2022-02-25
Contact: Chen Yang,E-mail address:cyang@fzu.edu.cn;Ting Qiu,E-mail address:tingqiu@fzu.edu.cn
Supported by:
This work was supported by the National Natural Science Foundation of China (21908026), the Fujian Province science and technology guidance project (2021Y0007) and Key Program of Qingyuan Innovation Laboratory (00221004).

摘要/Abstract

摘要： Responsive emulsions are the emulsions that can be reversibly switched on-demand between “stable” and “unstable” by environmental stimulus or trigger, which allows a simple and effective adjustment approach to achieve emulsification and demulsification. In recent years, stimuli-responsive emulsions acting as smart soft material are received considerable attention with the advantages of simple manipulation, good reversibility, low cost, easy treatment, and little effect on the system. In this paper, the recent research progress of emulsions that can respond to external stimuli, including pH, light, magnetic field, CO₂/N₂ and dual responsive are reviewed. Also, the potential applications based on responsive emulsion are discussed, such as catalytic reactions, heavy oil recovery, polymer particles synthesis and optical sensor, aiming to summarize the latest achievements and put forward the possible development trends of responsive emulsions.

关键词: Stimuli-responsive, Emulsions, Switchable surfactants, Interface

Abstract: Responsive emulsions are the emulsions that can be reversibly switched on-demand between “stable” and “unstable” by environmental stimulus or trigger, which allows a simple and effective adjustment approach to achieve emulsification and demulsification. In recent years, stimuli-responsive emulsions acting as smart soft material are received considerable attention with the advantages of simple manipulation, good reversibility, low cost, easy treatment, and little effect on the system. In this paper, the recent research progress of emulsions that can respond to external stimuli, including pH, light, magnetic field, CO₂/N₂ and dual responsive are reviewed. Also, the potential applications based on responsive emulsion are discussed, such as catalytic reactions, heavy oil recovery, polymer particles synthesis and optical sensor, aiming to summarize the latest achievements and put forward the possible development trends of responsive emulsions.

Key words: Stimuli-responsive, Emulsions, Switchable surfactants, Interface

Xue-hui Ge, Liangji Mo, Anhe Yu, Chenzi Tian, Xiaoda Wang, Chen Yang, Ting Qiu. Stimuli-responsive emulsions: Recent advances and potential applications[J]. 中国化学工程学报, 2022, 41(1): 193-209.

Xue-hui Ge, Liangji Mo, Anhe Yu, Chenzi Tian, Xiaoda Wang, Chen Yang, Ting Qiu. Stimuli-responsive emulsions: Recent advances and potential applications[J]. Chinese Journal of Chemical Engineering, 2022, 41(1): 193-209.

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Stimuli-responsive emulsions: Recent advances and potential applications

Stimuli-responsive emulsions: Recent advances and potential applications

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[3]	Hao Zhang, Daiwei Liu, Jiangbo Wen, Guangyu Sun, Chuanxian Li, Xinya Chen, Huihui Zhang, Ze Duan. Co-adsorption behaviors of asphaltenes and different flow improvers and their impacts on the interfacial viscoelasticity[J]. 中国化学工程学报, 2022, 48(8): 149-157.
[4]	Guangchun Song, Yuanxing Ning, Yuxing Li, Wuchang Wang. Investigation on hydrate growth at the oil–water interface: In the presence of asphaltene[J]. 中国化学工程学报, 2022, 45(5): 211-218.
[5]	Yanan Wei, Yunlei Zhang, Bing Li, Wen Guan, Changhao Yan, Xin Li, Yongsheng Yan. Facile synthesis of metal-organic frameworks embedded in interconnected macroporous polymer as a dual acid-base bifunctional catalyst for efficient conversion of cellulose to 5-hydroxymethylfurfural[J]. 中国化学工程学报, 2022, 44(4): 169-181.
[6]	Shaoxiang Cai, Han Yan, Qiuyi Wang, He Han, Ru Li, Zhichao Lou. Top-down strategy for bamboo lignocellulose-derived carbon heterostructure with enhanced electromagnetic wave dissipation[J]. 中国化学工程学报, 2022, 43(3): 360-369.
[7]	Yaping Wang, Songyue Cheng, Wendi Fan, Yikun Jiang, Jie Yang, Zaizai Tong, Guohua Jiang. Dual responsive block copolymer coated hollow mesoporous silica nanoparticles for glucose-mediated transcutaneous drug delivery[J]. 中国化学工程学报, 2022, 51(11): 35-42.
[8]	Hongliang Qian, Hongzhou Tian, Guoqiang Yang, Gaodong Yang, Lei Li, Feng Zhang, Zheng Zhou, Weihua Huang, Yufu Chen, Zhibing Zhang. Microinterface intensification in hydrogenation and air oxidation processes[J]. 中国化学工程学报, 2022, 50(10): 292-300.
[9]	Jule Ma, Peiwen Xiao, Pingmei Wang, Xue Han, Jianhui Luo, Ruifang Shi, Xuan Wang, Xianyu Song, Shuangliang Zhao. Molecular dynamics simulation study on π-π stacking of Gemini surfactants in oil/water systems[J]. 中国化学工程学报, 2022, 50(10): 335-346.
[10]	Shan Ni, Hongnan Qu, Huifang Xing, Zihao Xu, Xiangyang Zhu, Menglei Yuan, Meng Rong, Li Wang, Jiemiao Yu, Yanqing Li, Liangrong Yang, Huizhou Liu. Interfacial engineering of transition-metal sulfides heterostructures with built-in electric-field effects for enhanced oxygen evolution reaction[J]. 中国化学工程学报, 2022, 41(1): 320-328.
[11]	Guohui Zhou, Kun Jiang, Zhenlei Wang, Xiaomin Liu. Insight into the behavior at the hygroscopicity and interface of the hydrophobic imidazolium-based ionic liquids[J]. 中国化学工程学报, 2021, 29(3): 42-55.
[12]	Kai Ge, Yuanhui Ji, Xiaohua Lu. A novel interfacial thermodynamic model for predicting solubility of nanoparticles coated by stabilizers[J]. 中国化学工程学报, 2021, 29(3): 103-112.
[13]	Jie Yang, Alejandro Gallegos, Cheng Lian, Shengwei Deng, Honglai Liu, Jianzhong Wu. Curvature effects on electric-double-layer capacitance[J]. 中国化学工程学报, 2021, 29(3): 145-152.
[14]	Qingwei Gao, Yumeng Zhang, Aatto Laaksonen, Yudan Zhu, Xiaoyan Ji, Shuangliang Zhao, Yaojia Chen, Xiaohua Lu. Effect of dimethyl carbonate on the behavior of water confined in carbon nanotube[J]. 中国化学工程学报, 2021, 29(3): 177-185.
[15]	Qihui Hu, Xiaoyu Wang, Wuchang Wang, Yuxing Li, Shuai Liu. Growth and aggregation micromorphology of natural gas hydrate particles near gas-liquid interface under stirring condition[J]. 中国化学工程学报, 2021, 40(12): 65-77.