One-pot in-situ synthesis of coralloid supported VO2 catalyst for intensified aerobic oxidative desulfurization

doi:10.1016/j.cjche.2022.07.005

中国化学工程学报 ›› 2023, Vol. 56 ›› Issue (4): 136-140.DOI: 10.1016/j.cjche.2022.07.005

• Short Communication • 上一篇下一篇

One-pot in-situ synthesis of coralloid supported VO₂ catalyst for intensified aerobic oxidative desulfurization

Suhang Xun¹, Cancan Wu¹, Lida Tang², Mengmeng Yuan², Haofeng Chen², Minqiang He², Wenshuai Zhu², Huaming Li²

1. Institute of Environmental Health and Ecological Security, School of Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China;
2. School of Chemistry and Chemical Engineering, Institute for Energy Research, Jiangsu University, Zhenjiang 212013, China

收稿日期:2022-03-21 修回日期:2022-06-18 出版日期:2023-04-28 发布日期:2023-06-13
通讯作者: Minqiang He,E-mail:hemq@ujs.edu.cn;Wenshuai Zhu,E-mail:zhuws@ujs.edu.cn
基金资助:
We thank the financial support from National Natural Science Foundation of China (21808091 and 22178154). This work was also supported by the Student Innovation and Entrepreneurship Training Program (202210299640X).

One-pot in-situ synthesis of coralloid supported VO₂ catalyst for intensified aerobic oxidative desulfurization

Suhang Xun¹, Cancan Wu¹, Lida Tang², Mengmeng Yuan², Haofeng Chen², Minqiang He², Wenshuai Zhu², Huaming Li²

1. Institute of Environmental Health and Ecological Security, School of Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China;
2. School of Chemistry and Chemical Engineering, Institute for Energy Research, Jiangsu University, Zhenjiang 212013, China

Received:2022-03-21 Revised:2022-06-18 Online:2023-04-28 Published:2023-06-13
Contact: Minqiang He,E-mail:hemq@ujs.edu.cn;Wenshuai Zhu,E-mail:zhuws@ujs.edu.cn
Supported by:
We thank the financial support from National Natural Science Foundation of China (21808091 and 22178154). This work was also supported by the Student Innovation and Entrepreneurship Training Program (202210299640X).

摘要/Abstract

摘要： A coralloid 3D g-C₃N₄ supported VO₂ catalyst was successfully synthesized in-situ by one-pot method, avoiding the agglomeration of VO₂ during the reaction. The morphological and compositional information of the supported catalyst were investigated detailedly. 30% VO₂/3D g-C₃N₄ revealed excellent catalytic activity in aerobic oxidative desulfurization, the oxidative of dibenzothiophene (DBT), 4-methyldibenzothiophene (4-MDBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT) reached 98.6%, 99% and 99.4%, respectively, under the same mild conditions. The recycling performance and the mechanism on the oxidative of DBT were studied as well.

关键词: Alzheimer’s disease, Amyloid-b protein, Protein aggregation, Chirality, Inhibitor, Heptapeptide

Abstract: A coralloid 3D g-C₃N₄ supported VO₂ catalyst was successfully synthesized in-situ by one-pot method, avoiding the agglomeration of VO₂ during the reaction. The morphological and compositional information of the supported catalyst were investigated detailedly. 30% VO₂/3D g-C₃N₄ revealed excellent catalytic activity in aerobic oxidative desulfurization, the oxidative of dibenzothiophene (DBT), 4-methyldibenzothiophene (4-MDBT) and 4,6-dimethyldibenzothiophene (4,6-DMDBT) reached 98.6%, 99% and 99.4%, respectively, under the same mild conditions. The recycling performance and the mechanism on the oxidative of DBT were studied as well.

Key words: Alzheimer’s disease, Amyloid-b protein, Protein aggregation, Chirality, Inhibitor, Heptapeptide

Suhang Xun, Cancan Wu, Lida Tang, Mengmeng Yuan, Haofeng Chen, Minqiang He, Wenshuai Zhu, Huaming Li. One-pot in-situ synthesis of coralloid supported VO₂ catalyst for intensified aerobic oxidative desulfurization[J]. 中国化学工程学报, 2023, 56(4): 136-140.

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One-pot in-situ synthesis of coralloid supported VO₂ catalyst for intensified aerobic oxidative desulfurization

One-pot in-situ synthesis of coralloid supported VO₂ catalyst for intensified aerobic oxidative desulfurization

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