Recent development of catalytic strategies for sustainable ammonia production

doi:10.1016/j.cjche.2023.03.028

中国化学工程学报 ›› 2023, Vol. 62 ›› Issue (10): 65-113.DOI: 10.1016/j.cjche.2023.03.028

Recent development of catalytic strategies for sustainable ammonia production

Supeng Yu^1,2, Ting Xiang³, Njud S. Alharbi⁴, Bothaina A. Al-aidaroos⁴, Changlun Chen^1,3

1. Institute of Plasma Physics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China;
2. University of Science and Technology of China, Hefei 230026, China;
3. Institute of Energy, Hefei Comprehensive National Science Center (Anhui Energy Laboratory), Hefei 230000, China;
4. Department of Biological Sciences, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia

收稿日期:2022-11-07 修回日期:2023-03-04 出版日期:2023-10-28 发布日期:2023-12-23
通讯作者: Changlun Chen,E-mail:clchen@ipp.ac.cn
基金资助:
Financial supports from the National Natural Science Foundation of China (22276194), Institute of Energy of Hefei comprehensive National Science Center (21KZZ501 and 21KZS201), and the Presidential Foundation of Hefei Institutes of Physical Science, Chinese Academy of Sciences (YZJJZX202019). This work was funded by the Deanship of Scientific Research (DSR), King Abdulaziz University, Jeddah, Saudi Arabia under grant (KEP-PhD: 65-247-1443). The authors, therefore, acknowledge with thanks DSR technical and financial support.

Recent development of catalytic strategies for sustainable ammonia production

Supeng Yu^1,2, Ting Xiang³, Njud S. Alharbi⁴, Bothaina A. Al-aidaroos⁴, Changlun Chen^1,3

1. Institute of Plasma Physics, HFIPS, Chinese Academy of Sciences, Hefei 230031, China;
2. University of Science and Technology of China, Hefei 230026, China;
3. Institute of Energy, Hefei Comprehensive National Science Center (Anhui Energy Laboratory), Hefei 230000, China;
4. Department of Biological Sciences, Faculty of Science, King Abdulaziz University, Jeddah 21589, Saudi Arabia

Received:2022-11-07 Revised:2023-03-04 Online:2023-10-28 Published:2023-12-23
Contact: Changlun Chen,E-mail:clchen@ipp.ac.cn
Supported by:
Financial supports from the National Natural Science Foundation of China (22276194), Institute of Energy of Hefei comprehensive National Science Center (21KZZ501 and 21KZS201), and the Presidential Foundation of Hefei Institutes of Physical Science, Chinese Academy of Sciences (YZJJZX202019). This work was funded by the Deanship of Scientific Research (DSR), King Abdulaziz University, Jeddah, Saudi Arabia under grant (KEP-PhD: 65-247-1443). The authors, therefore, acknowledge with thanks DSR technical and financial support.

摘要/Abstract

摘要： Presently, ammonia is an ideal candidate for future clean energy. The Haber-Bosch process has been an essential ammonia production process, and it is one of the most important technological advancements since its invention, sustaining the explosive growth of military munitions industry and fertilizers in the first half of the 20th century. However, the process is facing great challenges: the growing need for ammonia and the demands of environmental protection. High energy consumption and high CO₂ emissions greatly limit the application of the Haber-Bosch method, and increasing research efforts are devoted to “green” ammonia synthesis. Thermocatalytic, electrocatalytic, and photocatalytic ammonia production under mild conditions and the derived chemical looping and plasma ammonia production methods, have been widely developed. Electrocatalytic and photocatalytic methods, which use low fossil fuels, are naturally being considered as future directions for the development of ammonia production. Although their catalytic efficiency of ammonia generation is not yet sufficient to satisfy the actual demands, considerable progress has been made in terms of regulating structure and morphology of catalyst and improving preparation efficiency. The chemical looping approach of ammonia production differs from the thermocatalytic, electrocatalytic, and photocatalytic methods, and is the method of reusing raw materials. The plasma treatment approach alters the overall ammonia production approach and builds up a new avenue of development in combination with thermal, photocatalytic, and electrocatalytic methods as well. This review discusses several recent effective catalysts for different ammonia production methods and explores mechanisms as well as efficiency of these catalysts for catalytic N₂ fixation of ammonia.

关键词: Thermocatalytic ammonia production, Electrocatalytic, and photocatalytic ammonia production, Thermodynamics process, Electrochemistry, Multiphase reaction

Abstract: Presently, ammonia is an ideal candidate for future clean energy. The Haber-Bosch process has been an essential ammonia production process, and it is one of the most important technological advancements since its invention, sustaining the explosive growth of military munitions industry and fertilizers in the first half of the 20th century. However, the process is facing great challenges: the growing need for ammonia and the demands of environmental protection. High energy consumption and high CO₂ emissions greatly limit the application of the Haber-Bosch method, and increasing research efforts are devoted to “green” ammonia synthesis. Thermocatalytic, electrocatalytic, and photocatalytic ammonia production under mild conditions and the derived chemical looping and plasma ammonia production methods, have been widely developed. Electrocatalytic and photocatalytic methods, which use low fossil fuels, are naturally being considered as future directions for the development of ammonia production. Although their catalytic efficiency of ammonia generation is not yet sufficient to satisfy the actual demands, considerable progress has been made in terms of regulating structure and morphology of catalyst and improving preparation efficiency. The chemical looping approach of ammonia production differs from the thermocatalytic, electrocatalytic, and photocatalytic methods, and is the method of reusing raw materials. The plasma treatment approach alters the overall ammonia production approach and builds up a new avenue of development in combination with thermal, photocatalytic, and electrocatalytic methods as well. This review discusses several recent effective catalysts for different ammonia production methods and explores mechanisms as well as efficiency of these catalysts for catalytic N₂ fixation of ammonia.

Key words: Thermocatalytic ammonia production, Electrocatalytic, and photocatalytic ammonia production, Thermodynamics process, Electrochemistry, Multiphase reaction

Supeng Yu, Ting Xiang, Njud S. Alharbi, Bothaina A. Al-aidaroos, Changlun Chen. Recent development of catalytic strategies for sustainable ammonia production[J]. 中国化学工程学报, 2023, 62(10): 65-113.

Supeng Yu, Ting Xiang, Njud S. Alharbi, Bothaina A. Al-aidaroos, Changlun Chen. Recent development of catalytic strategies for sustainable ammonia production[J]. Chinese Journal of Chemical Engineering, 2023, 62(10): 65-113.

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Recent development of catalytic strategies for sustainable ammonia production

Recent development of catalytic strategies for sustainable ammonia production

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