Fabrication of Sb-based alloys/carbon nanofibers with uniform dispersion as anode material for high efficiency sodium storage

doi:10.1016/j.cjche.2025.03.017

中国化学工程学报 ›› 2025, Vol. 83 ›› Issue (7): 208-216.DOI: 10.1016/j.cjche.2025.03.017

Fabrication of Sb-based alloys/carbon nanofibers with uniform dispersion as anode material for high efficiency sodium storage

Zhe Wang¹, Zhengpeng Zhu¹, Kai Xue¹, Xingmei Guo¹, Yuanjun Liu¹, Xiangjun Zheng¹, Qianqian Fan¹, Zhongyao Duan¹, Qinghong Kong², Junhao Zhang^1,

1 School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2 School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China

收稿日期:2024-11-11 修回日期:2025-02-26 接受日期:2025-03-05 出版日期:2025-07-28 发布日期:2025-07-28
通讯作者: Qianqian Fan,E-mail:fqq@just.edu.cn;Junhao Zhang,E-mail:jhzhang6@just.edu.cn
基金资助:
The work was financially supported by National Natural Science Foundation of China (22379056, 22479065), Industry foresight and common key technology research in Carbon Peak and Carbon Neutrality Special Project from Zhenjiang city (CG2023003), Industry-University-Research Cooperation Project of Jiangsu Province (BY20230347), and the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (24KJB150008).

Fabrication of Sb-based alloys/carbon nanofibers with uniform dispersion as anode material for high efficiency sodium storage

Zhe Wang¹, Zhengpeng Zhu¹, Kai Xue¹, Xingmei Guo¹, Yuanjun Liu¹, Xiangjun Zheng¹, Qianqian Fan¹, Zhongyao Duan¹, Qinghong Kong², Junhao Zhang^1,

1 School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2 School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China

Received:2024-11-11 Revised:2025-02-26 Accepted:2025-03-05 Online:2025-07-28 Published:2025-07-28
Contact: Qianqian Fan,E-mail:fqq@just.edu.cn;Junhao Zhang,E-mail:jhzhang6@just.edu.cn
Supported by:
The work was financially supported by National Natural Science Foundation of China (22379056, 22479065), Industry foresight and common key technology research in Carbon Peak and Carbon Neutrality Special Project from Zhenjiang city (CG2023003), Industry-University-Research Cooperation Project of Jiangsu Province (BY20230347), and the Natural Science Foundation of the Jiangsu Higher Education Institutions of China (24KJB150008).

摘要/Abstract

摘要： To solve the serious volume expansion problem of Sb-based anode materials in the alloying/dealloying process, a strategy combining electrospinning and hydrogen reduction is proposed to prepare a series of Sb-based alloys/carbon nanofiber composites (SbM/CNFs, M = Co, Zn, Ni). Inactive elements are innovatively introduced to form Sb based alloys with enhanced stability. The results show that the content of SbCo nanoparticles is high to 69.12% (mass), which are uniformly dispersed in carbon fibers. When evaluated as anode material for SIBs, SbCo/CNFs anode exhibits excellent sodium storage capacity, the initial discharge capacity is 580.0 mA h·g^-1 at 0.1 A g^-1, which can hold 483.5 mA h·g^-1 after 100 cycles. Even the current density increases to 1.0 A g^-1, the specific capacity still maintains at 344.5 mA h·g^-1 after 150 cycles. The improved sodium storage capacity is attributed to the synergistic effect of conductive carbon fibers and SbCo nanoparticles with uniform dispersion, which not only provide excellent electronic conductivity, but also enhance structural stability to reduce volume change.

关键词: Electrospinning, Sb based alloy, Sodium ion batteries, Electrochemistry, Kinetics, Composites

Abstract: To solve the serious volume expansion problem of Sb-based anode materials in the alloying/dealloying process, a strategy combining electrospinning and hydrogen reduction is proposed to prepare a series of Sb-based alloys/carbon nanofiber composites (SbM/CNFs, M = Co, Zn, Ni). Inactive elements are innovatively introduced to form Sb based alloys with enhanced stability. The results show that the content of SbCo nanoparticles is high to 69.12% (mass), which are uniformly dispersed in carbon fibers. When evaluated as anode material for SIBs, SbCo/CNFs anode exhibits excellent sodium storage capacity, the initial discharge capacity is 580.0 mA h·g^-1 at 0.1 A g^-1, which can hold 483.5 mA h·g^-1 after 100 cycles. Even the current density increases to 1.0 A g^-1, the specific capacity still maintains at 344.5 mA h·g^-1 after 150 cycles. The improved sodium storage capacity is attributed to the synergistic effect of conductive carbon fibers and SbCo nanoparticles with uniform dispersion, which not only provide excellent electronic conductivity, but also enhance structural stability to reduce volume change.

Key words: Electrospinning, Sb based alloy, Sodium ion batteries, Electrochemistry, Kinetics, Composites

Zhe Wang, Zhengpeng Zhu, Kai Xue, Xingmei Guo, Yuanjun Liu, Xiangjun Zheng, Qianqian Fan, Zhongyao Duan, Qinghong Kong, Junhao Zhang. Fabrication of Sb-based alloys/carbon nanofibers with uniform dispersion as anode material for high efficiency sodium storage[J]. 中国化学工程学报, 2025, 83(7): 208-216.

参考文献

[1] X.M. Guo, S.J. Liu, X.H. Wan, J.H. Zhang, Y.J. Liu, X.J. Zheng, Q.H. Kong, Z. Jin, Controllable solid-phase fabrication of an Fe₂O₃/Fe₅C₂/Fe-N-C electrocatalyst toward optimizing the oxygen reduction reaction in zinc-air batteries, Nano Lett. 22(12) (2022) 4879-4887.
[2] T. Zhang, D.S. Yuan, Q. Guo, F.X. Qiu, D.Y. Yang, Z.P. Ou, Preparation of a renewable biomass carbon aerogel reinforced with sisal for oil spillage clean-up: inspired by green leaves to green Tofu, Food Bioprod. Process. 114(2019) 154-162.
[3] H.S. Mao, S.S. Yang, Y.J. Yang, J.Y. Yang, G.Z. Yuan, M.T. Zheng, H. Hu, Y.R. Liang, X.Y. Yu, Hybrid catalyst-assisted synthesis of multifunctional carbon derived from Camellia shell for high-performance sodium-ion batteries and sodiumion hybrid capacitors, Carbon Neutralization 3(4) (2024) 673-688.
[4] Z.Z. Wang, J.F. Ni, L. Li, Gradient designs for efficient sodium batteries, ACS Energy Lett. 7(11) (2022) 4106-4117.
[5] Q. Cu, C.Q. Shang, G.F. Zhou, X. Wang, From micro to macro: freestanding electrode based on low crystalline Cu_2-xSe for sodium storage, Appl. Surf. Sci. 605(2022) 154780.
[6] Q. Cu, C.Q. Shang, G.F. Zhou, X. Wang, “Grafting” NiSe onto Cu_2-xSe with twinborn structure embedded in carbon-based nanofibers to weave freestanding sodiumion storage electrode, J. Colloid Interface Sci. 647(2023) 287-295.
[7] Q. Cu, C. Shang, G. Zhou, X. Wang, Rational design of freestanding necklacelike ZnSe with double N-doped carbon layer protection for efficient sodium storage, Mater. Today Chem. 25(2022) 100976.
[8] Y.C. Dou, L.L. Zhao, Y. Liu, Z.D. Zhang, Y.M. Zhang, R.F. Li, X.Q. Liu, Y. Zhou, J.Z. Wang, J. Wang, High-abundance and low-cost anodes for sodium-ion batteries, Carbon Neutralization 3(6) (2024) 954-995.
[9] A. Nazir, H.T.T. Le, A.G. Nguyen, J. Kim, C.J. Park, Conductive metal organic framework mediated Sb nanoparticles as high-capacity anodes for rechargeable potassium-ion batteries, Chem. Eng. J. 450(2022) 138408.
[10] L. Zhou, Z. Cao, J. Zhang, H. Cheng, G. Liu, G.T. Park, L. Cavallo, L.M. Wang, H.N. Alshareef, Y.K. Sun, J. Ming, Electrolyte-mediated stabilization of highcapacity micro-sized antimony anodes for potassium-ion batteries, Adv. Mater. 33(8) (2021) e2005993.
[11] M.G. Xie, C.G. Li, S.Y. Ren, Y. Ma, X.B. Chen, X.F. Fan, Y. Han, Z. Shi, S.H. Feng, Ultrafine Sb nanoparticles in situ confined in covalent organic frameworks for high-performance sodium-ion battery anodes, J. Mater. Chem. A 10(28) (2022) 15089-15100.
[12] T.L. Zhang, M.R. Wu, H. Gu, H.W. Yu, M. Zhou, X.M. Guo, Y.J. Liu, X.J. Zheng, Q. H. Kong, J.H. Zhang, Double carbon modified CoS₂/NiS₂ as anode material for efficient lithium storage performance, J. Energy Storage 73(2023) 108981.
[13] H.S. Hou, M.J. Jing, Y.C. Yang, Y. Zhang, Y.R. Zhu, W.X. Song, X.M. Yang, X.B. Ji, Sb porous hollow microspheres as advanced anode materials for sodium-ion batteries, J. Mater. Chem. A 3(6) (2015) 2971-2977.
[14] H. Gao, J. Lee, Q. Lu, Y. Kim, K.H. Shin, H.S. Park, Z. Zhang, L.Y.S. Lee, Highly stable Sb/C anode for K+ and Na+ energy storage enabled by pulsed laser ablation and polydopamine coating, Small 19(4) (2023) e2205681.
[15] P.X. Xiong, J.X. Wu, M.F. Zhou, Y.H. Xu, Bismuth-antimony alloy Nanoparticle@ Porous carbon nanosheet composite anode for high-performance potassiumion batteries, ACS Nano 14(1) (2020) 1018-1026.
[16] D.K. Yu, C.M. Park, Sb-based intermetallics and nanocomposites as stable and fast Na-ion battery anodes, Chem. Eng. J. 409(2021) 127380.
[17] B.X. Peng, S.M. Xu, Z.R. Lv, S.N. Zhang, Y.S. Gao, T.Q. Lin, F.Q. Huang, Toward extremely fast charging through boosting intercalative redox pseudocapacitance: a SbCrSe₃ anode for large and fast sodium storage, Adv. Energy Mater. 13(2) (2023) 2203187.
[18] X.X. Wang, B. Feng, L.M. Huang, Q.F. Fu, W.Z. Li, C. Zhu, P. Chen, C.L. Yang, Y.L. Ding, Superior electrochemical performance of SbeBi alloy for sodium storage: understanding from alloying element effects and new cause of capacity attenuation, J. Power Sources 520(2022) 230826.
[19] X. Zhong, J.M. Duan, Y.E. Xiang, X.Y. Hu, Y.J. Huang, Y.J. Li, W.T. Deng, G.Q. Zou, H.S. Hou, X.B. Ji, Constructing rich interfacial structure by carbon dots to improve the sodium storage capacity of Sb/C composite, Adv. Funct. Mater. 33(52) (2023) 2306574.
[20] G.J. Cui, H. Wang, F.P. Yu, H.Y. Che, X.Z. Liao, L.S. Li, W.M. Yang, Z.F. Ma, Scalable synthesis of Na₃V₂(PO₄)₃/C with high safety and ultrahigh-rate performance for sodium-ion batteries, Chin. J. Chem. Eng. 46(2022) 280-286.
[21] S. Sarkar, A. Chaupatnaik, S.D. Ramarao, U. Subbarao, P. Barpanda, S.C. Peter, Operando sodiation mechanistic study of a new antimony-based intermetallic CoSb as a high-performance sodium-ion battery anode, J. Phys. Chem. C 124(29) (2020) 15757-15768.
[22] X.M. Zheng, J.H. You, J.J. Fan, G.P. Tu, W.Q. Rong, W.J. Li, Y.X. Wang, S. Tao, P.Y. Zhang, S.Y. Zhang, S.Y. Shen, J.T. Li, L. Huang, S.G. Sun, Electrodeposited binder-free Sb/NiSb anode of sodium-ion batteries with excellent cycle stability and rate capability and new insights into its reaction mechanism by operando XRD analysis, Nano Energy 77(2020) 105123.
[23] X.Y. Fan, J.X. Han, Y. Jiang, J.F. Ni, L. Gou, D.L. Li, L. Li, Hierarchical porous Sb films on 3D Cu substrate have promise for stable sodium storage, ACS Appl. Energy Mater. 1(8) (2018) 3598-3602.
[24] H.W. Yu, M.Y. Gao, M. Zhou, H. Gu, X.J. Zheng, X.M. Guo, Y.J. Liu, F. Cao, Q.H. Kong, J.H. Zhang, F127/PDA dual-assisted fabricating high dispersed Ge nanoparticles/N-doped porous carbon composites with efficient lithium storage, J. Mater. Res. Technol. 26(2023) 5055-5064.
[25] Y.F. Zhao, K. Xue, X.Y. Liu, Z.Y. Gao, J.H. Zhang, Y.J. Liu, X.J. Zheng, Z.Y. Duan, Q. Q. Fan, X.M. Guo, Sb nanoparticles embedded uniformly on the surface of porous carbon fibres for high-efficiency sodium storage, Chem. Commun. 60(91) (2024) 13428-13431.
[26] T.L. Zhang, P.F. Yu, X.M. Guo, Y.J. Liu, X.J. Zheng, Z.Y. Duan, Q.Q. Fan, F. Cao, C.S. Li, Q.H. Kong, J.H. Zhang, Co2P/CoP embedded in N, P, S triply-doped hollow carbon towards enhanced oxygen electrocatalysis, J. Colloid Interface Sci. 679(Pt A) (2025) 273-281.
[27] Q.Q. Wu, Y.T. Zhong, R.M. Chen, G.Y. Ling, X.H. Wang, Y.R. Shen, C. Hao, Cu-AgC@Ni₃S₄ with core shell structure and rose derived carbon electrode materials: an environmentally friendly supercapacitor with high energy and power density, Ind. Crops Prod. 222(2024) 119676.
[28] M. Zhou, M.R. Wu, H.W. Yu, X.J. Zheng, K. Shen, X.M. Guo, Y.J. Liu, F. Cao, H.X. Gu, Q.H. Kong, J.H. Zhang, Controllable fabrication of FeCoS₄ nanoparticles/Sdoped bowl-shaped hollow carbon as efficient lithium storage anode, Chin. J. Chem. Eng. 67(2024) 78-88.
[29] X.K. Wang, Y. Pan, X.H. Wang, Y.N. Guo, C.H. Ni, J.B. Wu, C. Hao, High performance hybrid supercapacitors assembled with multi-cavity nickel cobalt sulfide hollow microspheres as cathode and porous typha-derived carbon as anode, Ind. Crops Prod. 189(2022) 115863.
[30] Z.H. Yang, W.B. Li, G.N. Zhang, J.J. Wang, J.X. Zuo, Q. Xu, H. Shan, X.F. He, M.F. Lv, J.H. Hu, W. Huang, J.J. Zhang, X.F. Li, Constructing SbOC bond to improve the alloying reaction reversibility of free-standing Sb₂Se₃ nanorods for potassium-ion batteries, Nano Energy 93(2022) 106764.
[31] R. Verma, A.G. Nguyen, P.N. Didwal, C.E. Moon, J. Kim, C.J. Park, In-situ synthesis of antimony nanoparticles encapsulated in nitrogen-doped porous carbon framework as high performance anode material for potassium-ion batteries, Chem. Eng. J. 446(2022) 137302.
[32] X.F. Zhou, F.F. Liu, Y.J. Wang, Y. Yao, Y. Shao, X.H. Rui, F.X. Wu, Y. Yu, Heterogeneous interfacial layers derived from the in situ reaction of CoF₂ nanoparticles with sodium metal for dendrite-free Na metal anodes, Adv. Energy Mater. 12(42) (2022) 2202323.
[33] H. Dong, X.H. Shao, S. Hancox, S.T. McBeath, W.A. Tarpeh, M.R. Hoffmann, Understanding the catalytic active sites of crystalline CoSbxOy for electrochemical chlorine evolution, ACS Appl. Mater. Interfaces 15(34) (2023) 40369-40377.
[34] X.M. Guo, J. Shi, M. Li, J.H. Zhang, X.J. Zheng, Y.J. Liu, B.J. Xi, X.G. An, Z.Y. Duan, Q.Q. Fan, F. Gao, S.L. Xiong, Modulating coordination of iron atom clusters on N, P, S triply-doped hollow carbon support towards enhanced electrocatalytic oxygen reduction, Angew. Chem. Int. Ed. 62(49) (2023) e202314124.
[35] A.D. Xu, M.Y. Huang, C.X. Liu, T. Li, X. Li, S.P. Wu, Z.G. Xu, Y.R. Yan, Constructing high-content Sb atomic clusters and robust SbeOeC bond in Sb/C composites for ultrahigh rate and long-term sodium storage, Adv. Funct. Mater. 34(33) (2024) 2400302.
[36] Q.H. Li, W. Zhang, J. Peng, W. Zhang, Z.X. Liang, J.W. Wu, J.J. Feng, H.X. Li, S.M. Huang, Metal-organic framework derived ultrafine Sb@Porous carbon octahedron via in situ substitution for high-performance sodium-ion batteries, ACS Nano 15(9) (2021) 15104-15113.
[37] N. Zhang, X.J. Chen, J.J. Zhao, P.F. He, X.L. Ding, Mass produced Sb/P@C composite nanospheres for advanced sodium-ions battery anodes, Electrochim. Acta 439(2023) 141602.
[38] Q. Lai, B.C. Yin,Y.Dou, Q. Zhang, Y.H.Zhu,Y.K. Yang, Electrospun carbon nanofibersupported V₂O₃ with enriched oxygen vacancies as a free-standing high-rate anode for an all-vanadium-based full battery, Carbon Energy 6(9) (2024) e517.
[39] T. Yuan, S.Q. Li, Y.Y. Sun, J.H. Wang, A.J. Chen, Q.F. Zheng, Y.X. Zhang, L.W. Chen, G. Nam, H.Y. Che, J.H. Yang, S.Y. Zheng, Z.F. Ma, M.L. Liu, A high-rate, durable cathode for sodium-ion batteries: Sb-doped O₃ -Type Ni/Mn-based layered oxides, ACS Nano 16(11) (2022) 18058-18070.
[40] J. Yang, J.B. Li, T.Y. Wang, P.H.L. Notten, H. Ma, Z.G. Liu, C.Y. Wang, G.X. Wang, Novel hybrid of amorphous Sb/N-doped layered carbon for high-performance sodium-ion batteries, Chem. Eng. J. 407(2021) 127169.
[41] J.J. Tian, H. Yang, C.M. Fu, M.L. Sun, L.N. Wang, T.X. Liu, In-situ synthesis of microspherical Sb@C composite anode with high tap density for lithium/ sodium-ion batteries, Compos. Commun. 17(2020) 177-181.
[42] H.J. Liu, Z.J. Wang, Z.H. Wu, S. Zhang, S.H. Ge, P. Guo, M.L. Hua, X.Q. Lu, S.T. Wang, J. Zhang, Direct tuning of meso-/micro-porous structure of carbon nanofibers confining Sb nanocrystals for advanced sodium and potassium storage, J. Alloys Compd. 833(2020) 155127.
[43] X.Y. Li, J.K. Qu, H.W. Xie, Q.S. Song, G.F. Fu, H.Y. Yin, An electro-deoxidation approach to co-converting antimony oxide/graphene oxide to antimony/ graphene composite for sodium-ion battery anode, Electrochim. Acta 332(2020) 135501.
[44] C. Liu, X. Fu, S.Z. Liao, G.Q. Zou, H. Yang, Interface engineering enables highperformance Sb anode for sodium storage, Nanomaterials 13(2) (2023) 254.
[45] S. Arnold, A. Gentile, Y.J. Li, Q.S. Wang, S. Marchionna, R. Ruffo, V. Presser, Design of high-performance antimony/MXene hybrid electrodes for sodiumion batteries, J. Mater. Chem. A 10(19) (2022) 10569-10585.
[46] X.Y. Li, J.K. Qu, Z.J. Hu, H.W. Xie, H.Y. Yin, Electrochemically converting Sb₂S₃/ CNTs to Sb/CNTs composite anodes for sodium-ion batteries, Int. J. Hydrogen Energy 46(33) (2021) 17071-17083.
[47] C. Liu, F.X. Zeng, L. Xu, S.Y. Liu, J.C. Liu, X.P. Ai, H.X. Yang, Y.L. Cao, Enhanced cycling stability of antimony anode by downsizing particle and combining carbon nanotube for high-performance sodium-ion batteries, J. Mater. Sci. Technol. 55(2020) 81-88.
[48] Y.W. Liu, J.W. Shi, M.F. Su, F. Gao, Q.Y. Lu, Constructing inverse opal antimony@carbon frameworks with multi-level porosity towards high performance sodium storage, J. Alloys Compd. 914(2022) 165335.
[49] H. Gu, M.Y. Gao, K. Shen, T.L. Zhang, J.H. Zhang, X.J. Zheng, X.M. Guo, Y.J. Liu, F. Cao, H.X. Gu, Q.H. Kong, S.L. Xiong, F127 assisted fabrication of Ge/rGO/CNTs nanocomposites with three-dimensional network structure for efficient lithium storage, Chin. Chem. Lett. 35(9) (2024) 109273.
[50] M.Y. Gao, Y.C. Xue, Y.T. Zhang, C.X. Zhu, H.W. Yu, X.M. Guo, S.S. Sun, S.L. Xiong, Q.H. Kong, J.H. Zhang, Growing CoeNieSe nanosheets on 3D carbon frameworks as advanced dual functional electrodes for supercapacitors and sodium ion batteries, Inorg. Chem. Front. 9(15) (2022) 3933-3942.
[51] H.W. Yu, Y.F. Zhao, J.H. Zhang, Y.J. Liu, X.J. Zheng, Q.Q. Fan, Z.Y. Duan, X.M. Guo, Coordination regulation strategy in fabricating Bi₂S₃@CNFs composites with uniform dispersion for robust sodium storage, Inorg. Chem. 63(45) (2024) 21441-21449.

Fabrication of Sb-based alloys/carbon nanofibers with uniform dispersion as anode material for high efficiency sodium storage

Fabrication of Sb-based alloys/carbon nanofibers with uniform dispersion as anode material for high efficiency sodium storage

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