Evolution of copper nanowires through coalescing of copper nanoparticles induced by aliphatic amines and their electrical conductivities in polyester films

doi:10.1016/j.cjche.2021.03.003

中国化学工程学报 ›› 2022, Vol. 44 ›› Issue (4): 284-291.DOI: 10.1016/j.cjche.2021.03.003

Evolution of copper nanowires through coalescing of copper nanoparticles induced by aliphatic amines and their electrical conductivities in polyester films

Mingxia Tian, Aili Wang, Hengbo Yin

Faculty of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China

收稿日期:2020-11-15 修回日期:2021-03-03 出版日期:2022-04-28 发布日期:2022-06-18
通讯作者: Aili Wang,E-mail:alwang@ujs.edu.cn;Hengbo Yin,E-mail:yin@ujs.edu.cn
基金资助:
This work was financially supported by the fund from the Jiangsu Science and Technology Department, China (FZ20180919). We also sincerely thank Dr. Kangmin Chen for his helpful support on TEM and HRTEM analyses.

Evolution of copper nanowires through coalescing of copper nanoparticles induced by aliphatic amines and their electrical conductivities in polyester films

Mingxia Tian, Aili Wang, Hengbo Yin

Faculty of Chemistry and Chemical Engineering, Jiangsu University, Zhenjiang 212013, China

Received:2020-11-15 Revised:2021-03-03 Online:2022-04-28 Published:2022-06-18
Contact: Aili Wang,E-mail:alwang@ujs.edu.cn;Hengbo Yin,E-mail:yin@ujs.edu.cn
Supported by:
This work was financially supported by the fund from the Jiangsu Science and Technology Department, China (FZ20180919). We also sincerely thank Dr. Kangmin Chen for his helpful support on TEM and HRTEM analyses.

摘要/Abstract

摘要： Copper nanowires were synthesized by the wet chemical reduction method using copper sulfate as the copper precursor, aliphatic amines (methylamine, ethanediamine, 1,2-propanediamine) as the inducing reagents, and hydrazine hydrate as the reductant through the aging and reduction processes. The high-resolution transmission electron microscopy (HRTEM) images reveal that the copper nanowires were synthesized by coalescing extremely small-sized copper nanoparticles with the particle sizes of 1–6 nm in copper complex micelles. A longer aging time period favored the coalescing of the copper nanoparticles to form thinner copper nanowires in the following reduction process. The coalescing extent of copper nanoparticles in copper nanowires was highly enhanced by ethanediamine and 1,2-propanediamine as compared with that by methylamine. The copper nanowire-filled polyester films had higher electrical conductivity than the copper nanoparticle-filled ones.

关键词: Nanomaterials, Nanostructure, Electronic materials, Copper nanowires, Electrical conductivity, Polyester film

Abstract: Copper nanowires were synthesized by the wet chemical reduction method using copper sulfate as the copper precursor, aliphatic amines (methylamine, ethanediamine, 1,2-propanediamine) as the inducing reagents, and hydrazine hydrate as the reductant through the aging and reduction processes. The high-resolution transmission electron microscopy (HRTEM) images reveal that the copper nanowires were synthesized by coalescing extremely small-sized copper nanoparticles with the particle sizes of 1–6 nm in copper complex micelles. A longer aging time period favored the coalescing of the copper nanoparticles to form thinner copper nanowires in the following reduction process. The coalescing extent of copper nanoparticles in copper nanowires was highly enhanced by ethanediamine and 1,2-propanediamine as compared with that by methylamine. The copper nanowire-filled polyester films had higher electrical conductivity than the copper nanoparticle-filled ones.

Key words: Nanomaterials, Nanostructure, Electronic materials, Copper nanowires, Electrical conductivity, Polyester film

Mingxia Tian, Aili Wang, Hengbo Yin. Evolution of copper nanowires through coalescing of copper nanoparticles induced by aliphatic amines and their electrical conductivities in polyester films[J]. 中国化学工程学报, 2022, 44(4): 284-291.

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Evolution of copper nanowires through coalescing of copper nanoparticles induced by aliphatic amines and their electrical conductivities in polyester films

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