SCI和EI收录∣中国化工学会会刊

中国化学工程学报 ›› 2022, Vol. 44 ›› Issue (4): 377-383.DOI: 10.1016/j.cjche.2021.04.021

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Boosting low-temperature selective catalytic reduction of NO with NH3 of V2O5/TiO2 catalyst via B-doping

Hanghang Li1, Wei Zhao1, Licheng Wu1, Qian Wang1, Danhong Shang2, Qin Zhong3   

  1. 1 School of Energy & Power Engineering, Jiangsu University, Zhenjiang 212013, China;
    2 School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
    3 School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
  • 收稿日期:2020-12-31 修回日期:2021-03-29 出版日期:2022-04-28 发布日期:2022-06-18
  • 通讯作者: Wei Zhao,E-mail:wzhao@ujs.edu.cn;Qian Wang,E-mail:qwang@ujs.edu.cn
  • 基金资助:
    This research was funded by the National Natural Science Foundation of China (51506077), the Natural Science Foundation of Jiangsu Province (BK20150488), the Natural Science Foundation of Jiangsu High School (15KJB430007) and the Research Foundation of Jiangsu University (15JDG156).

Boosting low-temperature selective catalytic reduction of NO with NH3 of V2O5/TiO2 catalyst via B-doping

Hanghang Li1, Wei Zhao1, Licheng Wu1, Qian Wang1, Danhong Shang2, Qin Zhong3   

  1. 1 School of Energy & Power Engineering, Jiangsu University, Zhenjiang 212013, China;
    2 School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
    3 School of Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
  • Received:2020-12-31 Revised:2021-03-29 Online:2022-04-28 Published:2022-06-18
  • Contact: Wei Zhao,E-mail:wzhao@ujs.edu.cn;Qian Wang,E-mail:qwang@ujs.edu.cn
  • Supported by:
    This research was funded by the National Natural Science Foundation of China (51506077), the Natural Science Foundation of Jiangsu Province (BK20150488), the Natural Science Foundation of Jiangsu High School (15KJB430007) and the Research Foundation of Jiangsu University (15JDG156).

摘要: A series of B-doped V2O5/TiO2 catalysts has been prepared the by sol-gel and impregnation methods to investigate the influence of B-doping on the selective catalytic reduction (SCR) of NOx with NH3. X-ray diffraction, Brunauer-Emmett-Teller specific surface area, scanning electron microscope, X-ray photoelectron spectroscopy, temperature-programmed reduction of H2 and temperature-programmed desorption of NH3 technology were used to study the effect of the B-doping on the structure and NH3-SCR activity of V2O5/TiO2 catalysts. The experimental results demonstrated that the introduction of B not only improved the low-temperature SCR activity of the catalysts, but also broadened the activity temperature window. The best SCR activity in the entire test temperature range is obtained for VTiB2.0 with 2.0% doping amount of B and the NOx conversion rate is up to 94.3% at 210 ℃. The crystal phase, specific surface area, valence state reducibility and surface acidity of the active components for the as-prepared catalysts are significantly affected by the B-doping, resulting in an improved NH3-SCR performance. These results suggest that the V2O5/TiO2 catalysts with an appropriate B content afford good candidates for SCR in the low temperature window.

关键词: B-doping, Catalyst, SCR, NOx, Support

Abstract: A series of B-doped V2O5/TiO2 catalysts has been prepared the by sol-gel and impregnation methods to investigate the influence of B-doping on the selective catalytic reduction (SCR) of NOx with NH3. X-ray diffraction, Brunauer-Emmett-Teller specific surface area, scanning electron microscope, X-ray photoelectron spectroscopy, temperature-programmed reduction of H2 and temperature-programmed desorption of NH3 technology were used to study the effect of the B-doping on the structure and NH3-SCR activity of V2O5/TiO2 catalysts. The experimental results demonstrated that the introduction of B not only improved the low-temperature SCR activity of the catalysts, but also broadened the activity temperature window. The best SCR activity in the entire test temperature range is obtained for VTiB2.0 with 2.0% doping amount of B and the NOx conversion rate is up to 94.3% at 210 ℃. The crystal phase, specific surface area, valence state reducibility and surface acidity of the active components for the as-prepared catalysts are significantly affected by the B-doping, resulting in an improved NH3-SCR performance. These results suggest that the V2O5/TiO2 catalysts with an appropriate B content afford good candidates for SCR in the low temperature window.

Key words: B-doping, Catalyst, SCR, NOx, Support