Ca2MnO4-layered perovskite modified by NaNO3 for chemical-looping oxidative dehydrogenation of ethane to ethylene

doi:10.1016/j.cjche.2023.12.021

中国化学工程学报 ›› 2024, Vol. 68 ›› Issue (4): 53-64.DOI: 10.1016/j.cjche.2023.12.021

Ca₂MnO₄-layered perovskite modified by NaNO₃ for chemical-looping oxidative dehydrogenation of ethane to ethylene

Weixiao Ding^1,2,3, Kun Zhao², Shican Jiang^1,2, Zhen Huang², Fang He¹

1. College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541006, China;
2. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
3. School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

收稿日期:2023-09-25 修回日期:2023-11-30 出版日期:2024-04-28 发布日期:2024-06-28
通讯作者: Kun Zhao,E-mail address:zhaokun@ms.giec.ac.cn;Fang He,E-mail address:hefang@glut.edu.cn
基金资助:
The financial support of National Natural Science Foundation of China (22179027) is gratefully acknowledged. This work was also supported by the Natural Science Foundation of Guangxi Province (2021GXNSFAA075063, 2018GXNSFDA281005), and the National Key Research and Development Program of China (2017YFE0105500), Science & Technology Research Project of Guangdong Province (2017A020216009).

Ca₂MnO₄-layered perovskite modified by NaNO₃ for chemical-looping oxidative dehydrogenation of ethane to ethylene

Weixiao Ding^1,2,3, Kun Zhao², Shican Jiang^1,2, Zhen Huang², Fang He¹

1. College of Chemistry and Bioengineering, Guilin University of Technology, Guilin 541006, China;
2. Guangzhou Institute of Energy Conversion, Chinese Academy of Sciences, Guangzhou 510640, China;
3. School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China

Received:2023-09-25 Revised:2023-11-30 Online:2024-04-28 Published:2024-06-28
Contact: Kun Zhao,E-mail address:zhaokun@ms.giec.ac.cn;Fang He,E-mail address:hefang@glut.edu.cn
Supported by:
The financial support of National Natural Science Foundation of China (22179027) is gratefully acknowledged. This work was also supported by the Natural Science Foundation of Guangxi Province (2021GXNSFAA075063, 2018GXNSFDA281005), and the National Key Research and Development Program of China (2017YFE0105500), Science & Technology Research Project of Guangdong Province (2017A020216009).

摘要/Abstract

摘要： Chemical-looping oxidative dehydrogenation (CL-ODH) is a process designed for the conversion of alkanes into olefins through cyclic redox reactions, eliminating the need for gaseous O₂. In this work, we investigated the use of Ca₂MnO₄-layered perovskites modified with NaNO₃ dopants, serving as redox catalysts (also known as oxygen carriers), for the CL-ODH of ethane within a temperature range of 700-780 ℃. Our findings revealed that the incorporation of NaNO₃ as a modifier significantly enhanced the selectivity for ethylene generation from Ca₂MnO₄. At 750 ℃ and a gas hourly space velocity of 1300 h^-1, we achieved an ethane conversion up to 68.17%, accompanied by a corresponding ethylene yield of 57.39%. X-ray photoelectron spectroscopy analysis unveiled that the doping NaNO₃ onto Ca₂MnO₄ not only played a role in reducing the oxidation state of Mn ions but also increased the lattice oxygen content of the redox catalyst. Furthermore, formation of NaNO₃ shell on the surface of Ca₂MnO₄ led to a reduction in the concentration of manganese sites and modulated the oxygen-releasing behavior in a step-wise manner. This modulation contributed significantly to the enhanced selectivity for ethylene of the NaNO₃-doped Ca₂MnO₄ catalyst. These findings provide compelling evidence for the potential of Ca₂MnO₄-layered perovskites as promising redox catalysts in the context of CL-ODH reactions.

关键词: Chemical-looping oxidative dehydrogenation, Ethane, Ethylene, NaNO₃-doped Ca₂MnO₄ redox catalyst, Layered perovskites

Abstract: Chemical-looping oxidative dehydrogenation (CL-ODH) is a process designed for the conversion of alkanes into olefins through cyclic redox reactions, eliminating the need for gaseous O₂. In this work, we investigated the use of Ca₂MnO₄-layered perovskites modified with NaNO₃ dopants, serving as redox catalysts (also known as oxygen carriers), for the CL-ODH of ethane within a temperature range of 700-780 ℃. Our findings revealed that the incorporation of NaNO₃ as a modifier significantly enhanced the selectivity for ethylene generation from Ca₂MnO₄. At 750 ℃ and a gas hourly space velocity of 1300 h^-1, we achieved an ethane conversion up to 68.17%, accompanied by a corresponding ethylene yield of 57.39%. X-ray photoelectron spectroscopy analysis unveiled that the doping NaNO₃ onto Ca₂MnO₄ not only played a role in reducing the oxidation state of Mn ions but also increased the lattice oxygen content of the redox catalyst. Furthermore, formation of NaNO₃ shell on the surface of Ca₂MnO₄ led to a reduction in the concentration of manganese sites and modulated the oxygen-releasing behavior in a step-wise manner. This modulation contributed significantly to the enhanced selectivity for ethylene of the NaNO₃-doped Ca₂MnO₄ catalyst. These findings provide compelling evidence for the potential of Ca₂MnO₄-layered perovskites as promising redox catalysts in the context of CL-ODH reactions.

Key words: Chemical-looping oxidative dehydrogenation, Ethane, Ethylene, NaNO₃-doped Ca₂MnO₄ redox catalyst, Layered perovskites

Weixiao Ding, Kun Zhao, Shican Jiang, Zhen Huang, Fang He. Ca₂MnO₄-layered perovskite modified by NaNO₃ for chemical-looping oxidative dehydrogenation of ethane to ethylene[J]. 中国化学工程学报, 2024, 68(4): 53-64.

参考文献

[1] I. Amghizar, L.A. Vandewalle, K.M. Van Geem, G.B. Marin, New trends in olefin production, Engineering 3(2) (2017) 171-178.
[2] T. Ren, M. Patel, K. Blok, Olefins from conventional and heavy feedstocks: Energy use in steam cracking and alternative processes, Energy 31(4) (2006) 425-451.
[3] V.P. Haribal, Y. Chen, L. Neal, F.X. Li, Intensification of ethylene production from naphtha via a redox oxy-cracking scheme: Process simulations and analysis, Engineering 4(5) (2018) 714-721.
[4] A. Toghan, R. Arrigo, A. Knop-Gericke, R. Imbihl, Ambient pressure X-ray photoelectron spectroscopy during electrochemical promotion of ethylene oxidation over a bimetallic Pt-Ag/YSZ catalyst, J. Catal. 296(2012) 99-109.
[5] M.M. Bhasin, Is true ethane oxydehydrogenation feasible? Top. Catal. 23(1) (2003) 145-149.
[6] E.M. Thorsteinson, T.P. Wilson, F.G. Young, P.H. Kasai, The oxidative dehydrogenation of ethane over catalysts containing mixed oxides of molybdenum and vanadium, J. Catal. 52(1) (1978) 116-132.
[7] Y.L. Zhou, J. Lin, L. Li, M. Tian, X.Y. Li, X.L. Pan, Y. Chen, X.D. Wang, Improving the selectivity of Ni-Al mixed oxides with isolated oxygen species for oxidative dehydrogenation of ethane with nitrous oxide, J. Catal. 377(2019) 438-448.
[8] M. Hurtado Cotillo, D. Unsihuay, C.E. Santolalla-Vargas, A. Paredes Doig, R. Sun Kou, G. Picasso, Catalysts based on Ni-Fe oxides supported on γ-Al₂O₃ for the oxidative dehydrogenation of ethane, Catal. Today 356(2020) 312-321.
[9] P.B. Radstake, M. Roenning, A. Holmen, Influence of H₂ on the oxygen-assisted dehydrogenation of ethane over Al₂O₃-supported Pt-Sn catalysts, Catal. Lett. 148(4) (2018) 1055-1066.
[10] T.Q. Lei, Y.H. Cheng, C.X. Miao, W.M. Hua, Y.H. Yue, Z. Gao, Silica-doped TiO₂ as support of gallium oxide for dehydrogenation of ethane with CO₂, Fuel Process. Technol. 177(2018) 246-254.
[11] C.C. Liao, C.C. Chang, Y. Choi, M.K. Tsai, Ethane oxidative dehydrogenation mechanism on MoO₃(010) surface: A first-principle study using on-site Coulomb correction, Surf. Sci. 674(2018) 45-50.
[12] J.C. Vedrine, Metal oxides in heterogeneous oxidation catalysis: State of the art and challenges for a more sustainable world, ChemSusChem 12(3) (2019) 577-588.
[13] S.V. Mikhailovskii, N.A. Zhilyaeva, A.A. Obletsova, M.M. Ermilova, N.V. Orekhova, A.A. Malygin, A.B. Yaroslavtsev, Effect of the composition of (Mo, Nb, V, Ti)/γ-Al₂O₃ surface oxide structures on the oxidative dehydrogenation of ethane to ethylene, Russ. J. Appl. Chem. 89(1) (2016) 34-39.
[14] A.S.H. Kumar, K. Upendar, A. Qiao, P.S.N. Rao, N. Lingaiah, V.N. Kalevaru, A. Martin, C. Sailu, P.S.S. Prasad, Selective oxidative dehydrogenation of ethane over MoO₃/V₂O₅-Al₂O₃ catalysts: Heteropolymolybdate as a precursor for MoO₃, Catal. Commun. 33(2013) 76-79.
[15] K. Karim, A. Mamedov, M.H. Al-Hazmi, N. Al-Andis, Oxidative dehydrogenation of ethane over movmnw oxide catalysts, React. Kinet. Catal. Lett. 80(1) (2003) 3-11.
[16] D. Delgado, R. Sanchis, B. Solsona, P. Concepcion, J.M. Lopez Nieto, Influence of the nature of the promoter in NiO catalysts on the selectivity to olefin during the oxidative dehydrogenation of propane and ethane, Top. Catal. 63(19) (2020) 1731-1742.
[17] J.M. Lopez Nieto, P. Botella, M.I. Vazquez, A. Dejoz, The selective oxidative dehydrogenation of ethane over hydrothermally synthesised MoVTeNb catalysts, Chem. Commun. (17) (2002) 1906-1907.
[18] C.P. Kumar, S. Gaab, T.E. Muller, J.A. Lercher, Oxidative dehydrogenation of light alkanes on supported molten alkali metal chloride catalysts, Top. Catal. 50(1) (2008) 156-167.
[19] B. Tope, Y.Z. Zhu, J.A. Lercher, Oxidative dehydrogenation of ethane over Dy₂O₃/MgO supported LiCl containing eutectic chloride catalysts, Catal. Today 123(1-4) (2007) 113-121.
[20] B. Sarkar, R. Goyal, L.N. Sivakumar Konathala, C. Pendem, T. Sasaki, R. Bal, MoO₃ nanoclusters decorated on TiO₂ nanorods for oxidative dehydrogenation of ethane to ethylene, Appl. Catal. B Environ. 217(2017) 637-649.
[21] V.P. Haribal, L.M. Neal, F.X. Li, Oxidative dehydrogenation of ethane under a cyclic redox scheme-Process simulations and analysis, Energy 119(2017) 1024-1035.
[22] Y.F. Gao, L.M. Neal, F.X. Li, Li-promoted La_xSr_2-xFeO_4-δcore-shell redox catalysts for oxidative dehydrogenation of ethane under a cyclic redox scheme, ACS Catal. 6(11) (2016) 7293-7302.
[23] S. Yusuf, L.M. Neal, F.X. Li, Effect of promoters on manganese-containing mixed metal oxides for oxidative dehydrogenation of ethane via a cyclic redox scheme, ACS Catal. 7(8) (2017) 5163-5173.
[24] Y.F. Gao, L. Neal, D. Ding, W. Wu, C. Baroi, A.M. Gaffney, F.X. Li, Recent advances in intensified ethylene production-a review, ACS Catal. 9(9) (2019) 8592-8621.
[25] X.H. Zhang, C.L. Pei, X. Chang, S. Chen, R. Liu, Z.J. Zhao, R.T. Mu, J.L. Gong, FeO₆ octahedral distortion activates lattice oxygen in perovskite ferrite for methane partial oxidation coupled with CO₂ splitting, J. Am. Chem. Soc. 142(26) (2020) 11540-11549.
[26] N. Galinsky, M. Sendi, L. Bowers, F.X. Li, CaMn_1-xB_xO_3-δ (B = Al, V, Fe, Co, and Ni) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU), Appl. Energy 174(2016) 80-87.
[27] N. Galinsky, A. Mishra, J. Zhang, F.X. Li, Ca_1-a MnO₃(a = Sr and Ba) perovskite based oxygen carriers for chemical looping with oxygen uncoupling (CLOU), Appl. Energy 157(2015) 358-367.
[28] T. Mattisson, Materials for chemical-looping with oxygen uncoupling, ISRN Chem. Eng. 2013(2013) 526375.
[29] A. Shafiefarhood, A. Stewart, F.X. Li, Iron-containing mixed-oxide composites as oxygen carriers for Chemical Looping with Oxygen Uncoupling (CLOU), Fuel 139(2015) 1-10.
[30] M. Arjmand, A. Hedayati, A.M. Azad, H. Leion, M. Ryden, T. Mattisson, Ca_xLa_1-xMn_1-yMyO_3-δ (M = Mg, Ti, Fe, or Cu) as oxygen carriers for chemical-looping with oxygen uncoupling (CLOU), Energy Fuels 27(8) (2013) 4097-4107.
[31] P. Hallberg, D.Z. Jing, M. Ryden, T. Mattisson, A. Lyngfelt, Chemical looping combustion and chemical looping with oxygen uncoupling experiments in a batch reactor using spray-dried CaMn_1-xM_xO_3-δ (M = Ti, Fe, Mg) particles as oxygen carriers, Energy Fuels 27(3) (2013) 1473-1481.
[32] R.B. Dudek, Y.F. Gao, J.S. Zhang, F.X. Li, Manganese-containing redox catalysts for selective hydrogen combustion under a cyclic redox scheme, AlChE. J. 64(8) (2018) 3141-3150.
[33] Y.F. Gao, S. Wang, F. Hao, Z.J. Dai, F.X. Li, Zeolite-perovskite composites as effective redox catalysts for autothermal cracking of n-hexane, ACS Sustainable Chem. Eng. 8(38) (2020) 14268-14273.
[34] R.B. Dudek, X. Tian, M. Blivin, L.M. Neal, H.B. Zhao, F.X. Li, Perovskite oxides for redox oxidative cracking of n-hexane under a cyclic redox scheme, Appl. Catal. B Environ. 246(2019) 30-40.
[35] F. Hao, Y.F. Gao, L. Neal, R.B. Dudek, W.Y. Li, C. Chung, B. Guan, P.L. Liu, X.B. Liu, F.X. Li, Sodium tungstate-promoted CaMnO₃ as an effective, phase-transition redox catalyst for redox oxidative cracking of cyclohexane, J. Catal. 385(2020) 213-223.
[36] Y. Tian, R.B. Dudek, P.R. Westmoreland, F.X. Li, Effect of sodium tungstate promoter on the reduction kinetics of CaMn_0.9Fe_0.1O₃ for chemical looping-oxidative dehydrogenation of ethane, Chem. Eng. J. 398(2020) 125583.
[37] L. Brody, L. Neal, V. Haribal, F.X. Li, Ethane to liquids via a chemical looping approach-Redox catalyst demonstration and process analysis, Chem. Eng. J. 417(2021) 128886.
[38] M.H. Yuan, W.J. Dong, L.L. Wei, Q. Liu, Y.J. Meng, X.Y. Wang, B.Y. Wang, B. Zhu, Stability study of SOFC using layered perovskite oxide La_1.85Sr_0.15CuO₄ mixed with ionic conductor as membrane, Electrochim. Acta 332(2020) 135487.
[39] P. Rocha-Rodrigues, S.S.M. Santos, G.N.P. Oliveira, T. Leal, I.P. Miranda, A.M. dos Santos, J.G. Correia, L.V.C. Assali, H.M. Petrilli, J.P. Araujo, A.M.L. Lopes, Ca₂MnO₄ structural path: Following the negative thermal expansion at the local scale, Phys. Rev. B 102(10) (2020) 104115.
[40] C. Autret, C. Martin, M. Hervieu, R. Retoux, B. Raveau, G. Andre, F. Bouree, Structural investigation of Ca₂MnO₄ by neutron powder diffraction and electron microscopy, J. Solid State Chem. 177(6) (2004) 2044-2052.
[41] C. Ablitt, H. McCay, S. Craddock, L. Cooper, E. Reynolds, A.A. Mostofi, N.C. Bristowe, C.A. Murray, M.S. Senn, Tolerance factor control of uniaxial negative thermal expansion in a layered perovskite, Chem. Mater. 32(1) (2020) 605-610.
[42] W.X. Ding, K. Zhao, S.C. Jiang, Z.L. Zhao, Y. Cao, F. He, Alkali-metal enhanced LaMnO₃ perovskite oxides for chemical looping oxidative dehydrogenation of ethane, Appl. Catal. A Gen. 609(2021) 117910.
[43] S. Yusuf, V. Haribal, D. Jackson, L. Neal, F.X. Li, Mixed iron-manganese oxides as redox catalysts for chemical looping-oxidative dehydrogenation of ethane with tailorable heat of reactions, Appl. Catal. B Environ. 257(2019) 117885.
[44] M. Ali, Z.W. Liao, Y. Yang, J.Y. Sun, B.B. Jiang, J.D. Wang, Y.R. Yang, Modeling and optimization of ethane steam cracking process in an industrial tubular reactor with improved reaction scheme, CHINA PET PROCESS PE 22(2020) 117-125.
[45] Y.F. Gao, X.J. Wang, J.C. Liu, C.D. Huang, K. Zhao, Z.L. Zhao, X.D. Wang, F.X. Li, A molten carbonate shell modified perovskite redox catalyst for anaerobic oxidative dehydrogenation of ethane, Sci. Adv. 6(17) (2020) eaaz9339.
[46] Y.J. Yang, J. Liu, Z. Wang, Y. Long, J.Y. Ding, Interface reaction activity of recyclable and regenerable Cu-Mn spinel-type sorbent for Hg⁰ capture from flue gas, Chem. Eng. J. 372(2019) 697-707.
[47] X. Bai, R. He, A.J. Wei, X.H. Li, L.H. Zhang, Z.F. Liu, A Co-Modified strategy for enhanced structural stability and long cycling life of Ni-Rich LiNi_0.8Co_0.1Mn_0.1O₂ cathode material, J. Alloys Compd. 857(2021) 157877.
[48] Y.J. Luo, D.F. Lin, Y.B. Zheng, X.S. Feng, Q.H. Chen, K. Zhang, X.Y. Wang, L.L. Jiang, MnO₂ nanoparticles encapsuled in spheres of Ce-Mn solid solution: Efficient catalyst and good water tolerance for low-temperature toluene oxidation, Appl. Surf. Sci. 504(2020) 144481.
[49] X.J. Zhang, J.G. Zhao, Z.X. Song, W. Liu, H. Zhao, M. Zhao, Y. Xing, Z.A. Ma, H.X. Du, The catalytic oxidation performance of toluene over the Ce-Mn-O_x catalysts: Effect of synthetic routes, J. Colloid Interface Sci. 562(2020) 170-181.
[50] B. Guan, H. Lin, L. Zhu, B. Tian, Z. Huang, Effect of ignition temperature for combustion synthesis on the selective catalytic reduction of NO_x with NH₃ over Ti_0.9Ce_0.05V_0.05O_2-δ nanocomposites catalysts prepared by solution combustion route, Chem. Eng. J. 181-182(2012) 307-322.
[51] Z.Z. Huang, Y.H. Wei, Z.X. Song, J.W. Luo, Y.L. Mao, J.Q. Gao, X.J. Zhang, C. Niu, H.Y. Kang, Z.D. Wang, Three-dimensional (3D) hierarchical Mn₂O₃ catalysts with the highly efficient purification of benzene combustion, Sep. Purif. Technol. 255(2021) 117633.
[52] E. Heracleous, A.A. Lemonidou, Ni-Nb-O mixed oxides as highly active and selective catalysts for ethene production via ethane oxidative dehydrogenation. Part II: Mechanistic aspects and kinetic modeling, J. Catal. 237(1) (2006) 175-189.
[53] J. Kim, J.E. Lee, H.W. Lee, J.K. Jeon, J. Song, S.C. Jung, Y.F. Tsang, Y.K. Park, Catalytic ozonation of toluene using Mn-M bimetallic HZSM-5(M: Fe, Cu, Ru, Ag) catalysts at room temperature, J. Hazard. Mater. 397(2020) 122577.
[54] Y.P. Zhang, P. Wu, G.B. Li, K. Zhuang, K. Shen, S. Wang, T.J. Huang, Improved activity of Ho-modified Mn/Ti catalysts for the selective catalytic reduction of NO with NH₃, Environ. Sci. Pollut. Res. Int. 27(21) (2020) 26954-26964.
[55] J. Chen, X. Chen, D.X. Yan, M.Z. Jiang, W.J. Xu, H. Yu, H.P. Jia, A facile strategy of enhancing interaction between cerium and manganese oxides for catalytic removal of gaseous organic contaminants, Appl. Catal. B Environ. 250(2019) 396-407.

Ca₂MnO₄-layered perovskite modified by NaNO₃ for chemical-looping oxidative dehydrogenation of ethane to ethylene

Ca₂MnO₄-layered perovskite modified by NaNO₃ for chemical-looping oxidative dehydrogenation of ethane to ethylene

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