High tap density of Ni3(PO4)2 coated LiNi1/3Co1/3Mn1/3O2 with enhanced cycling performance at high cut-off voltage

doi:10.1016/j.cjche.2014.03.001

Chinese Journal of Chemical Engineering ›› 2015, Vol. 23 ›› Issue (1): 315-320.DOI: 10.1016/j.cjche.2014.03.001

High tap density of Ni₃(PO₄)₂ coated LiNi_1/3Co_1/3Mn_1/3O₂ with enhanced cycling performance at high cut-off voltage

Yan Cui, Shengming Xu

Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

收稿日期:2013-09-09 修回日期:2014-03-04 出版日期:2015-01-28 发布日期:2015-01-24
通讯作者: Shengming Xu
基金资助:
Supported by the National Natural Science Foundation of China (51074096).

High tap density of Ni₃(PO₄)₂ coated LiNi_1/3Co_1/3Mn_1/3O₂ with enhanced cycling performance at high cut-off voltage

Yan Cui, Shengming Xu

Institute of Nuclear and New Energy Technology, Tsinghua University, Beijing 100084, China

Received:2013-09-09 Revised:2014-03-04 Online:2015-01-28 Published:2015-01-24
Contact: Shengming Xu
Supported by:
Supported by the National Natural Science Foundation of China (51074096).

摘要/Abstract

摘要： The LiNi_1/3Co_1/3Mn_1/3O₂ is first obtained by the controlled crystallization method and then coatedwith Ni₃(PO₄)₂ particles. The effects of the coating on rate capability and cycle life at high cut-off voltage are investigated by electrochemical impedance spectroscopy and galvanostatic measurements. The element ratio of Ni:Mn:Co is tested by inductively-coupled plasma spectrometer (ICP) analysis and it testified to be 1:1:1. It is indicated that Ni₃(PO₄)₂-coated LiNi_1/3Co_1/3Mn_1/3O₂ has an outstanding capacity retention, where 99% capacity retention is maintained after 10 cycles at 5C discharge rate between 2.7 V and 4.6 V. The electrochemical impedance spectroscopy (EIS) results show that the current exchange density i0 of the coated sample is higher than that of LiNi_1/3Co_1/3Mn_1/3O₂, which is beneficial to its electrochemical performances. All the conclusions show that the Ni₃(PO₄)₂ coating can prominently enhance the high rate performance of the LiNi_1/3Co_1/3Mn_1/3O₂, especially at high cut-off voltage.

关键词: LiNi_1/3Co_1/3Mn_1/3O₂ cathode material, Electrochemistry, Ni₃(PO₄)₂ coating, High tap density, High rate discharge capacity

Abstract: The LiNi_1/3Co_1/3Mn_1/3O₂ is first obtained by the controlled crystallization method and then coatedwith Ni₃(PO₄)₂ particles. The effects of the coating on rate capability and cycle life at high cut-off voltage are investigated by electrochemical impedance spectroscopy and galvanostatic measurements. The element ratio of Ni:Mn:Co is tested by inductively-coupled plasma spectrometer (ICP) analysis and it testified to be 1:1:1. It is indicated that Ni₃(PO₄)₂-coated LiNi_1/3Co_1/3Mn_1/3O₂ has an outstanding capacity retention, where 99% capacity retention is maintained after 10 cycles at 5C discharge rate between 2.7 V and 4.6 V. The electrochemical impedance spectroscopy (EIS) results show that the current exchange density i0 of the coated sample is higher than that of LiNi_1/3Co_1/3Mn_1/3O₂, which is beneficial to its electrochemical performances. All the conclusions show that the Ni₃(PO₄)₂ coating can prominently enhance the high rate performance of the LiNi_1/3Co_1/3Mn_1/3O₂, especially at high cut-off voltage.

Key words: LiNi_1/3Co_1/3Mn_1/3O₂ cathode material, Electrochemistry, Ni₃(PO₄)₂ coating, High tap density, High rate discharge capacity

Yan Cui, Shengming Xu . High tap density of Ni₃(PO₄)₂ coated LiNi_1/3Co_1/3Mn_1/3O₂ with enhanced cycling performance at high cut-off voltage[J]. Chinese Journal of Chemical Engineering, 2015, 23(1): 315-320.

Yan Cui, Shengming Xu . High tap density of Ni₃(PO₄)₂ coated LiNi_1/3Co_1/3Mn_1/3O₂ with enhanced cycling performance at high cut-off voltage[J]. Chin.J.Chem.Eng., 2015, 23(1): 315-320.

参考文献

[1] Z.R. Chang, Z.J. Chen, F. Wu, Synthesis and characterization of high-density nonspherical Li(Ni_1/3Co_1/3Mn_1/3)O₂ cathode material for lithium ion batteries by twostep drying method, Electrochim. Acta 53 (2008) 5927-5933.

[2] S.H. Na, H.S. Kim, S.I. Moon, A new synthetic route of LiNi_0.5Mn_0.5O₂ as the cathode material of secondary lithium batteries, Electrochim. Acta 50 (2004) 449-452.

[3] P. He, H.R.Wang, L. Qi, Electrochemical characteristics of layered Li(Ni_1/3Co_1/3Mn_1/3) O₂ and with different synthesis conditions, J. Power Sources 160 (2006) 627-632.

[4] A. Yoshinori, K. Hironori, E. Shuichi, Li de-intercalation mechanism in LiNi_0.5Mn_0.5O₂ cathode material for Li-ion batteries, Solid State Ionics 176 (2005) 895-903.

[5] L. Wang, Y.S. He, X.M. Zhang, X.Z. Liao, Z.F. Ma, Preparation and electrochemical properties of LiNi0. 8Co0.2O₂ cathodematerial bymicrowave coprecipitation method, J. Chem. Ind. Eng. 58 (4) (2007) 1048 (in Chinese).

[6] Y.Z. Sun, J.Q. Pan, P.Y.Wan, C.C. Xu, X.G. Liu, Electrolytic preparation, structure characterization and electro-chemical performance of NiOOH, Chin. J. Chem. Eng. 15 (2007) 262-267.

[7] I. Belharouak, Y.K. Sun, J. Liu, Li(Ni_1/3Co_1/3Mn_1/3)O₂ as a suitable cathode for high power applications, J. Power Sources 123 (2003) 247-252.

[8] Jeffrey W. Fergus, Recent developments in cathode materials for lithium ion batteries, J. Power Sources 195 (2010) 939-954.

[9] Y.Q. Ye, X.Y. Xiao, C.X. Wan, Progress in LiNi_1/3Co_1/3Mn_1/3O₂ cathode material for lithium-ion battery, Chem. Ind. Eng. Prog. 28 (2009) 1192 (in Chinese).

[10] X. Li, Y.J. Wei, H. Ehrenberg, Characterizations on the structural and electrochemical properties of Li(Ni_1/3Co_1/3Mn_1/3)O₂ prepared by a wet-chemical process, Solid State Ionics 178 (2008) 1969-1974.

[11] Y.S. He, L. Pei, X.Z. Liao, Synthesis of LiNi_1/3Co_1/3Mn_1/3O₂_zFz cathode material from oxalate precursors for lithium ion battery, J. Fluor. Chem. 128 (2007) 139-143.

[12] S. Zhang, Characterization of high tap density Li[Ni_1/3Co_1/3Mn_1/3]O₂ cathodematerial synthesized via hydroxide co-precipitation, Electrochim. Acta 52 (2007) 7337-7342.

[13] S. Zhang, C. Deng, B.L. Fu, Synthetic optimization of spherical Li[Ni_1/3Mn_1/3Co_1/3]O₂ prepared by a carbonate co-precipitation method, Powder Technol. 198 (2010) 373-380.

[14] Y. Chen, G.X. Wang, K. Konstantinov, H.K. Liu, Synthesis and characterization of LiCoxMnyNi1_x_yO₂ as a cathode material for secondary lithium batteries, J. Power Sources 119-121 (2003) 184-188.

[15] P. Sebastien, M.D. Marca, Direct synthesis of Li(Ni_1/3Co_1/3Mn_1/3)O₂ from nitrate precursors, Electrochem. Commun. 6 (2004) 767-772.

[16] Z.M. Liu, G.R. Hu, Z.D. Peng, Synthesis and characterization of layered Li(Ni_l/3Ni_l/3Co_l/3)O₂ cathode materials by spray-drying method, Trans. Nonferrous Metals Soc. China 17 (2007) 1-295.

[17] C.F. Zhang, P. Yang, X. Dai, Synthesis of Li(Ni_1/3Co_1/3Mn_1/3)O₂ cathode material via oxalate precursor, Trans. Nonferrous Metals Soc. China 19 (2009) 635-641.

[18] M. Kageyama, D.C. Li, K. Kobayakawa, Structural and electrochemical properties of Li(Ni_1/3Co_1/3Mn_1/3)O₂ -xFx prepared by solid state reaction, J. Power Sources 157 (2006) 494-500.

[19] S. Zhang, C. Deng, B.L. Fu, Synthetic optimization of spherical Li(Ni_1/3Co_1/3Mn_1/3)O₂ prepared by a carbonate co-precipitation method, Powder Technol. 198 (2010) 373-380.

[20] M. Sathiya, A.S. Prakash, K. Ramesha, Rapid synthetic routes to prepare Li(Ni_1/3Co_1/3Mn_1/3)O₂ as a high voltage, high-capacity Li-ion battery cathode material, Mater. Res. Bull. 44 (2009) 1990-1994.

[21] N. Yabuuchi, O. Tsutomu, Novel lithium insertion material of Li(Ni_1/3Co_1/3Mn_1/3)O₂ for advanced lithium-ion batteries, J. Power Sources 119-121 (2003) 171-174.

[22] Y.Y. Huang, J.T. Chen, J.F. Ni, A modified ZrO₂-coating process to improve electrochemical performance of Li(Ni_1/3Co_1/3Mn_1/3)O₂, J. Power Sources 188 (2009) 538-545.

[23] Y.Y. Huang, J.T. Chen, F.Q. Cheng, A modified Al₂O₃ coating process to enhance the electrochemical performance of Li(Ni_1/3Co_1/3Mn_1/3)O₂ and its comparison with traditional Al₂O₃ coating process, J. Power Sources 195 (2010) 8267-8274.

[24] Y. Koyama, I. Tanaka, H. Adachi, Crystal and electronic structures of superstructural Li1_x[Co_1/3Ni_1/3Mn_1/3]O₂, J. Power Sources 119-121 (2003) 644-648.

[25] K. Youngsik, S.K. Hyun,W.M. Steve, Synthesis and electrochemical characteristics of Al₂O₃-coated Li(Ni_1/3Co_1/3Mn_1/3)O₂ cathode materials for lithium ion batteries, Electrochim. Acta 52 (2006) 1316-1322.

[26] H.S. Kim, Y. Kim, S. Kim, Enhanced electrochemical properties of Li(Ni_1/3Co_1/3Mn_1/3) O₂ cathode material by coating with LiAlO₂ nanoparticles, J. Power Sources 161 (2006) 623-627.

High tap density of Ni₃(PO₄)₂ coated LiNi_1/3Co_1/3Mn_1/3O₂ with enhanced cycling performance at high cut-off voltage

High tap density of Ni₃(PO₄)₂ coated LiNi_1/3Co_1/3Mn_1/3O₂ with enhanced cycling performance at high cut-off voltage

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