Efficient conversion of H2S into mercaptan alcohol by tertiary-amine functionalized ionic liquids

doi:10.1016/j.cjche.2022.07.001

中国化学工程学报 ›› 2022, Vol. 50 ›› Issue (10): 197-204.DOI: 10.1016/j.cjche.2022.07.001

• Separation Science and Engineering • 上一篇下一篇

Efficient conversion of H₂S into mercaptan alcohol by tertiary-amine functionalized ionic liquids

Wenjie Xiong¹, Mingzhen Shi¹, Yan Lu¹, Xiaomin Zhang^1,2, Xingbang Hu^1,2, Zhuoheng Tu¹, Youting Wu¹

1 Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China;
2 Institute of Green Chemistry and Engineering, Nanjing University, Suzhou 215163, China

收稿日期:2022-03-19 修回日期:2022-06-29 出版日期:2022-10-28 发布日期:2023-01-04
通讯作者: Xiaomin Zhang,E-mail:xmzhang@nju.edu.cn;Zhuoheng Tu,E-mail:zhtu@nju.edu.cn;Youting Wu,E-mail:ytwu@nju.edu.cn
基金资助:
This work was sponsored by the National Natural Science Foundation of China (22078145 and 22208140).

Efficient conversion of H₂S into mercaptan alcohol by tertiary-amine functionalized ionic liquids

Wenjie Xiong¹, Mingzhen Shi¹, Yan Lu¹, Xiaomin Zhang^1,2, Xingbang Hu^1,2, Zhuoheng Tu¹, Youting Wu¹

1 Key Laboratory of Mesoscopic Chemistry of MOE, School of Chemistry and Chemical Engineering, Nanjing University, Nanjing 210023, China;
2 Institute of Green Chemistry and Engineering, Nanjing University, Suzhou 215163, China

Received:2022-03-19 Revised:2022-06-29 Online:2022-10-28 Published:2023-01-04
Contact: Xiaomin Zhang,E-mail:xmzhang@nju.edu.cn;Zhuoheng Tu,E-mail:zhtu@nju.edu.cn;Youting Wu,E-mail:ytwu@nju.edu.cn
Supported by:
This work was sponsored by the National Natural Science Foundation of China (22078145 and 22208140).

摘要/Abstract

摘要： The resource utilization of hydrogen sulfide (H₂S) is of great significance in natural gas chemical industry. Described herein have developed a novel method mediated in tertiary amine-functionalized ionic liquids (ILs) to convert H₂S into mercaptan alcohols with enols. The effect of ILs, substrate scope, and regeneration experiments have been investigated. It is found that the conversion of 3-methyl-2-buten-1-ol by H₂S can reach 52% with a 50% (mol) catalyst loading of bis(2-dimethylaminoethyl) ether methoxyacetate within 12 h at 90 ℃. The reaction mechanism was speculated based on theoretical calculation. Besides, a plausible reaction-separation-integrated strategy was further proposed. This work reveals an effective insight into the capture and catalytic conversion of H₂S to high valuable mercaptan alcohol, which makes the utilization method of H₂S resource universal and has the potentiality for industrial application.

关键词: Ionic liquids, Reaction, Catalysis, Hydrogen sulfide, DFT calculation

Abstract: The resource utilization of hydrogen sulfide (H₂S) is of great significance in natural gas chemical industry. Described herein have developed a novel method mediated in tertiary amine-functionalized ionic liquids (ILs) to convert H₂S into mercaptan alcohols with enols. The effect of ILs, substrate scope, and regeneration experiments have been investigated. It is found that the conversion of 3-methyl-2-buten-1-ol by H₂S can reach 52% with a 50% (mol) catalyst loading of bis(2-dimethylaminoethyl) ether methoxyacetate within 12 h at 90 ℃. The reaction mechanism was speculated based on theoretical calculation. Besides, a plausible reaction-separation-integrated strategy was further proposed. This work reveals an effective insight into the capture and catalytic conversion of H₂S to high valuable mercaptan alcohol, which makes the utilization method of H₂S resource universal and has the potentiality for industrial application.

Key words: Ionic liquids, Reaction, Catalysis, Hydrogen sulfide, DFT calculation

Wenjie Xiong, Mingzhen Shi, Yan Lu, Xiaomin Zhang, Xingbang Hu, Zhuoheng Tu, Youting Wu. Efficient conversion of H₂S into mercaptan alcohol by tertiary-amine functionalized ionic liquids[J]. 中国化学工程学报, 2022, 50(10): 197-204.

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Efficient conversion of H₂S into mercaptan alcohol by tertiary-amine functionalized ionic liquids

Efficient conversion of H₂S into mercaptan alcohol by tertiary-amine functionalized ionic liquids

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