Controllable fabrication of FeCoS4 nanoparticles/S-doped bowl-shaped hollow carbon as efficient lithium storage anode

doi:10.1016/j.cjche.2023.12.003

中国化学工程学报 ›› 2024, Vol. 67 ›› Issue (3): 78-88.DOI: 10.1016/j.cjche.2023.12.003

Controllable fabrication of FeCoS₄ nanoparticles/S-doped bowl-shaped hollow carbon as efficient lithium storage anode

Ming Zhou¹, Mengrong Wu¹, Haiwei Yu¹, Xiangjun Zheng¹, Kuan Shen¹, Xingmei Guo¹, Yuanjun Liu¹, Fu Cao¹, Hongxing Gu², Qinghong Kong³, Junhao Zhang¹

1 School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2 Jiangsu Hengshen Co., Ltd, Zhenjiang 212314, China;
3 School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China

收稿日期:2023-07-23 修回日期:2023-11-04 出版日期:2024-03-28 发布日期:2024-06-01
通讯作者: Xiangjun Zheng,E-mail address:zhengxj@just.edu.cn;Junhao Zhang,E-mail address:jhzhang6@just.edu.cn.
基金资助:
This work was financially supported by the National Natural Science Foundation of China (22379056, 52102260), the Project funded by China Postdoctoral Science Foundation (2022M711545), and the Carbon Peak and Carbon Neutrality Project (Breakthrough for Industry Prospect and Key Technologies) of Zhenjiang City (CG2023003).

Controllable fabrication of FeCoS₄ nanoparticles/S-doped bowl-shaped hollow carbon as efficient lithium storage anode

Ming Zhou¹, Mengrong Wu¹, Haiwei Yu¹, Xiangjun Zheng¹, Kuan Shen¹, Xingmei Guo¹, Yuanjun Liu¹, Fu Cao¹, Hongxing Gu², Qinghong Kong³, Junhao Zhang¹

1 School of Environmental and Chemical Engineering, Jiangsu University of Science and Technology, Zhenjiang 212003, China;
2 Jiangsu Hengshen Co., Ltd, Zhenjiang 212314, China;
3 School of the Environment and Safety Engineering, Jiangsu University, Zhenjiang 212013, China

Received:2023-07-23 Revised:2023-11-04 Online:2024-03-28 Published:2024-06-01
Contact: Xiangjun Zheng,E-mail address:zhengxj@just.edu.cn;Junhao Zhang,E-mail address:jhzhang6@just.edu.cn.
Supported by:
This work was financially supported by the National Natural Science Foundation of China (22379056, 52102260), the Project funded by China Postdoctoral Science Foundation (2022M711545), and the Carbon Peak and Carbon Neutrality Project (Breakthrough for Industry Prospect and Key Technologies) of Zhenjiang City (CG2023003).

摘要/Abstract

摘要： To address the low conductivity and easy agglomeration of transition metal sulfide nanoparticles, FeCoS₄ nanoparticles embedded in S-doped hollow carbon (FeCoS₄@S-HC) composites were successfully fabricated through a combination of hydrothermal processes and sulfidation treatment. The unique bowlshaped FeCoS₄/S-HC composites exhibit excellent structural stability with a high specific surface area of 303.7 m²·g^-1 and a pore volume of≥0.93 cm³·g^-1. When applied as anode material for lithium-ion batteries, the FeCoS₄@S-HC anode exhibits efficient lithium storage with high reversible specific capacity (970.2 mA·h·g^-1 at 100 mA·g^-1) and enhanced cycling stability (574 mA·h·g^-1 at≥0.2 A·g^-1 after 350 cycles, a capacity retention of 84%). The excellent lithium storage is attributed to the fact that the bimetallic FeCoS₄ nanoparticles with abundant active sites can accelerate the electrochemical reaction kinetics, and the bowl-shaped S-HC structure can provide a stable mechanical structure to suppress volume expansion.

关键词: Bimetallic sulfides, Bowl-shaped hollow carbon, S doping, Buffering volume expand, Lithium-ion batteries

Abstract: To address the low conductivity and easy agglomeration of transition metal sulfide nanoparticles, FeCoS₄ nanoparticles embedded in S-doped hollow carbon (FeCoS₄@S-HC) composites were successfully fabricated through a combination of hydrothermal processes and sulfidation treatment. The unique bowlshaped FeCoS₄/S-HC composites exhibit excellent structural stability with a high specific surface area of 303.7 m²·g^-1 and a pore volume of≥0.93 cm³·g^-1. When applied as anode material for lithium-ion batteries, the FeCoS₄@S-HC anode exhibits efficient lithium storage with high reversible specific capacity (970.2 mA·h·g^-1 at 100 mA·g^-1) and enhanced cycling stability (574 mA·h·g^-1 at≥0.2 A·g^-1 after 350 cycles, a capacity retention of 84%). The excellent lithium storage is attributed to the fact that the bimetallic FeCoS₄ nanoparticles with abundant active sites can accelerate the electrochemical reaction kinetics, and the bowl-shaped S-HC structure can provide a stable mechanical structure to suppress volume expansion.

Key words: Bimetallic sulfides, Bowl-shaped hollow carbon, S doping, Buffering volume expand, Lithium-ion batteries

Ming Zhou, Mengrong Wu, Haiwei Yu, Xiangjun Zheng, Kuan Shen, Xingmei Guo, Yuanjun Liu, Fu Cao, Hongxing Gu, Qinghong Kong, Junhao Zhang. Controllable fabrication of FeCoS₄ nanoparticles/S-doped bowl-shaped hollow carbon as efficient lithium storage anode[J]. 中国化学工程学报, 2024, 67(3): 78-88.

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Controllable fabrication of FeCoS₄ nanoparticles/S-doped bowl-shaped hollow carbon as efficient lithium storage anode

Controllable fabrication of FeCoS₄ nanoparticles/S-doped bowl-shaped hollow carbon as efficient lithium storage anode

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