One-step Continuous Phenol Synthesis Technology via Selective Hydroxylation of Benzene over Ultrafine TS-1 in a Submerged Ceramic Membrane Reactor

doi:10.1016/j.cjche.2014.09.016

›› 2014, Vol. 22 ›› Issue (11/12): 1199-1207.DOI: 10.1016/j.cjche.2014.09.016

• 催化、动力学与反应工程 • 上一篇下一篇

One-step Continuous Phenol Synthesis Technology via Selective Hydroxylation of Benzene over Ultrafine TS-1 in a Submerged Ceramic Membrane Reactor

Hong Jiang¹, Fei She¹, Yan Du², Rizhi Chen¹, Weihong Xing¹

1 State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 College of Environment, Nanjing Tech University, Nanjing 210009, China

收稿日期:2014-05-26 修回日期:2014-07-31 出版日期:2014-12-28 发布日期:2014-12-24
通讯作者: Rizhi Chen, Weihong Xing
基金资助:
Supported by the National High Technology Research and Development Program (2012AA03A606), the National Natural Science Foundation (21306081, 21125629), the Natural Science Foundation of Jiangsu Province (BK20130920) and a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) of China.

One-step Continuous Phenol Synthesis Technology via Selective Hydroxylation of Benzene over Ultrafine TS-1 in a Submerged Ceramic Membrane Reactor

Hong Jiang¹, Fei She¹, Yan Du², Rizhi Chen¹, Weihong Xing¹

1 State Key Laboratory of Materials-Oriented Chemical Engineering, Nanjing Tech University, Nanjing 210009, China;
2 College of Environment, Nanjing Tech University, Nanjing 210009, China

Received:2014-05-26 Revised:2014-07-31 Online:2014-12-28 Published:2014-12-24
Supported by:
Supported by the National High Technology Research and Development Program (2012AA03A606), the National Natural Science Foundation (21306081, 21125629), the Natural Science Foundation of Jiangsu Province (BK20130920) and a Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions (PAPD) of China.

摘要/Abstract

摘要： A newroute towards phenol production by one-step selective hydroxylation of benzenewith hydrogen peroxide over ultrafine titaniumsilicalites-1 (TS-1) in a submerged ceramic membrane reactorwas developed, which can maintain the in situ removal of ultrafine catalyst particles fromthe reaction slurry and keep the process continuous. The effects of key operating parameters on the benzene conversion and phenol selectivity, as well as themembrane filtration resistance were examined by single factor experiments. A continuous reaction process was carried out under the obtained optimumoperation conditions. Results showed that the systemcan be continuously and stably operated over 20 h, and the benzene conversion and phenol selectivity kept at about 4% and 91%, respectively. The ceramic membrane exhibits excellent thermal and chemical stability in the continuous reaction process.

关键词: Phenol, Benzene hydroxylation, TS-1, Submerged membrane reactor, Ceramic membrane

Abstract: A newroute towards phenol production by one-step selective hydroxylation of benzenewith hydrogen peroxide over ultrafine titaniumsilicalites-1 (TS-1) in a submerged ceramic membrane reactorwas developed, which can maintain the in situ removal of ultrafine catalyst particles fromthe reaction slurry and keep the process continuous. The effects of key operating parameters on the benzene conversion and phenol selectivity, as well as themembrane filtration resistance were examined by single factor experiments. A continuous reaction process was carried out under the obtained optimumoperation conditions. Results showed that the systemcan be continuously and stably operated over 20 h, and the benzene conversion and phenol selectivity kept at about 4% and 91%, respectively. The ceramic membrane exhibits excellent thermal and chemical stability in the continuous reaction process.

Key words: Phenol, Benzene hydroxylation, TS-1, Submerged membrane reactor, Ceramic membrane

Hong Jiang, Fei She, Yan Du, Rizhi Chen, Weihong Xing. One-step Continuous Phenol Synthesis Technology via Selective Hydroxylation of Benzene over Ultrafine TS-1 in a Submerged Ceramic Membrane Reactor[J]. , 2014, 22(11/12): 1199-1207.

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One-step Continuous Phenol Synthesis Technology via Selective Hydroxylation of Benzene over Ultrafine TS-1 in a Submerged Ceramic Membrane Reactor

One-step Continuous Phenol Synthesis Technology via Selective Hydroxylation of Benzene over Ultrafine TS-1 in a Submerged Ceramic Membrane Reactor

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