Easy removing of phenol from wastewater using vegetable oil-based organic solvent in emulsion liquid membrane process

doi:10.1016/j.cjche.2016.06.002

›› 2017, Vol. 25 ›› Issue (1): 45-52.DOI: 10.1016/j.cjche.2016.06.002

• Separation Science and Engineering • 上一篇下一篇

Easy removing of phenol from wastewater using vegetable oil-based organic solvent in emulsion liquid membrane process

Norasikin Othman^1,2, Norul Fatiha Mohamed Noah², Lim Yin Shu², Zing-Yi Ooi², Norela Jusoh², Mariani Idroas², Masahiro Goto³

1 Centre of Lipids Engineering and Applied Research(CLEAR), Ibnu Sina Institute for Scientific and Industrial Research(Ibnu Sina ISIR), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia;
2 Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia;
3 Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

收稿日期:2016-03-20 修回日期:2016-06-07 出版日期:2017-01-28 发布日期:2017-02-15
通讯作者: Norasikin Othman,E-mail address:norasikin@cheme.utm.my
基金资助:
Supported by the Ministry of Higher Education (MOHE) and Universiti Teknologi Malaysia (RU Research Grant; GUP:Q.J130000.2546.12H50).

Easy removing of phenol from wastewater using vegetable oil-based organic solvent in emulsion liquid membrane process

Norasikin Othman^1,2, Norul Fatiha Mohamed Noah², Lim Yin Shu², Zing-Yi Ooi², Norela Jusoh², Mariani Idroas², Masahiro Goto³

1 Centre of Lipids Engineering and Applied Research(CLEAR), Ibnu Sina Institute for Scientific and Industrial Research(Ibnu Sina ISIR), Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia;
2 Faculty of Chemical and Energy Engineering, Universiti Teknologi Malaysia, 81310 UTM Johor Bahru, Johor, Malaysia;
3 Department of Applied Chemistry, Graduate School of Engineering, Kyushu University, 744 Motooka, Nishi-ku, Fukuoka-shi, Fukuoka 819-0395, Japan

Received:2016-03-20 Revised:2016-06-07 Online:2017-01-28 Published:2017-02-15
Supported by:
Supported by the Ministry of Higher Education (MOHE) and Universiti Teknologi Malaysia (RU Research Grant; GUP:Q.J130000.2546.12H50).

摘要/Abstract

摘要： Phenol is considered as pollutant due to its toxicity and carcinogenic effect. Thus, variety of innovative methods for separation and recovery of phenolic compounds is developed in order to remove the unwanted phenol from wastewater and obtain valuable phenolic compound. One of potential method is extraction using green based liquid organic solvent. Therefore, the feasibility of using palm oil was investigated. In this research, palm oil based organic phase was used as diluents to treat a simulated wastewater containing 300×10^-6 of phenol solution using emulsion liquid membrane process (ELM). The stability of water-in-oil (W/O) emulsion on diluent composition and the parameters affecting the phenol removal efficiency and stability of the emulsion; such as emulsification speed, emulsification time, agitation speed, surfactant concentration, pH of external phase, contact time, stripping agent concentration and treat ratio were carried out. The results of ELM study showed that at ratio 7 to 3 of palm oil to kerosene, 5 min and 1300 r·min^-1 of emulsification process the stabile primary emulsion were formed. Also, no carrier is needed to facilitate the phenol extraction. In experimental conditions of 500 r·min^-1 of agitation speed, 3% Span 80, pH 8 of external phase, 5 min of contact time, 0.1 mol·L^-1 NaOH as stripping agent and 1:10 of treat ratio, the ELM process was very promising for removing the phenol from the wastewater. The extraction performance at about 83% of phenol was removed for simulated wastewater and an enrichment of phenol in recovery phase as phenolate compound was around 11 times.

关键词: Vegetable palm oil-based, Liquid membrane, Phenol removal, Wastewater

Abstract: Phenol is considered as pollutant due to its toxicity and carcinogenic effect. Thus, variety of innovative methods for separation and recovery of phenolic compounds is developed in order to remove the unwanted phenol from wastewater and obtain valuable phenolic compound. One of potential method is extraction using green based liquid organic solvent. Therefore, the feasibility of using palm oil was investigated. In this research, palm oil based organic phase was used as diluents to treat a simulated wastewater containing 300×10^-6 of phenol solution using emulsion liquid membrane process (ELM). The stability of water-in-oil (W/O) emulsion on diluent composition and the parameters affecting the phenol removal efficiency and stability of the emulsion; such as emulsification speed, emulsification time, agitation speed, surfactant concentration, pH of external phase, contact time, stripping agent concentration and treat ratio were carried out. The results of ELM study showed that at ratio 7 to 3 of palm oil to kerosene, 5 min and 1300 r·min^-1 of emulsification process the stabile primary emulsion were formed. Also, no carrier is needed to facilitate the phenol extraction. In experimental conditions of 500 r·min^-1 of agitation speed, 3% Span 80, pH 8 of external phase, 5 min of contact time, 0.1 mol·L^-1 NaOH as stripping agent and 1:10 of treat ratio, the ELM process was very promising for removing the phenol from the wastewater. The extraction performance at about 83% of phenol was removed for simulated wastewater and an enrichment of phenol in recovery phase as phenolate compound was around 11 times.

Key words: Vegetable palm oil-based, Liquid membrane, Phenol removal, Wastewater

Norasikin Othman, Norul Fatiha Mohamed Noah, Lim Yin Shu, Zing-Yi Ooi, Norela Jusoh, Mariani Idroas, Masahiro Goto. Easy removing of phenol from wastewater using vegetable oil-based organic solvent in emulsion liquid membrane process[J]. , 2017, 25(1): 45-52.

参考文献

[1] E. Kalaiarasan, T. Palvannan, Removal of phenols from acidic environment by horseradish peroxidase (HRP):Aqueous thermostabilization of HRP by polysaccharide additives, J. Taiwan Inst. Chem. Eng. 45(2) (2014) 625-634.
[2] S. Mohammadi, A. Kargari, H. Sanaeepur, K. Abbassian, A. Najafi, E. Mofarrah, Phenol removal from industrial wastewaters:A short review, Desalin. Water Treat. (2014) 1-20.
[3] M.S.A. Palma, J.L. Paiva, M. Zilli, A. Converti, Batch phenol removal from methyl isobutyl ketone by liquid-liquid extraction with chemical reaction, Chem. Eng. Process. 46(2007) 764-768.
[4] Y. Park, A. Skelland, L. Forney, J. Kim, Removal of phenol and substituted phenols by newly developed emulsion liquid membrane process, Water Res. 40(9) (2006) 1763-1772.
[5] C.C. Tung, Y.M. Yang, C.H. Chang, J.R. Maa, Removal of copper ions and dissolved phenol from water using micellar-enhanced ultrafiltration with mixed surfactants, Waste Manag. 22(2002) 695-701.
[6] A. Witek, A. Koltuniewicz, K. Bartosz, M. Radziejowska, M. Hatalski, Simultaneous removal of phenols and Cr³⁺ using micellar-enhanced ultrafiltration process, Desalination 191(2006) 111-116.
[7] G.M. Zeng, K. Xu, J.H. Huang, X. Li, Y.Y. Fang, Y.H. Qu, Micellar enhanced ultrafiltration of phenol in synthetic wastewater using polysulfone spiral membrane, J. Membr. Sci. 310(2008) 149-160.
[8] C. Zidi, R. Tayed, M. Dhahbi, Extraction of phenol from aqueous solutions by means of supported liquid membrane (MLS) containing tri-n-octyl phosphine oxide (TOPO), J. Hazard. Mater. 194(2011) 62-68.
[9] V. Badgujar, N.K. Rastogi, Extraction of phenol from aqueous effluent using triglycerides in supported liquid membrane, Desalin. Water Treat. 36(2011) 187-196.
[10] P. Venkateswaran, K. Palanivelu, Recovery of phenol from aqueous solution by supported liquid membrane using vegetable oils as liquid membrane, J. Hazard. Mater. B131(2006) 146-152.
[11] A. Balasubramanian, S. Venkatesan, Optimization of process parameters using response surface methodology for the removal of phenol by emulsion liquid membrane, Pol. J. Chem. Technol. 14(1) (2012) 46-49.
[12] Y.S. Ng, N.S. Jayakumar, M.A. Hashim, Performance evaluation of organic emulsion liquid membrane on phenol removal, J. Hazard. Mater. 184(2010) 255-260.
[13] H.J. Park, T.S. Chung, Removal of phenol from aqueous solution by liquid emulsion membrane, Korean J. Chem. Eng. 20(4) (2003) 731-735.
[14] M.T.A. Reis, O.M.F. Freitas, M.R.C. Ismael, R. Machado, J.M.R. Carvalho, Recovery of phenol from aqueous solutions using liquid membranes with Cyanex 923, J. Membr. Sci. 305(2007) 313-324.
[15] M. Chakraborty, C. Bhattacharya, S. Datta, Emulsion liquid membranes:Definitions and classification, theories, module design, applications, new directions and perspectives, in:V.S. Kislik (Ed.), Liquid membranes, Elsevier, Amsterdam 2010, pp. 141-199.
[16] Z.Y. Ooi, N. Othman, M. Mohamad, R. Rashid, Removal performance of lignin compound from simulated pulping wastewater using emulsion liquid membrane process, Int. J. Glob. Warm. 6(23) (2014) 270-283.
[17] N. Othman, R. Djamal, N. Mili, S.N. Zailani, Removal of red 3bs dye from wastewater using emulsion liquid membrane process, J. Appl. Sci. 11(7) (2011) 1406-1410.
[18] T.T. Teng, A. Talebi, Green liquid membrane:Development and challenges, J. Membr. Sci. Technol. 2(3) (2012) 1-2.
[19] N. Othman, N.F.M. Noah, R.N.R. Sulaiman, N.A. Abdullah, S.K. Bachok, Liquid-liquid extraction of palladium from simulated liquid waste using phospinic acid as a carrier, J. Teknol. 68(5) (2014) 41-45.
[20] N.Y. Chan, N. Othman, Z.Y. Ooi, Prediction of Kraft lignin extraction performance using emulsion liquid membrane carrier-diffusion model, J. Teknol. (Sci. Eng.) 67(2) (2014) 17-21.
[21] A. Gheorghe, A. Stoica, O. Floarea, Emulsion liquid membranes stability, U.P.B. Sci. Bull. B70(3) (2008) 23-30.
[22] P.F.M.M. Correia, J.M.R. de Carvalho, Recovery of phenol from phenolic resin plant effluents by emulsion liquid membrane, J. Membr. Sci. 225(2003) 41-49.
[23] W. Peng, C.J. Xu, Removal of phenol by a new emulsion liquid membrane system and its heat-induced demulsification, Adv. Mater. Res. 356-360(2012) 1675-1678.
[24] N. Othman, K.H. Chan, M. Goto, H. Mat, Emulsion liquid membrane extraction of silver from photographic waste using CYANEX 302 as the mobile carrier, Solvent Extr. Res. Dev. 13(2006) 191-202.
[25] J.W. Frenkenfeld, N.N. Li, Recent advances in liquid membrane technology, in:R.W. Rousseau (Ed.), Handbook of separation process technology, John Wiley & Sons Inc., New York 1987, pp. 840-861.
[26] N. Messikh, M.H. Samar, L. Messikh, Neural network analysis of liquid-liquid extraction of phenol from wastewater using TBP solvent, Desalination 208(2007) 42-48.
[27] Tecnico, Chemical reactions of oil, fat and fat based products, Department of Chemical Engineering, Technico, Portugal, 1997(Retrieved from http://journeytoforever.org/biofuel_library/chemoils.html at 30th November 2014).
[28] M.S. Gasser, N.E. El-Hefny, J.A. Daoud, Extraction of Co (II) from aqueous solution using emulsion liquid membrane, J. Hazard. Mater. 151(2-3) (2008) 610-615.
[29] J. Yan, R. Pal, Osmostic swelling behaviour of globules of W/O/W emulsion liquid membranes, J. Membr. Sci. 190(2001) 79-91.
[30] Y. Wan, X. Zhang, Swelling determination of W/O/W emulsion liquid membranes, J. Membr. Sci. 196(2002) 185-201.
[31] R.N.R. Sulaiman, N. Othman, N.A.S. Amin, Emulsion liquid membrane stability in the extraction of ionized Nanosilver from wash water, J. Ind. Eng. Chem. 20(2014) 3243-3250.
[32] M. Chiha, M. Samar, O. Hamdoui, Extraction of Chromoum (VI) from sulphuric acid aqueous solutions by a liquid surfactant membrane (LSM), Desalination 194(2006) 69-80.
[33] M. Chiha, O. Hamdaoui, F. Ahmedchekkat, C. Pétrier, Study on ultrasonically assisted emulsification and recovery of copper (II) from wastewater using an emulsion liquid membrane process, Ultrason. Sonochem. 17(2010) 318-325.
[34] S. Praipruke1, K. Kriausakul, S. Tantayanon, Extraction of palladium from acidic chloride media into emulsion liquid membranes using LIX 984N-C^®, Int. J. Nonferrous Metall. 1(2012) 13-22.
[35] J. Cheng, J.-F. Cehn, M. Zhao, Q. Luo, L.-X. Wen, K.D. Papadopoulos, Transport of ions transport of ions through the oil phase of W(1)/O/W(2) double emulsions, J. Colloid Interface Sci. 305(1) (2007) 175-182.
[36] E.M. Silva, H. Rogez, Y. Larondelle, Optimization of extraction of phenolics from Inga edulis leaves using response surface methodology, Sep. Purif. Technol. 55(3) (2007) 381-387.
[37] P.S. Kulkarni, K.K. Tiwari, V.V. Mahajani, Membrane stability and enrichment of nickel in the liquid emulsion membrane process, J. Chem. Technol. Biotechnol. 75(2000) 553-560.
[38] N. Othman, K.H. Hie, M. Goto, H. Mat, Emulsion liquid membrane extraction of silver from photographic waste using cyanex 302 as a mobile carrier, Solvent Extr. Res. Dev., Jpn. 13(2006) 191-202.
[39] T. Juntachote, E. Berghofer, F. Bauer, S. Siebenhandl, The application of response surface methodology to the production of phenolic extracts of lemon grass, galangal, holy basil and rosemary, Int. J. Food Sci. Technol. 41(2) (2006) 121-133.
[40] R. Chirinos, H. Rogez, D. Campos, R. Pedreschi, Y. Larondelle, Optimization of extraction conditions of antioxidant phenolic compounds from mashua (Tropaeolum tuberosum Ruíz & Pavón) tubers, Sep. Purif. Technol. 55(2) (2007) 217-225.
[41] S.W. Chan, C.Y. Lee, C.F. Yap, W.M. Wan Aida, C.W. Ho, Optimisation of extraction conditions for phenolic compounds from limau purut (Citrus hystrix) peels, Int. Food Res. J. 16(2009) 203-219.
[42] N. Othman, Z.Y. Ooi, S.N. Zailani, E.Z. Zulkifli, S. Subramaniam, Extraction of rhodamine 6G dye from liquid waste solution:Study on emulsion liquid membrane stability performance and recovery, Sep. Sci. Technol. 48(2013) 1177-1183.
[43] Z. Tong, S. Wada, Y. Takao, T. Yamagishi, I. Hiroyasu, K. Tamatsu, Treatment of bleaching wastewater from pulp-paper plants in China using enzymes and coagulants, J. Environ. Sci. 11(4) (1999) 480-484.
[44] R. Sabry, A. Hafez, M. Khedr, A. El-Hassanin, Removal of lead by an emulsion liquid membrane:part I, Desalination 212(1-3) (2007) 165-175.

Easy removing of phenol from wastewater using vegetable oil-based organic solvent in emulsion liquid membrane process

Easy removing of phenol from wastewater using vegetable oil-based organic solvent in emulsion liquid membrane process

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