Promoted hydrolysis performances and mechanism of Si-NaBH4-AlCl3 in deionized water

doi:10.1016/j.cjche.2020.08.019

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (12): 3136-3144.DOI: 10.1016/j.cjche.2020.08.019

• Materials and Product Engineering • 上一篇下一篇

Promoted hydrolysis performances and mechanism of Si-NaBH₄-AlCl₃ in deionized water

Zhao Feng¹, Chaoling Wu^1,2, Shuang Zhong¹, Yungui Chen^1,2, Hui Chen¹, Yao Wang³

1 Department of Advanced Energy Materials, College of Materials Science and Engineering, Sichuan University, Chengdu 610207, China;
2 Engineering Research Center of Alternative Energy Materials & Devices, Ministry of Education, Chengdu 610064, China;
3 Institute of New Energy and Low-Carbon Technology, Sichuan University, Chengdu 610207, China

收稿日期:2020-03-15 修回日期:2020-08-17 出版日期:2020-12-28 发布日期:2021-01-11
通讯作者: Chaoling Wu
基金资助:
This work was financially supported by National Key R&D Program of China (No. 2018YFB1502101) and the International/Hongkong, Macao & Taiwan Scientific and Technological Innovation Cooperation Project (2019YFH0148).

Promoted hydrolysis performances and mechanism of Si-NaBH₄-AlCl₃ in deionized water

Zhao Feng¹, Chaoling Wu^1,2, Shuang Zhong¹, Yungui Chen^1,2, Hui Chen¹, Yao Wang³

1 Department of Advanced Energy Materials, College of Materials Science and Engineering, Sichuan University, Chengdu 610207, China;
2 Engineering Research Center of Alternative Energy Materials & Devices, Ministry of Education, Chengdu 610064, China;
3 Institute of New Energy and Low-Carbon Technology, Sichuan University, Chengdu 610207, China

Received:2020-03-15 Revised:2020-08-17 Online:2020-12-28 Published:2021-01-11
Contact: Chaoling Wu
Supported by:
This work was financially supported by National Key R&D Program of China (No. 2018YFB1502101) and the International/Hongkong, Macao & Taiwan Scientific and Technological Innovation Cooperation Project (2019YFH0148).

摘要/Abstract

摘要： Si-based hydrolysis material system can be used in mobile/portable hydrogen source applications connected to fuel cells but is limited by alkaline solutions. In the present research, we reported an acid/alkaline free hydrolysis system combining silicon with NaBH₄. Samples with different ratios between Si and NaBH₄ are prepared via high energy ball milling and hydrolyzed in deionized water at different temperatures. Synergetic effect between silicon and NaBH₄ was found in the hydrolysis process. 2Si-NaBH₄ sample displays the best hydrolysis performances with the hydrogen yield of 1594 ml·g^-1 in deionized water at 70℃. Thereafter, AlCl₃ is added into the 2Si-NaBH₄ sample to further improve its comprehensive properties. The effect of AlCl₃ content and promotion mechanism of the reaction are explored. 2Si-NaBH₄-5 wt% AlCl₃ sample shows a significant improvement with a high hydrogen yield of 1689 ml·g^-1 in deionized water at 70℃ and a corresponding conversion rate of 95.8%, indicating that the Si-NaBH₄-AlCl₃ composite is promising to be a hydrogen source in applications of mobile/portable fuelcell-powered facilities.

关键词: Hydrolysis, Hydrogen generation, Si-NaBH₄-AlCl₃ composite, Synergetic effect

Abstract: Si-based hydrolysis material system can be used in mobile/portable hydrogen source applications connected to fuel cells but is limited by alkaline solutions. In the present research, we reported an acid/alkaline free hydrolysis system combining silicon with NaBH₄. Samples with different ratios between Si and NaBH₄ are prepared via high energy ball milling and hydrolyzed in deionized water at different temperatures. Synergetic effect between silicon and NaBH₄ was found in the hydrolysis process. 2Si-NaBH₄ sample displays the best hydrolysis performances with the hydrogen yield of 1594 ml·g^-1 in deionized water at 70℃. Thereafter, AlCl₃ is added into the 2Si-NaBH₄ sample to further improve its comprehensive properties. The effect of AlCl₃ content and promotion mechanism of the reaction are explored. 2Si-NaBH₄-5 wt% AlCl₃ sample shows a significant improvement with a high hydrogen yield of 1689 ml·g^-1 in deionized water at 70℃ and a corresponding conversion rate of 95.8%, indicating that the Si-NaBH₄-AlCl₃ composite is promising to be a hydrogen source in applications of mobile/portable fuelcell-powered facilities.

Key words: Hydrolysis, Hydrogen generation, Si-NaBH₄-AlCl₃ composite, Synergetic effect

Zhao Feng, Chaoling Wu, Shuang Zhong, Yungui Chen, Hui Chen, Yao Wang. Promoted hydrolysis performances and mechanism of Si-NaBH₄-AlCl₃ in deionized water[J]. 中国化学工程学报, 2020, 28(12): 3136-3144.

Zhao Feng, Chaoling Wu, Shuang Zhong, Yungui Chen, Hui Chen, Yao Wang. Promoted hydrolysis performances and mechanism of Si-NaBH₄-AlCl₃ in deionized water[J]. Chinese Journal of Chemical Engineering, 2020, 28(12): 3136-3144.

参考文献

[1] C. Tang, F.L. Qu, A.M. Asirir, Y.L. Luo, X.P. Sun, CoP nanoarray:a robust non-noblemetal hydrogen-generating catalyst toward effective hydrolysis of ammonia borane, Inorg. Chem. Front. 4(2017) 659-662.
[2] C. Tang, R. Zhang, W.B. Lu, L.B. He, X.J Asirir.A.M., X.P. Sun, Fe-doped cop nanoarray:a monolithic multifunctional catalyst for high efficient hydrogen generation, Adv. Mater. 29(2017) 1602241-1602246.
[3] L. Schlapbach, A. Züttel, P. Gröning, O. Gröning, P. Aebi, Hydrogen for novel materials and devices, Appl. Phys. A Mater. Sci. Process. 72(2001) 245-253.
[4] A. Abuelnuor, M. Wahid, S. Hosseini, A. Saat, M. Khalid, H. Hani, M. Osman, Characteristics of biomass in flameless combustion:a review, Renew. Sust. Energ. Rev. 33(2014) 363-370.
[5] Züttel, Materials for hydrogen storage, Materialstoday 6(2003) 24-33.
[6] G. Principi, F. Agresti, A. Maddalena, S. Russo, The problem of solid state hydrogen storage, Energy 34(2009) 2087-2091.
[7] F. Schuth, B. Bogdanovic, M. Felderhoff, light metal hydrides and complex hydrides for hydrogen storage, Chem. Commun. 22(2004) 2249-2258.
[8] V. Kong, F. Foulkes, D. Kirk, J. Hinatsu, Development of hydrogen storage for fuel cell generators I:hydrogen generation using hydrolysis hydrides, Int. J. Hydrog. Energy 24(1999) 665-675.
[9] S. Lluís, M. Maria, C. Juan, Synergistic hydrogen generation from aluminum, aluminum alloys and sodium borohydride in aqueous solutions, Int. J. Hydrog. Energy 32(2007) 4702-4710.
[10] M. Joan, G. Thomas, M. Margaret, Fuels for fuel cell vehicles, Fuel Cells Bull. 3(2000) 5-13.
[11] M. Liuan, D. Chen, The effect of composition design on the hydrolysis reaction of Al-Li-Sn alloy and water, Energy Sources 37(2015) 356-364.
[12] M.Q. Fan, F. Xu, L.X. Sun, Studies on hydrogen generation characteristics of hydrolysis of the ball milling Al-based materials in pure water, Int. J. Hydrog. Energy 32(2007) 2809-2815.
[13] X.Y. Chen, Z.W. Zhao, X.H. Liu, M.M. Hao, A.L. Chen, Z.Y. Tang, Hydrogen generation by the hydrolysis reaction of ball-milled aluminiume lithium alloys, J. Power Sources 254(2014) 345-352.
[14] M.C. Wang, L.Z. Ouyang, J.W. Liu, H. Wang, M. Zhu, Hydrogen generation from sodium borohydride hydrolysis accelerated by zinc chloride without catalyst:a kinetic study, J. Alloys Compounds 717(2017) 48-54.
[15] T. Sousa, V. Fernandes, P. Pinto, Y. Slavkov, L. Bosukov, C. Rangel, A sodium borohydride hydrogen generation reactor for stationary applications:experimental and reactor simulation studies, Chem. Eng. Sci. 84(2012) 70-79.
[16] H. Zhong, H. Wang, J.W. Liu, D.L. Sun, F. Fang, Q. Zhang, L.Z. Ouyang, M. Zhu, Enhanced hydrolysis properties and energy efficiency of MgH₂-base hydrides, J. Alloys Compounds 680(2016) 419-426.
[17] A. Babak, M. Korosh, A novel method for generating hydrogen by hydrolysis of highly activated aluminum nanoparticles in pure water, Int. J. Hydrog. Energy 34(2009) 7934-7938.
[18] Y.H. Liu, X.J. Liu, S.Y. Yang, C.P. Wang, Hydrogen generation from hydrolysis of activated Al-Bi, Al-Sn powders prepared by gas atomization method, Int. J. Hydrog. Energy 42(2017) 10943-10951.
[19] S. Zhong, C.L. Wu, Y.G. Chen, Z. Feng, Y. Zhao, Y.T. Xia, Enhanced hydrolysis performance and the air-stability of Mg-Ca hydride-chloride composites, J. Alloys Compounds 792(2019) 869-877.
[20] M.H. Huang, L.Z. Ouyang, H. Wang, J.W. Liu, M. Zhu, Hydrogen generation by hydrolysis of MgH₂ and enhanced kinetics performance of ammonium chloride introducing, Int. J. Hydrog. Energy 40(2015) 6145-6150.
[21] J. Liao, C.L. Wu, Y.G. Chen, Effect on hydrogen generation of microstructures of refined Si powders in KOH aqueous solution, Chinese J. Inorg. Chem. 34(2018) 1555-1565.
[22] U. Demirci, O. Akdim, J. Andrieux, J. Hannauer, R. Chamoun, P. Miele, Sodium borohydride hydrolysis as hydrogen generator:issues, state of the art and applicability upstream froma fuel cell, Fuel Cells 3(2010) 335-350.
[23] D.W. Zhuang, J.J. Zhang, H.B. Dai, P. Wang, Hydrogen generation from hydrolysis of solid sodium borohydride promoted by a cobaltemolybdenumeboron catalyst and aluminum powder, Int. J. Hydrog. Energy 38(2013) 10845-10850.
[24] H.B. Dai, Y. Liang, P. Wang, H.M. Cheng, Amorphous cobalt-boron/nickel foam as an effective catalyst for hydrogen generation from alkaline sodium borohydride solution, J. Power Sources 177(2008) 17-23.
[25] H.B. Dai, G.L. Ma, H.J. Xia, P. Wang, Combined usage of sodium Borohydride and aluminum powder for high-performance hydrogen generation, Fuel Cells 3(2011) 424-430.
[26] H. Schlesinger, C. Herbert, A. Brown, Finholt, R. James, Sodium borohydride, its hydrolysis and its use as a reducing agent and in the generation of hydrogen, J. Am. Chem. Soc. 75(1953) 215-219.
[27] A. Norbert, H. Sven, Silicon as energy carrier-facts and perspectives, Energy 31(2006) 1395-1402.
[28] L. Xu, A. Sobia, J.P. Hu, P. Peter, Ball-milled Si powder for the production of H₂ from water for fuel cell applications, Int. J. Hydrog. Energy 41(2016) 12730-12737.
[29] P. Brack, S. Dann, K. Wijayantha, A. Paul, F. Simon, An assessment of the viability of hydrogen generation from the reaction of silicon powder and sodium hydroxide solution for portable applications, Int. J. Energy Res. 41(2017) 220-228.
[30] M. Clifford, S. Buddhadev Kaufman, Hydrogen generation by hydrolysis of sodium tetrahydroborate:effects of acids and transition metals and their salts, J. Chem. Soc. Dalton Trans. (1985) 307-313.
[31] Y.B. Yao, T. Xie, Y.M. Gao, Handbook of Chemistry and Physics, Chemistry and Physics,, Science and Technology Press, Shanghai, 1985, 923-925.
[32] U. Demirci, O. Akdim, P. Miele, Aluminum chloride for accelerating hydrogen generation from sodium borohydride, J. Power Sources 192(2009) 310-315.
[33] Y. Nakamori, H.W. Li, K. Kikuchi, M. Aokib, K. Miwa, S. Towata, S. Orimoa, Thermodynamical stabilities of metal-borohydrides, J. Alloys Compounds 446(2007) 296-300.
[34] Y.A. Liu, X.H. Wang, Z.H. Dong, H.Z. Liu, S.Q. Li, H.W. Ge, M. Yan, Hydrogen generation from the hydrolysis of mg powder ball-milled with AlCl₃, Energy 53(2013) 147-152.
[35] Y.M. Xu, J. Chen, C.L. Wu, Y.G. Chen, J.F. Li, Z.Y. Li, Hydrogen generation from hydrolysis of NaBH₄-NH₃BH₃ composite promoted by AlCl₃, Int. J. Hydrog. Energy 41(2016) 16344-16351.
[36] J.F. Li, P.P. Liu, C.L. Wu, Y.G. Chen, Common ion effect in the hydrolysis reaction of Mg-Ca alloy hydride-salt composites, Int. J. Hydrog. Energy 42(2017) 1429-1435.
[37] N. Patel, A. Fernandes, Miotello, hydrogen generation by hydrolysis of NaBH₄ with efficient Co-P-B catalyst:a kinetic study, J. Power Sources 188(2009) 411-420.
[38] M.Q. Fan, L.X. Sun, F. Li, Study of the controllable reactivity of aluminum alloys and their promising application for hydrogen generation, Energy Convers. Manag. 51(2010) 594-599.

Promoted hydrolysis performances and mechanism of Si-NaBH₄-AlCl₃ in deionized water

Promoted hydrolysis performances and mechanism of Si-NaBH₄-AlCl₃ in deionized water

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