Weak base favoring the synthesis of highly ordered V-MCM-41 with well-dispersed vanadium and the catalytic performances on selective oxidation of benzyl alcohol

doi:10.1016/j.cjche.2020.02.027

中国化学工程学报 ›› 2020, Vol. 28 ›› Issue (5): 1424-1435.DOI: 10.1016/j.cjche.2020.02.027

• Materials and Product Engineering • 上一篇下一篇

Weak base favoring the synthesis of highly ordered V-MCM-41 with well-dispersed vanadium and the catalytic performances on selective oxidation of benzyl alcohol

Jing Zhao, Yifu Zhang, Lei Xu, Fuping Tian, Tao Hu, Changgong Meng

School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

收稿日期:2019-09-30 修回日期:2020-01-29 出版日期:2020-05-28 发布日期:2020-07-29
通讯作者: Yifu Zhang, Changgong Meng
基金资助:
This work was partially supported by the National Natural Science Foundation of China (Grant Nos. 21601026, 21771030), and Fundamental Research Funds for the Central Universities (DUT16RC(4)10, DUT18RC(6)008).

Weak base favoring the synthesis of highly ordered V-MCM-41 with well-dispersed vanadium and the catalytic performances on selective oxidation of benzyl alcohol

Jing Zhao, Yifu Zhang, Lei Xu, Fuping Tian, Tao Hu, Changgong Meng

School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

Received:2019-09-30 Revised:2020-01-29 Online:2020-05-28 Published:2020-07-29
Contact: Yifu Zhang, Changgong Meng
Supported by:
This work was partially supported by the National Natural Science Foundation of China (Grant Nos. 21601026, 21771030), and Fundamental Research Funds for the Central Universities (DUT16RC(4)10, DUT18RC(6)008).

摘要/Abstract

摘要： The key to improve the performance of heteroatom catalysts is to ensure the orderliness of catalysts and the good dispersion of heteroatoms. The alkalinity plays the indispensable role in synthetic process of V-MCM-41 catalyst. The excessive alkalinity of synthetic system will make the MCM-41 difficult to crystallize, even to dissolve. It is easy to accumulate for heteroatomic species in the system of low alkalinity. Herein, the highly ordered VMCM-41 with high vanadic content in framework is synthesized in the condition of excessive NH₃·H₂O in this paper. A series of characterization results prove the good dispersion of vanadium species, and most of vanadium gets into the framework of MCM-41 with the states of tetravalence and pentavalence. Furthermore, the modified MCM-41 by other transition metals is successful synthesized by the method of V-MCM-41 in this paper. The VMCM-41 shows well catalytic activity for the selective oxidation of benzyl alcohol, which up to 74.83% for the conversion of benzyl alcohol and 96.20% for selectivity of benzaldehyde when initial V/Si=0.10. The paper provides the possibility for industrial application of V-MCM-41 in the oxidation of benzyl alcohol for benzaldehyde. Besides, the work provides a significant idea for the synthesis of modified MCM-41 by well-dispersed transition metals.

关键词: V-MCM-41, Well-dispersed vanadium, Framework, Weak base, Benzyl alcohol, Selective oxidation

Abstract: The key to improve the performance of heteroatom catalysts is to ensure the orderliness of catalysts and the good dispersion of heteroatoms. The alkalinity plays the indispensable role in synthetic process of V-MCM-41 catalyst. The excessive alkalinity of synthetic system will make the MCM-41 difficult to crystallize, even to dissolve. It is easy to accumulate for heteroatomic species in the system of low alkalinity. Herein, the highly ordered VMCM-41 with high vanadic content in framework is synthesized in the condition of excessive NH₃·H₂O in this paper. A series of characterization results prove the good dispersion of vanadium species, and most of vanadium gets into the framework of MCM-41 with the states of tetravalence and pentavalence. Furthermore, the modified MCM-41 by other transition metals is successful synthesized by the method of V-MCM-41 in this paper. The VMCM-41 shows well catalytic activity for the selective oxidation of benzyl alcohol, which up to 74.83% for the conversion of benzyl alcohol and 96.20% for selectivity of benzaldehyde when initial V/Si=0.10. The paper provides the possibility for industrial application of V-MCM-41 in the oxidation of benzyl alcohol for benzaldehyde. Besides, the work provides a significant idea for the synthesis of modified MCM-41 by well-dispersed transition metals.

Key words: V-MCM-41, Well-dispersed vanadium, Framework, Weak base, Benzyl alcohol, Selective oxidation

Jing Zhao, Yifu Zhang, Lei Xu, Fuping Tian, Tao Hu, Changgong Meng. Weak base favoring the synthesis of highly ordered V-MCM-41 with well-dispersed vanadium and the catalytic performances on selective oxidation of benzyl alcohol[J]. 中国化学工程学报, 2020, 28(5): 1424-1435.

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Weak base favoring the synthesis of highly ordered V-MCM-41 with well-dispersed vanadium and the catalytic performances on selective oxidation of benzyl alcohol

Weak base favoring the synthesis of highly ordered V-MCM-41 with well-dispersed vanadium and the catalytic performances on selective oxidation of benzyl alcohol

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