Insight into SO2 poisoning and regeneration of one-pot synthesized Cu-SSZ-13 catalyst for selective reduction of NOx by NH3

doi:10.1016/j.cjche.2021.06.012

中国化学工程学报 ›› 2022, Vol. 46 ›› Issue (6): 184-193.DOI: 10.1016/j.cjche.2021.06.012

Insight into SO₂ poisoning and regeneration of one-pot synthesized Cu-SSZ-13 catalyst for selective reduction of NO_x by NH₃

Xin Yong², Hong Chen¹, Huawang Zhao², Miao Wei², Yingnan Zhao³, Yongdan Li^2,3

1 School of Environmental Engineering, Tianjin University, Tianjin 300072, China;
2 Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin Key Laboratory of Applied Catalysis Science and Technology, State Key Laboratory of Chemical Engineering (Tianjin University), School of Chemical Engineering, Tianjin University, Tianjin 300072, China;
3 Department of Chemical and Metallurgical Engineering, School of Chemical Engineering, Aalto University, Espoo 02150, Finland

收稿日期:2021-03-28 修回日期:2021-06-07 出版日期:2022-06-28 发布日期:2022-07-20
通讯作者: Hong Chen,E-mail:chenhong_0405@tju.edu.cn;Yongdan Li,E-mail:yongdan.li@aalto.fi
基金资助:
Financial supports from the Natural Science Foundation of Tianjin 19JCTPJC42300.

Insight into SO₂ poisoning and regeneration of one-pot synthesized Cu-SSZ-13 catalyst for selective reduction of NO_x by NH₃

Xin Yong², Hong Chen¹, Huawang Zhao², Miao Wei², Yingnan Zhao³, Yongdan Li^2,3

1 School of Environmental Engineering, Tianjin University, Tianjin 300072, China;
2 Collaborative Innovation Center of Chemical Science and Engineering (Tianjin), Tianjin Key Laboratory of Applied Catalysis Science and Technology, State Key Laboratory of Chemical Engineering (Tianjin University), School of Chemical Engineering, Tianjin University, Tianjin 300072, China;
3 Department of Chemical and Metallurgical Engineering, School of Chemical Engineering, Aalto University, Espoo 02150, Finland

Received:2021-03-28 Revised:2021-06-07 Online:2022-06-28 Published:2022-07-20
Contact: Hong Chen,E-mail:chenhong_0405@tju.edu.cn;Yongdan Li,E-mail:yongdan.li@aalto.fi
Supported by:
Financial supports from the Natural Science Foundation of Tianjin 19JCTPJC42300.

摘要/Abstract

摘要： The effects of SO₂ on an one-pot synthesized Cu-SSZ-13 catalyst for selective reduction of NO_x by NH₃ were examined. The addition of SO₂ inhibited NO_x conversion significantly below 300 ℃, while no effect on NO_x conversion was observed above 300 ℃. TGA, TPD, and XPS results showed that the deactivation was caused by the formation of (NH₄)₂SO₄, SO₂ chemisorption on the isolated Cu²⁺ ion sites, as well as the formation of CuSO₄-like species. Among them, the site-blocking effect of (NH₄)₂SO₄ on Cu²⁺ was the primary reason for deactivation. Fortunately, 89% of deNO_x activity of the poisoned catalyst was recovered after thermal treatment at 500 ℃ in air, where (NH₄)₂SO₄ was completely decomposed. The activity was further recovered with regeneration temperature increasing to 600 ℃, removing the adsorbed SO₂ on the Cu²⁺ sites. The regeneration at 600 ℃ could not recover the activity completely, because of the high stability of CuSO₄-like species.

关键词: Emission control, SCR, One-pot synthesis of Cu-SSZ-13, SO₂ poisoning, Activity regeneration

Abstract: The effects of SO₂ on an one-pot synthesized Cu-SSZ-13 catalyst for selective reduction of NO_x by NH₃ were examined. The addition of SO₂ inhibited NO_x conversion significantly below 300 ℃, while no effect on NO_x conversion was observed above 300 ℃. TGA, TPD, and XPS results showed that the deactivation was caused by the formation of (NH₄)₂SO₄, SO₂ chemisorption on the isolated Cu²⁺ ion sites, as well as the formation of CuSO₄-like species. Among them, the site-blocking effect of (NH₄)₂SO₄ on Cu²⁺ was the primary reason for deactivation. Fortunately, 89% of deNO_x activity of the poisoned catalyst was recovered after thermal treatment at 500 ℃ in air, where (NH₄)₂SO₄ was completely decomposed. The activity was further recovered with regeneration temperature increasing to 600 ℃, removing the adsorbed SO₂ on the Cu²⁺ sites. The regeneration at 600 ℃ could not recover the activity completely, because of the high stability of CuSO₄-like species.

Key words: Emission control, SCR, One-pot synthesis of Cu-SSZ-13, SO₂ poisoning, Activity regeneration

Xin Yong, Hong Chen, Huawang Zhao, Miao Wei, Yingnan Zhao, Yongdan Li. Insight into SO₂ poisoning and regeneration of one-pot synthesized Cu-SSZ-13 catalyst for selective reduction of NO_x by NH₃[J]. 中国化学工程学报, 2022, 46(6): 184-193.

参考文献

[1] A.M. Beale, F. Gao, I. Lezcano-Gonzalez, C.H.F. Peden, J. Szanyi, Recent advances in automotive catalysis for NO_x emission control by small-pore microporous materials, Chem. Soc. Rev. 44 (2015) 7371-7405
[2] J.H. Wang, H.W. Zhao, G. Haller, Y.D. Li, Recent advances in the selective catalytic reduction of NO_x with NH₃ on Cu-Chabazite catalysts, Appl. Catal. B:Environ. 202 (2017) 346-354
[3] J.H. Wang, H. Chen, Z.C. Hu, M.F. Yao, Y.D. Li, A review on the Pd-based three-way catalyst, Catal. Rev. 57 (2015) 79-144
[4] P. Li, X.Y. Chen, Y. D. Li, J.W. Schwank, A review on oxygen storage capacity of CeO₂-based materials:Influence factors, measurement techniques, and applications in reactions related to catalytic automotive emissions control, Catal. Today 327 (2019) 90-115
[5] H.W. Zhao, Y.N. Zhao, Y.H. Ma, X. Yong, M. Wei, H. Chen, C.J. Zhang, Y.D. Li, Enhanced hydrothermal stability of a Cu-SSZ-13 catalyst for the selective reduction of NO_x by NH₃ synthesized with SAPO-34 micro-crystallite as seed, J. Catal. 377 (2019) 218-223
[6] Y.L. Shan, J.P. Du, Y. Zhang, W.P. Shan, X.Y. Shi, Y.B. Yu, R.D. Zhang, X.J. Meng, F.S. Xiao, H. He, Selective catalytic reduction of NO_x with NH₃:opportunities and challenges of Cu-based small-pore zeolites, Natl. Sci. Rev. 8 (2021) nwab010
[7] D.W. Fickel, E. D'Addio, J.A. Lauterbach, R.F. Lobo, The ammonia selective catalytic reduction activity of copper-exchanged small-pore zeolites, Appl. Catal. B:Environ. 102 (2011) 441-448
[8] F. Gao, J.H. Kwak, J. Szanyi, C.H.F. Peden, Current understanding of Cu-exchanged chabazite molecular sieves for use as commercial diesel engine deNO_x catalysts, Top. Catal. 56 (2013) 1441-1459
[9] N. Zhu, Y.L. Shan, W.P. Shan, Y. Sun, K. Liu, Y. Zhang, H. He, Distinct NO₂ effects on Cu-SSZ-13 and Cu-SSZ-39 in the selective catalytic reduction of NO_x with NH₃, Environ. Sci. Technol. 54 (2020) 15499-15506
[10] Y.L. Shan, W.P Shan, X.Y. Shi, J.P. Du, Y.B. Yu, H. He, A comparative study of the activity and hydrothermal stability of Al-rich Cu-SSZ-39 and Cu-SSZ-13, Appl. Catal. B:Environ. 264 (2020) 118511
[11] Y.S. Cheng, C. Lambert, D.H. Kim, J.H. Kwak, S.J. Cho, C.H.F. Peden, The different impacts of SO₂ and SO₃ on Cu/zeolite SCR catalysts, Catal. Today 151 (2010) 266-270
[12] W.K. Su, Z.G. Li, Y.N. Zhang, C.C. Meng, J.H. Li, Identification of sulfate species and their influence on SCR performance of Cu/CHA catalyst, Catal. Sci. Technol. 7 (2017) 1523-1528
[13] Y.L. Shan, X.Y. Shi, Z.D. Yan, J.J. Liu, Y.B. Yu, H. He, Deactivation of Cu-SSZ-13 in the presence of SO₂ during hydrothermal aging, Catal. Today 320 (2019) 84-90
[14] L. Olsson, K. Wijayanti, K. Leistner, A. Kumar, S.Y. Joshi, K. Kamasamudram, N.W. Currier, A. Yezerets, A kinetic model for sulfur poisoning and regeneration of Cu/SSZ-13 used for NH₃-SCR, Appl. Catal. B:Environ. 183 (2016) 394-406
[15] K. Wijayanti, K.P. Xie, A. Kumar, K. Kamasamudram, L. Olsson, Effect of gas compositions on SO₂ poisoning over Cu/SSZ-13 used for NH₃-SCR, Appl. Catal. B:Environ. 219 (2017) 142-154
[16] Y. Jangjou, Q. Do, Y.T. Gu, L. G. Lim, H. Sun, D. Wang, A. Kumar, J.H. Li, L.C. Grabow, W.S. Epling, Nature of Cu active centers in Cu-SSZ-13 and their responses to SO₂ exposure, ACS Catal. 8 (2018) 1325-1337
[17] S. Dahlina, C. Lantto, J. Englund, B. Westerberg, F. Regali, M. Skoglundh, L. J. Pettersson, Chemical aging of Cu-SSZ-13 SCR catalysts for heavy-duty vehicles-Influence of sulfur dioxide, Catal. Today 320 (2019) 72-83
[18] K. Wijayanti, K. Leistner, S. Chand, A. Kumar, K. Kamasamudram, N.W. Currier, A. Yezerets, L. Olsson, Deactivation of Cu-SSZ-13 by SO₂ exposure under SCR conditions, Catal. Sci. Technol. 6 (2016) 2565-2579
[19] A.J. Shih, I. Khurana, H. Li, J. González, A. Kumar, C. Paolucci, T.M. Lardinois, C.B. Jones, J.D. Albarracin Caballero, K. Kamasamudram, A. Yezerets, W.N. Delgass, J.T. Miller, A.L. Villa, W.F. Schneider, R. Gounder, F.H. Ribeiro, Spectroscopic and kinetic responses of Cu-SSZ-13 to SO₂ exposure and implications for NO_x selective catalytic reduction, Appl. Catal. A:Gen. 574 (2019) 122-131
[20] L. Wei, D.W. Yao, F. Wu, B. Liu, X.H. Hu, X.W. Li, X.L. Wang, Impact of hydrothermal aging on SO₂ poisoning over Cu-SSZ-13 diesel exhaust SCR catalysts, In. Engin. Chem. Res. 58 (2019) 3949-3958
[21] Y. Jangjou, C.S. Sampara, Y.T. Gu, D. Wang, A. Kumar, J.H. Li, W.S. Epling, Mechanism-based kinetic modeling of Cu-SSZ-13 sulfation and desulfation for NH₃-SCR applications, Re. Chem. Engin. 4 (2019) 1038-1049
[22] J. Luo, D. Wang, A. Kumar, J.H. Li, K. Kamasamudram, N. Currier, A. Yezerets, Identification of two types of Cu sites in Cu/SSZ-13 and their unique responses to hydrothermal aging and sulfur poisoning, Catal. Today 267 (2016) 3-9
[23] D.W. Brookshear, J.G. Nam, K. Nguyen, T.J. Toops, A. Binder, Impact of sulfation and desulfation on NO_x reduction using Cu-chabazite SCR catalysts, Catal. Today 258 (2015) 359-366
[24] A. Kumar, M.A. Smith, K. Kamasamudram, N.W. Currier, H.M. An, A. Yezerets, Impact of different forms of feed sulfur on small-pore Cu-zeolite SCR catalyst, Catal. Today 231 (2014) 75-82
[25] A. Kumar, M.A. Smith, K. Kamasamudram, N.W. Currier, A. Yezerets, Chemical deSOx:An effective way to recover Cu-zeolite SCR catalysts from sulfur poisoning, Catal. Today 267 (2016) 10-16
[26] P.S. Hammershøi, Y. Jangjou, W.S. Epling, A.D. Jensen, T.V.W. Janssens, Reversible and irreversible deactivation of Cu-CHA NH₃-SCRcatalysts by SO₂ and SO₃, Appl. Catal. B:Environ. 226 (2018) 38-45
[27] Y. Jangjou, D. Wang, A. Kumar, J.H. Li, W.S. Epling, SO₂ poisoning of the NH₃-SCR reaction over Cu-SAPO-34:Effect of ammonium sulfate versus other S-containing species, ACS Catal. 6 (2016) 6612-6622
[28] M.Q. Shen, H.Y. Wen, T. Hao, T. Yu, D.Q. Fan, J. Wang, W. Li, J.Q. Wang, Deactivation mechanism of SO₂ on Cu/SAPO-34 NH₃-SCR catalysts:structure and active Cu²⁺, Catal. Sci. Technol. 5 (2015) 1741-1749
[29] M.Q. Shen, Y. Zhang, J.Q. Wang, C. Wang, J. Wang, Nature of SO₃ poisoning on Cu/SAPO-34 SCR catalysts, J. Catal. 358 (2018) 277-286
[30] L. Zhang, D. Wang, Y. Liu, K. Kamasamudram, J.H. Li, W. Epling, SO₂ poisoning impact on the NH₃-SCR reaction over a commercial Cu-SAPO-34 SCR catalyst, Appl. Catal. B:Environ. 156-157 (2014) 371-377
[31] Y. Jangjou, M. Ali, Q.Y. Chang, D. Wang, J.H. Li, A. Kumar, W.S. Epling, Effect of SO₂ on NH₃ oxidation over a Cu-SAPO-34 SCR catalyst, Catal. Sci. Technol. 6 (2016) 2679-2685
[32] C. Wang, J. Wang, J.Q. Wang, T. Yu, M.Q. Shen, W.L. Wang, W. Li, The effect of sulfate species on the activity of NH₃-SCR over Cu/SAPO-34, Appl. Catal. B:Environ. 204 (2017) 239-249
[33] K. Wijayanti, S. Andonova, A. Kumar, J.H. Li, K. Kamasamudram, N.W. Currier, A. Yezerets, L. Olsson, Impact of sulfur oxide on NH₃-SCR over Cu-SAPO-34, Appl. Catal. B:Environ. 166-167 (2015) 568-579
[34] J.P. Du, X.Y. Shi, Y.L. Shan, G.Y. Xu, Y. Sun, Y.J. Wang, Y.B. Yu, W.P. Shan, H. He, Effects of SO₂ on Cu-SSZ-39 catalyst for the selective catalytic reduction of NO_x with NH₃, Catal. Sci. Technol. 10 (2020) 1256-1263
[35] X. Yong, C.J. Zhang, M. Wei, P.P. Xie, Y.D. Li, Promotion of the performance of Cu-SSZ-13 for selective catalytic reduction of NO_x by ammonia in the presence of SO₂ during high temperature hydrothermal aging, J. Catal. 394 (2020) 228-235
[36] L.M. Ren, L.F. Zhu, C.G. Yang, Y.M. Chen, Q. Sun, H.Y. Zhang, C.J. Li, F. Nawaz, X.J. Meng, F.S. Xiao, Designed copper-amine complex as an efficient template for one-pot synthesis of Cu-SSZ-13 zeolite with excellent activity for selective catalytic reduction of NO_x by NH₃, Chem. Commun. 47 (2011) 9789-9791
[37] L.J. Xie, F.D. Liu, L.M. Ren, X.Y. Shi, F.S. Xiao, H. He, Excellent performance of One-pot synthesized Cu-SSZ-13 catalyst for the selective catalytic reduction of NO_x with NH₃, Environ. Sci. Technol. 48 (2014) 566-572
[38] F. Gao, E.D. Walter, E.M. Karp, J.Y. Luo, R.G. Tonkyn, J.H. Kwak, J. Szanyi, C.H.F. Peden, Structure-activity relationships in NH₃-SCR over Cu-SSZ-13 as probed by reaction kinetics and EPR studies, J. Catal. 300 (2013) 20-29
[39] H. Jiang, B. Guan, X.S. Peng, R. Zhan, H. Lin, Z. Huang, Influence of synthesis method on catalytic properties and hydrothermal stability of Cu/SSZ-13 for NH₃-SCR reaction, Chem. Eng. J. 379 (2020) 122358
[40] T. Zhang, H.Z. Chang, Y.C. You, C.N. Shi, J.H. Li, Excellent activity and selectivity of one-pot synthesized Cu-SSZ-13 catalyst in the selective catalytic oxidation of ammonia to nitrogen, Environ. Sci. Technol. 52 (2018) 4802-4808
[41] D. Wang, F. Gao, C.H.F. Peden, J.H. Li, K. Kamasamudram, W.S. Epling, Selective catalytic reduction of NO_x with NH₃ over a Cu-SSZ-13 catalyst prepared by a solid-state ion-exchange method, ChemCatChem 6 (2014) 1579-1583
[42] J. Song, Y.L. Wang, E.D. Walter, N.M. Washton, D.H. Mei, L. Kovarik, M.H. Engelhard, S. Prodinger, Y. Wang, C.H.F. Peden, F. Gao, Toward rational design of Cu/SSZ-13 selective catalytic reduction catalysts:implications from atomic-level understanding of hydrothermal stability, ACS Catalysis 7 (2017) 8214-8227
[43] R. Martínez-Franco, M. Moliner, P. Concepcion, J.R. Thogersen, A. Corma, Synthesis, characterization and reactivity of high hydrothermally stable Cu-SAPO-34 materials prepared by "one-pot" processes, J. Catal. 314 (2014) 73-82
[44] H.W. Zhao, Y.N. Zhao, M.K. Liu, X.H. Li, Y.H. Ma, X. Yong, H. Chen, Y.D. Li, Phosphorus modification to improve the hydrothermal stability of a Cu-SSZ-13 catalyst for selective reduction of NO_x with NH₃, Appl. Catal. B:Environ. 252 (2019) 230-239
[45] X.S. Dong, J.H. Wang, H.W. Zhao, Y.D. Li, The promotion effect of CeOx on Cu-SAPO-34 catalyst for selective catalytic reduction of NO_x with ammonia, Catal. Today 258, (2015) 28-34
[46] R.M. Ferrizz, R.J. Gorte, J.M. Vohs, TPD and XPS investigation of the interaction of SO₂ with model ceria catalysts, Catal. Lett. 82(1-2) (2002) 123-129
[47] L.N. Kong, S.J. Zou, J. Mei, Y. Geng, H. Zhao, S.J. Yang, Outstanding resistance of H₂S-modified Cu/TiO₂ to SO₂ for capturing gaseous Hg⁰ from nonferrous metal smelting flue gas:Performance and reaction mechanism, Environ. Sci. Technol. 52 (2018) 10003-10010
[48] S.J. Zou, Y. Liao, S.C. Xiong, N. Huang, Y. Geng, S.J. Yang, H₂S-modified Fe-Ti spinel:A recyclable magnetic sorbent for recovering gaseous elemental mercury from flue gas as a Co-benefit of wet electrostatic precipitators, Environ. Sci. Technol. 51 (2017) 3426-3434
[49] T. Zhang, J.M. Li, J. Liu, D.X. Wang, Z. Zhao, K. Cheng, J.H. Li, High activity and wide temperature window of Fe-Cu-SSZ-13 in the selective catalytic reduction of NO with ammonia, AlChE J. 61 (2015) 3825-3837
[50] P.N.R. Vennestrøm, A. Katerinopoulou, R.R. Tiruvalam, A. Kustov, P.G. Moses, P. Concepcion, A. Corma, Migration of Cu ions in SAPO-34 and its impact on selective catalytic reduction of NO_x with NH₃, ACS Catal. 3 (2013) 2158-2161
[51] H.W. Zhao, H.S. Li, X.H. Li, M.K. Liu, Y.D. Li, The promotion effect of Fe to Cu-SAPO-34 for selective catalytic reduction of NO_x with NH₃, Catal. Today 297 (2017) 84-91
[52] J.F. Moulder, W.F. Stickle, P.E. Scobol, K.D. Bomben, Handbook of X-ray Photoelectron Spectroscopy United States of America, 1992.
[53] S.L. Bergman, S. Dahlin, V.V. Mesilov, Y. Xiao, J. Englund, S. Xi, C.H. Tang, M. Skoglundh, L.J. Pettersson, S.L. Bernasek, In-situ studies of oxidation/reduction of copper in Cu-CHA SCR catalysts:Comparison of fresh and SO₂-poisoned catalysts, Appl. Catal. B:Environ. 269 (2020) 118722

Insight into SO₂ poisoning and regeneration of one-pot synthesized Cu-SSZ-13 catalyst for selective reduction of NO_x by NH₃

Insight into SO₂ poisoning and regeneration of one-pot synthesized Cu-SSZ-13 catalyst for selective reduction of NO_x by NH₃

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Tao Sun, Shubin Li, Guangsheng Pei, Lei Chen, Weiwen Zhang. Towards understanding the mechanism of n-hexane tolerance in Synechocystis sp. PCC 6803[J]. 中国化学工程学报, 2023, 59(7): 128-134.
[2]	Shuang Qiu, Yonghou Xiao, Haoran Wu, Shengnan Lu, Qidong Zhao, Gaohong He. One-pot synthesis of bimetallic CeCu-SAPO-34 for high-efficiency selective catalytic reduction of nitrogen oxides with NH₃ at low temperature[J]. 中国化学工程学报, 2023, 56(4): 193-202.
[3]	Yaoyao Peng, Lei Song, Siru Lu, Ziyu Su, Kui Ma, Siyang Tang, Shan Zhong, Hairong Yue, Bin Liang. Superior resistance to alkali metal potassium of vanadium-based NH₃-SCR catalyst promoted by the solid superacid SO₄^2--TiO₂[J]. 中国化学工程学报, 2023, 55(3): 246-256.
[4]	Fei Wang, Zhiyuan Bi, Lifeng Ding, Qingyuan Yang. Large-scale computational screening of metal–organic frameworks for D₂/H₂ separation[J]. 中国化学工程学报, 2023, 54(2): 323-330.
[5]	Xueguang Li, Mengyan Yu, Changfa Zhang, Xiangtong Li, Guangqing Liu, Jianjun Dai, Chunbao Zhou, Yang Liu, Jie Fu, Yingwen Zhang, Bang Yao. Co-pyrolysis of soybean soapstock with iron slag/aluminum scrap, and characterization and analysis of their products[J]. 中国化学工程学报, 2023, 53(1): 25-36.
[6]	Huawang Zhao, Xiaomin Wu, Zhiwei Huang, Ziyi Chen, Guohua Jing. A comparative study of the thermal and hydrothermal aging effect on Cu-SSZ-13 for the selective catalytic reduction of NO_x with NH₃[J]. 中国化学工程学报, 2022, 45(5): 68-77.
[7]	Zhen Wan, Youjun Lu. Numerical simulation of local and global mixing/segregation characteristics in a gas–solid fluidized bed[J]. 中国化学工程学报, 2022, 44(4): 72-86.
[8]	Hanghang Li, Wei Zhao, Licheng Wu, Qian Wang, Danhong Shang, Qin Zhong. Boosting low-temperature selective catalytic reduction of NO with NH₃ of V₂O₅/TiO₂ catalyst via B-doping[J]. 中国化学工程学报, 2022, 44(4): 377-383.
[9]	Pengnan Ma, Jiankang Wang, Hanxiao Meng, Laiquan Lv, Hao Fang, Kefa Cen, Hao Zhou. Influence of coke rate on thermal treatment of waste selective catalytic reduction (SCR) catalyst during iron ore sintering[J]. 中国化学工程学报, 2022, 42(2): 415-423.
[10]	Guangyao Zhao, Minglei Yang, Wenli Du, Feifei Shen, Feng Qian. A stochastic reconstruction strategy based on a stratified library of structural descriptors and its application in the molecular reconstruction of naphtha[J]. 中国化学工程学报, 2022, 51(11): 153-167.
[11]	Dongqi An, Yuyao Yang, Weixin Zou, Yandi Cai, Qing Tong, Jingfang Sun, Lin Dong. Insight into the promotional mechanism of Cu modification towards wide-temperature NH₃-SCR performance of NbCe catalyst[J]. 中国化学工程学报, 2022, 50(10): 301-309.
[12]	Ben Liu, Nangui Lv, Chan Wang, Hongwei Zhang, Yuanyuan Yue, Jingdong Xu, Xiaotao Bi, Xiaojun Bao. Redistributing Cu species in Cu-SSZ-13 zeolite as NH₃-SCR catalyst via a simple ion-exchange[J]. 中国化学工程学报, 2022, 41(1): 329-341.
[13]	Weipeng Lu, Xuefeng Yan. Balanced multiple weighted linear discriminant analysis and its application to visual process monitoring[J]. 中国化学工程学报, 2021, 36(8): 128-137.
[14]	Piqiang Tan, Xiaoyu Li, Shiyan Wang, Zhiyuan Hu, Diming Lou. Selective catalytic reduction failure of low NH₃-NO_x ratio[J]. 中国化学工程学报, 2021, 32(4): 231-240.
[15]	Yudong Shen, Hao Liang, Zuwei Liao, Binbo Jiang, Jingdai Wang, Yongrong Yang, Minggang Li, Yibin Luo, Xingtian Shu. Pore plugging effects on the performance of ZSM-5 catalyst in MTP reaction using a discrete model[J]. 中国化学工程学报, 2021, 32(4): 253-263.