Interfacial Tension of CO2 and Organic Liquid under High Pressure and Temperature

doi:10.1016/j.cjche.2014.09.042

›› 2014, Vol. 22 ›› Issue (11/12): 1302-1306.DOI: 10.1016/j.cjche.2014.09.042

Interfacial Tension of CO₂ and Organic Liquid under High Pressure and Temperature

Zihao Yang^1,2, Mingyuan Li^1,3, Bo Peng^1,2, Meiqin Lin^1,2, Zhaoxia Dong^1,2, Yong Ling ¹

1 Enhanced Oil Recovery Research Institute, China University of Petroleum, Beijing 102249, China;
2 Key Laboratory of Enhanced Oil Recovery, China National Petroleum Corporation (CNPC), Beijing 102249, China;
3 State Key Laboratory of Heavy Oil Processing, Beijing 102249, China

收稿日期:2013-01-28 修回日期:2013-07-08 出版日期:2014-12-28 发布日期:2014-12-24
通讯作者: Zihao Yang
基金资助:
Supported by the National Basic Research Program of China (2011CB707305), the National Key Technologies R&D Program (2012BAC24B00), National Nature Science Foundation of China(51304222), the CNPC Innovation Foundation (2013D-5006-0204) and the Science Foundation of China University of Petroleum (YJRC-2013-20).

Interfacial Tension of CO₂ and Organic Liquid under High Pressure and Temperature

Zihao Yang^1,2, Mingyuan Li^1,3, Bo Peng^1,2, Meiqin Lin^1,2, Zhaoxia Dong^1,2, Yong Ling ¹

1 Enhanced Oil Recovery Research Institute, China University of Petroleum, Beijing 102249, China;
2 Key Laboratory of Enhanced Oil Recovery, China National Petroleum Corporation (CNPC), Beijing 102249, China;
3 State Key Laboratory of Heavy Oil Processing, Beijing 102249, China

Received:2013-01-28 Revised:2013-07-08 Online:2014-12-28 Published:2014-12-24
Supported by:
Supported by the National Basic Research Program of China (2011CB707305), the National Key Technologies R&D Program (2012BAC24B00), National Nature Science Foundation of China(51304222), the CNPC Innovation Foundation (2013D-5006-0204) and the Science Foundation of China University of Petroleum (YJRC-2013-20).

摘要/Abstract

摘要： In order to investigate the effect of organic liquidmolecular structure and the intermolecular force operatingwith CO₂ molecules and organic liquid molecules on interfacial tension (IFT) between CO₂ and organic liquid at the first contact, the interfacial tension between CO₂ and hexane, octane, ethanol and cyclohexane at different temperatures and pressures ismeasured by using the pendant drop method and the axisymmetric drop shape analysis (ADSA). The results show that the interfacial tension between CO₂ and organic liquids is affected by the polarity and the structure of the organic liquid molecule obviously. The intermolecular force operating within CO₂ molecules or organic liquid, and that between CO₂ and organic liquids molecules play a dominate role on the interfacial tension between CO₂ and the organic liquids.

关键词: Carbon dioxide, Organic liquids, Interfacial tension, ADSA

Abstract: In order to investigate the effect of organic liquidmolecular structure and the intermolecular force operatingwith CO₂ molecules and organic liquid molecules on interfacial tension (IFT) between CO₂ and organic liquid at the first contact, the interfacial tension between CO₂ and hexane, octane, ethanol and cyclohexane at different temperatures and pressures ismeasured by using the pendant drop method and the axisymmetric drop shape analysis (ADSA). The results show that the interfacial tension between CO₂ and organic liquids is affected by the polarity and the structure of the organic liquid molecule obviously. The intermolecular force operating within CO₂ molecules or organic liquid, and that between CO₂ and organic liquids molecules play a dominate role on the interfacial tension between CO₂ and the organic liquids.

Key words: Carbon dioxide, Organic liquids, Interfacial tension, ADSA

Zihao Yang, Mingyuan Li, Bo Peng, Meiqin Lin, Zhaoxia Dong, Yong Ling . Interfacial Tension of CO₂ and Organic Liquid under High Pressure and Temperature[J]. , 2014, 22(11/12): 1302-1306.

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Interfacial Tension of CO₂ and Organic Liquid under High Pressure and Temperature

Interfacial Tension of CO₂ and Organic Liquid under High Pressure and Temperature

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