Production of Bio-gasoline by Co-cracking of Acetic Acid in Bio-oil and Ethanol

doi:10.1016/S1004-9541(14)60013-6

Chinese Journal of Chemical Engineering ›› 2014, Vol. 22 ›› Issue (1): 98-103.DOI: 10.1016/S1004-9541(14)60013-6

• 能源、资源与环境技术 • 上一篇下一篇

Production of Bio-gasoline by Co-cracking of Acetic Acid in Bio-oil and Ethanol

王树荣, 王誉蓉, 蔡勤杰, 郭祚刚

State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China

收稿日期:2012-10-20 修回日期:2013-01-30 出版日期:2014-01-05 发布日期:2014-01-04
通讯作者: WANG Shurong
基金资助:
Supported by the National Natural Science Foundation of China (51276166), the National Science Technology Supporting Plan Through Contract (2011BAD22B06), the Zhejiang Provincial Natural Science Foundation (R1110089) and the Program for New Century Excellent Talents in University (NCET-10-0741).

Production of Bio-gasoline by Co-cracking of Acetic Acid in Bio-oil and Ethanol

WANG Shurong, WANG Yurong, CAI Qinjie, GUO Zuogang

State Key Laboratory of Clean Energy Utilization, Zhejiang University, Hangzhou 310027, China

Received:2012-10-20 Revised:2013-01-30 Online:2014-01-05 Published:2014-01-04
Contact: WANG Shurong
Supported by:
Supported by the National Natural Science Foundation of China (51276166), the National Science Technology Supporting Plan Through Contract (2011BAD22B06), the Zhejiang Provincial Natural Science Foundation (R1110089) and the Program for New Century Excellent Talents in University (NCET-10-0741).

摘要/Abstract

摘要： Acetic acid was selected as the model compound representing the carboxylic acids present in bio-oil. This work focuses the co-cracking of acetic acid with ethanol for bio-gasoline production. The influences of reaction temperature and pressure on the conversion of reactants as well as the selectivity and composition of the crude gasoline phase were investigated. It was found that increasing reaction temperature benefited the conversion of reactants and pressurized cracking produced a higher crude gasoline yield. At 400℃ and 1 MPa, the conversion of the reactants reached over 99% and the selectivity of the gasoline phase reached 42.79% (by mass). The gasoline phase shows outstanding quality, with a hydrocarbon content of 100%.

关键词: bio-oil, co-cracking, acetic acid, ethanol, hydrocarbons

Abstract: Acetic acid was selected as the model compound representing the carboxylic acids present in bio-oil. This work focuses the co-cracking of acetic acid with ethanol for bio-gasoline production. The influences of reaction temperature and pressure on the conversion of reactants as well as the selectivity and composition of the crude gasoline phase were investigated. It was found that increasing reaction temperature benefited the conversion of reactants and pressurized cracking produced a higher crude gasoline yield. At 400℃ and 1 MPa, the conversion of the reactants reached over 99% and the selectivity of the gasoline phase reached 42.79% (by mass). The gasoline phase shows outstanding quality, with a hydrocarbon content of 100%.

Key words: bio-oil, co-cracking, acetic acid, ethanol, hydrocarbons

王树荣, 王誉蓉, 蔡勤杰, 郭祚刚. Production of Bio-gasoline by Co-cracking of Acetic Acid in Bio-oil and Ethanol[J]. Chinese Journal of Chemical Engineering, 2014, 22(1): 98-103.

WANG Shurong, WANG Yurong, CAI Qinjie, GUO Zuogang. Production of Bio-gasoline by Co-cracking of Acetic Acid in Bio-oil and Ethanol[J]. Chin.J.Chem.Eng., 2014, 22(1): 98-103.

参考文献

1 Butler, E., Devlin, G., Meier, D., McDonnell, K., "A review of recent laboratory research and commercial developments in fast pyrolysis and upgrading", Renew. Sust. Energy Rev., 15 (8), 4171-4186 (2011).

2 Bridgwater, A.V., "Review of fast pyrolysis of biomass and product upgrading", Biomass Bioenergy, 38, 68-94 (2012).

3 Czernik, S., Bridgwater, A.V., "Overview of applications of biomass fast pyrolysis oil", Energy Fuels, 18 (2), 590-598 (2004).

4 Mortensen, P.M., Grunwaldta, J.D., Jensena, P.A., Knudsenc, K.G., Jensen, A.D., "A review of catalytic upgrading of bio-oil to engine fuels", Appl. Catal. A, 407, 1-19 (2011).

5 Park, H.J., Jeon, J.K., Suh, D.J., Suh, Y.W., Heo, H.S., Park Y.K., "Catalytic vapor cracking for improvement of bio-oil quality", Catal. Surv. Asia, 15 (3), 161-180 (2011).

6 Valle, B., Gayubo, A.G., Aguayo A.T., Olazar, M., Bilbao, J., "Selective production of aromatics by crude bio-oil valorization with a nickel-modified HZSM-5 zeolite catalyst", Energy Fuels, 24 (3), 2060-2070 (2010).

7 Luo, Z., Wang, S., Liao, Y., Zhou, J., Gu, Y., Cen, K., "Research on biomass fast pyrolysis for liquid fuel", Biomass Bioenergy, 26 (5), 455-462 (2004).

8 Guo, X., Wang, S., Wang, Q., Guo, Z., Luo, Z., "Properties of bio-oil from fast pyrolysis of rice husk", Chin. J. Chem. Eng., 19 (1), 116-121 (2011).

9 Adjaye, J.D., Bakhshi, N.N., "Production of hydrocarbons by catalytic upgrading of a fast pyrolysis bio-oil. Part I: conversion over various catalysts", Fuel Process. Technol., 45 (3), 161-183 (1995).

10 Gayubo, A.G., Aguayo, A.T., Atutxa, A., Aguado, R., Bilbao, J., "Transformation of oxygenate components of biomass pyrolysis oil on a HZSM-5 zeolite. I. Alcohols and phenols", Ind. Eng. Chem. Res., 43 (11), 2610-2618 (2004).

11 Gayubo, A.G., Aguayo, A.T., Atutxa, A., Aguado R., Olazar, M., Bilbao, J., "Transformation of oxygenate components of biomass pyrolysis oil on a HZSM-5 zeolite. H. Aldehydes, ketones, and acids", Ind. Eng. Chem. Res., 43 (11), 2619-2626 (2004).

12 Mentzel, U.V., Holm, M.S., "Utilization of biomass: conversion of model compounds to hydrocarbons over zeolite H-ZSM-5", Appl. Catal., A, 396, 59-67 (2011).

13 Lin, Y., Tanaka, S., "Ethanol fermentation from biomass resources: current state and prospects", Appl. Microbiol. Biotechnol., 69 (6), 627-642 (2006).

14 Wang, S.R., Guo, X., Liang, T., Zhou, Y., Luo, Z., "Mechanism research on cellulose pyrolysis by Py-GC/MS and subsequent density functional theory studies", Bioresour. Technol., 104, 722-728 (2012).

15 Peng, Y., Wu, S., "The structural and thermal characteristics of wheat straw hemicelluloses", J. Anal. Appl. Pyrolysis, 88 (2), 134-139 (2010).

16 Demirbas, A., "The influence of temperature on the yields of compounds existing in bio-oils obtained from biomass samples via pyrolysis", Fuel Process. Technol., 88 (6), 591-597 (2007).

17 Wang, S., Gu, Y., Liu, Q., Yao, Y., Guo, Z., Luo, Z., Cen, K., "Separation of bio-oil by molecular distillation", Fuel Process. Technol., 90 (5), 738-745 (2009).

18 Guo, Z., Wang, S., Gu, Y., Xu, G., Li, X., Luo, Z., "Separation characteristics of biomass pyrolysis oil in molecular distillation", Sep. Purif. Technol., 76 (1), 52-57 (2010).

19 Guo, Z., Wang, S., Zhu, Y., Luo, Z., Cen, K., "Separation of acid compounds for refining biomass pyrolysis oil", J. Fuel Chem. Technol., 37 (1), 49-52 (2009).

20 Wang, S., Cai, Q., Guo, Z., Wang, Y., Wang, X., "Renewable gasoline produced by co-cracking of methanol and ketones in bio-oil", Bioresourc., 7 (4), 5019-5031 (2012).

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Production of Bio-gasoline by Co-cracking of Acetic Acid in Bio-oil and Ethanol

Production of Bio-gasoline by Co-cracking of Acetic Acid in Bio-oil and Ethanol

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