Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

doi:10.1016/j.cjche.2017.05.021

Chinese Journal of Chemical Engineering ›› 2018, Vol. 26 ›› Issue (3): 601-607.DOI: 10.1016/j.cjche.2017.05.021

• Energy, Resources and Environmental Technology • 上一篇下一篇

Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

Moses Arowo^1,2, Zemeng Zhao^1,3, Guangjun Li^1,4, Guangwen Chu^1,3, Baochang Sun^1,3, Lei Shao^1,3

1 State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
2 Department of Chemical & Process Engineering, Moi University, 3900-3100 Eldoret, Kenya;
3 Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China;
4 Beijing Yanjing Beer Co. Ltd., Beijing 101300, China

收稿日期:2017-02-27 修回日期:2017-05-10 出版日期:2018-03-28 发布日期:2018-04-18
通讯作者: Baochang Sun, Lei Shao
基金资助:
Supported by the National Natural Science Foundation of China (21276013, 21676008) and Specialized Research Fund for the Doctoral Program of Higher Education of China (20130010110001).

Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

Moses Arowo^1,2, Zemeng Zhao^1,3, Guangjun Li^1,4, Guangwen Chu^1,3, Baochang Sun^1,3, Lei Shao^1,3

1 State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China;
2 Department of Chemical & Process Engineering, Moi University, 3900-3100 Eldoret, Kenya;
3 Research Center of the Ministry of Education for High Gravity Engineering and Technology, Beijing University of Chemical Technology, Beijing 100029, China;
4 Beijing Yanjing Beer Co. Ltd., Beijing 101300, China

Received:2017-02-27 Revised:2017-05-10 Online:2018-03-28 Published:2018-04-18
Contact: Baochang Sun, Lei Shao
Supported by:
Supported by the National Natural Science Foundation of China (21276013, 21676008) and Specialized Research Fund for the Doctoral Program of Higher Education of China (20130010110001).

摘要/Abstract

摘要： The study herein investigated the effectiveness of simultaneous use of ozone and hydrogen peroxide (O₃/H₂O₂ process) to degrade o-phenylenediamine (o-PDA) in a simulated wastewater. A rotor-stator reactor (RSR) was employed to create a high-gravity environment in order to enhance ozone-liquid mass transfer rate and possibly improve the degradation rate of o-PDA. The degradation efficiency of o-PDA (η) as well as the overall gas-phase volumetric mass transfer coefficient (K_Ga) were determined under different operating conditions of H₂O₂ concentration, initial o-PDA concentration, temperature of reaction, initial pH and rotation speed of RSR in attempt to establish the optimal conditions. Chemical oxygen demand reduction rate (r_COD) of wastewater treated at a particular set of conditions was also analyzed. Additionally, the intermediate products of degradation were identified using a gas chromatography-mass spectrometer (GC/MS) to further evaluate the extent of o-PDA degradation as well as establish its possible degradation pathway. Results were validated by comparison with those of sole use of ozone (O₃ process), and it was noted that η, K_Ga and r_COD achieved by O₃/H₂O₂ process was 24.4%, 31.6% and 25.2% respectively higher than those of O₃ process, indicating that H₂O₂ can greatly enhance ozonation of o-PDA. This work further demonstrates that an RSR can significantly intensify ozone-liquid mass transfer rate and thus provides a feasible intensification means for the ozonation of o-PDA as well as other recalcitrant organics.

关键词: Degradation, Environment, Organic compounds, Oxidation, Ozone, Rotor-stator reactor

Abstract: The study herein investigated the effectiveness of simultaneous use of ozone and hydrogen peroxide (O₃/H₂O₂ process) to degrade o-phenylenediamine (o-PDA) in a simulated wastewater. A rotor-stator reactor (RSR) was employed to create a high-gravity environment in order to enhance ozone-liquid mass transfer rate and possibly improve the degradation rate of o-PDA. The degradation efficiency of o-PDA (η) as well as the overall gas-phase volumetric mass transfer coefficient (K_Ga) were determined under different operating conditions of H₂O₂ concentration, initial o-PDA concentration, temperature of reaction, initial pH and rotation speed of RSR in attempt to establish the optimal conditions. Chemical oxygen demand reduction rate (r_COD) of wastewater treated at a particular set of conditions was also analyzed. Additionally, the intermediate products of degradation were identified using a gas chromatography-mass spectrometer (GC/MS) to further evaluate the extent of o-PDA degradation as well as establish its possible degradation pathway. Results were validated by comparison with those of sole use of ozone (O₃ process), and it was noted that η, K_Ga and r_COD achieved by O₃/H₂O₂ process was 24.4%, 31.6% and 25.2% respectively higher than those of O₃ process, indicating that H₂O₂ can greatly enhance ozonation of o-PDA. This work further demonstrates that an RSR can significantly intensify ozone-liquid mass transfer rate and thus provides a feasible intensification means for the ozonation of o-PDA as well as other recalcitrant organics.

Key words: Degradation, Environment, Organic compounds, Oxidation, Ozone, Rotor-stator reactor

Moses Arowo, Zemeng Zhao, Guangjun Li, Guangwen Chu, Baochang Sun, Lei Shao. Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology[J]. Chinese Journal of Chemical Engineering, 2018, 26(3): 601-607.

参考文献

[1] C. Ramshaw, R. H. Mallison, Imperial chemical industries limited, Euro. Pat., 0002568(1979).

[2] Y. Luo, G.W. Chu, H.K. Zou, Y. Xiang, L. Shao, J. Chen, Characteristics of a two stage counter-current rotating packed bed for continuous distillation, Chem. Eng. Process. 52(2012) 55-62.

[3] W.H. Chen, Y. Syu, Hydrogen production from water gas shift reaction in a high gravity (Higee) environment using a rotating packed bed, Int. J. Hydrog. Energy 35(2010) 10179-10189.

[4] A. Chandra, P. Goswami, D.P. Rao, Characteristics of flow in a rotating packed bed (Higee) with split packing, Ind. Eng. Chem. Res. 44(2005) 4051-4060.

[5] H. Zhao, L. Shao, J.F. Chen, High-gravity process intensification technology and application, Chem. Eng. J. 156(2010) 588-593.

[6] G.Q. Wang, Z.C. Xu, Y.L. Yu, J.B. Ji, Performance of a rotating zigzag bed-A new HIGEE, Chem. Eng. Process. 47(2008) 2131-2139.

[7] J. Burns, C. Ramshaw, Process intensification:Visual study of liquid maldistribution in rotating packed beds, Chem. Eng. Sci. 51(1996) 1347-1352.

[8] Y. H. Song, G. W. Chu, J. M. Chen, J. F. Chen., A rotor-stator reactor and its application, China Patent, 200410042631.6(2006).

[9] G.W. Chu, Y. Song, H. Yang, J.M. Chen, H. Chen, J.F. Chen, Micromixing efficiency of a novel rotor-stator reactor, Chem. Eng. J. 128(2007) 191-196.

[10] Z. Zhao, B. Sun, M. Arowo, G.W. Chu, J.F. Chen, L. Shao, Study on the hydrodynamic characteristics of a rotor-stator reactor by electrical conductance and response time technique, Chem. Eng. Process. 109(2016) 158-163.

[11] Y. Li, H. Wang, M. Arowo, B. Sun, J.F. Chen, L. Shao, Synthesis of nano-Ce_0.5Zr_0.5O₂ by absorption of ammonia into water-in-oil microemulsion in a rotor-stator reactor, J. Nanopart. Res. 17(2015) 51-61.

[12] G.W. Chu, Y.H. Song, J.M. Chen, H. Chen, Preparation of nano-CaCO₃ by rotor stator reactor, Chem. Ind. Eng. Prog. 24(2005) 545-548(in Chinese).

[13] H. Wang, Y. Li, Y. Zhang, J.F. Chen, G.W. Chu, L. Shao, Preparation of CeO₂ nanosupport in a novel rotor-stator reactor and its use in Au-based catalyst for CO oxidation, Powder Technol. 273(2015) 191-196.

[14] K. Ghasemi, A. Rezvani, A. Shokrollahi, I. Razak, M. Refahi, A. Moghimi, M. Rosli, Copper(Ⅱ) ion catalytic oxidation of o-phenylenediamine and characterization, X-ray crystal structure and solution studies of the final product[DAPH] [H₃O] [Cu(dipic)2].3H₂O, J. Mol. Struct. 1096(2015) 102-109.

[15] L. Mei, L. Tai, F. Tao, S. Jie, L. Rong, A novel synthesis of 2,3-diaminophenazine, Res. Chem. Intermed. 38(2012) 499-505.

[16] A.N. Ejhieh, Z. Salimi, Heterogeneous photodegradation catalysis of ophenylenediamine using CuO/X zeolite, Appl. Catal. A Gen. 390(2010) 110-118.

[17] H. Liu, Z. Wang, Y. Liu, J. Xiao, C. Wang, Enthalpy change and mechanism of oxidation of o-phenylenediamine by hydrogen peroxide catalyzed by horseradish peroxidase, Thermochim. Acta 443(2006) 173-178.

[18] T. Ono, K. Kawakami, M. Goto, S. Furusaki, Catalytic oxidation of ophenylenediamine by cytochrome c encapsulated in reversed micelles, J. Mol. Catal. B Enzym. 11(2001) 955-959.

[19] Z. Zeng, H.K. Zou, X. Li, B. Sun, J.F. Chen, L. Shao, Ozonation of phenol with O₃/Fe(Ⅱ) in acidic environment in a rotating packed bed, Ind. Eng. Chem. Res. 51(2012) 10509-10516.

[20] C.A. Quiroz, D.C. Barrera, M.G. Roa, B.P. Hernandez, R. Romero, R. Natividad, Wastewater ozonation catalyzed by iron, Ind. Eng. Chem. Res. 50(2011) 2488-2494.

[21] S.C. Kwon, J.Y. Kim, S.M. Yoon, W. Bae, K.S. Kang, Y.W. Rhee, Treatment characteristic of 1,4-dioxane by ozone-based advanced oxidation processes, Ind. Eng. Chem. 18(2012) 1951-1955.

[22] P. Faria, J.O. O'rfa, M. Pereira, Ozonation of aniline promoted by activated carbon, Chemosphere 67(2007) 809-815.

[23] S. Nelieu, L. Kerhoas, J. Einhorn, Degradation of atrazine into ammeline by combined ozone/hydrogen peroxide treatment in water, Environ. Sci. Technol. 34(2000) 430-437.

[24] J.L. Acero, S.B. Haderlein, T.C. Schmidt, M.F.S. Jr, U.V. Gunten, MTBE oxidation by conventional ozonation and the combination ozone/hydrogen peroxide:efficiency of the processes and bromate formation, Environ. Sci. Technol. 35(2001) 4252-4251.

[25] O. Chedeville, M. Debacq, C. Porte, Removal of phenolic compounds present in olive mill wastewaters by ozonation, Desalination 249(2009) 865-875.

[26] W. Zhao, F. Liu, Y. Yang, M. Tan, D. Zhao, Ozonation of cationic red X-GRL in aqueous solution:degradation, kinetics and modeling, Chem. Eng. J. 171(2011) 528-539.

[27] Q. Dai, L. Chen, W. Chen, J. Chen, Degradation and kinetics of phenoxyacetic acid in aqueous solution by ozonation, Sep. Purif. Technol. 142(2015) 287-297.

[28] J. Staehelin, J. Hoigne, Decomposition of ozone in water:rate of initiation by hydroxide ion and hydrogen peroxide, Environ. Sci. Technol. 16(1982) 676-681.

[29] J. Hoigne, H. Bader, Rate constants of reactions of ozone with organic and inorganic compounds in water. I. Non-dissociating organic compounds, Water Res. 17(1983) 173-183.

[30] Y. Li, B. Sun, Z. Zeng, Y. Song, J.M. Chen, G.W. Chu, J.F. Chen, L. Shao, A study on the absorption of ammonia into water in a rotor-stator reactor, Can. J. Chem. Eng. 93(2015) 116-120.

[31] C.C. Lin, C.Y. Chao, M.Y. Liu, Removal of ozone from air by absorption in a rotating packed bed, Ind. Eng. Chem. 16(2010) 140-146.

[32] B.G. Kwon, D.S. Lee, N. Kang, J. Yoon, Characteristics of p-chlorophenol oxidation by Fenton's reagent, Water Res. 33(1999) 2110-2118.

Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

Ozonation of o-phenylenediamine in the presence of hydrogen peroxide by high-gravity technology

PDF (PC)

可视化

摘要/Abstract

引用本文

使用本文

参考文献

相关文章 15

编辑推荐

Metrics

本文评价

[1]	Chuang Liang, Zhihao Liu, Baochang Sun, Haikui Zou, Guangwen Chu. Improvement in discharge characteristics and energy yield of ozone generation via configuration optimization of a coaxial dielectric barrier discharge reactor[J]. 中国化学工程学报, 2023, 60(8): 61-68.
[2]	Xia Miao, Xiaofan Pang, Shiyu Li, Haoguang Wei, Jianhao Yin, Xiangming Kong. Mechanical strength and the degradation mechanism of metakaolin based geopolymer mixed with ordinary Portland cement and cured at high temperature and high relative humidity[J]. 中国化学工程学报, 2023, 60(8): 118-130.
[3]	Xiaolin Pan, Mengyuan Gao, Yun Wang, Yanping He, Tian Si, Yanlin Sun. Poly(lactic acid)-aspirin microspheres prepared via the traditional and improved solvent evaporation methods and its application performances[J]. 中国化学工程学报, 2023, 60(8): 194-204.
[4]	Xun Tao, Fan Zhou, Xinlei Yu, Songling Guo, Yunfei Gao, Lu Ding, Guangsuo Yu, Zhenghua Dai, Fuchen Wang. Effect of carbon dioxide on oxy-fuel combustion of hydrogen sulfide: An experimental and kinetic modeling[J]. 中国化学工程学报, 2023, 59(7): 105-117.
[5]	Minjie Shi, Nianting Chen, Yue Zhao, Cheng Yang, Chao Yan. Facile wet-chemical fabrication of bi-functional coordination polymer nanosheets for high-performance energy storage and anti-corrosion engineering[J]. 中国化学工程学报, 2023, 59(7): 118-127.
[6]	Zijie Zhang, Qianyu Zha, Ying Liu, Zhibing Zhang, Jia Liu, Zheng Zhou. Study on the epoxidation of olefins with H₂O₂ catalyzed by biquaternary ammonium phosphotungstic acid[J]. 中国化学工程学报, 2023, 58(6): 146-154.
[7]	Yanli Zhang, Zhengkun Hou, Dong Yao, Xiaomin Qiu, Hongru Zhang, Peizhe Cui, Yinglong Wang, Jun Gao, Zhaoyou Zhu, Limei Zhong. Energy, exergy, economic and environmental comprehensive analysis and multi-objective optimization of a sustainable zero liquid discharge integrated process for fixed-bed coal gasification wastewater[J]. 中国化学工程学报, 2023, 58(6): 341-354.
[8]	Linlin Su, Meijun Chen, Li Gong, Hua Yang, Chao Chen, Jun Wu, Ling Luo, Gang Yang, Lulu Long. Boost activation of peroxymonosulfate by iron doped K_2-xMn₈O₁₆: Mechanism and properties[J]. 中国化学工程学报, 2023, 57(5): 88-97.
[9]	Chenyang Zhao, Yinhan Cheng, Guangfei Qu, Yongheng Yuan, Fenghui Wu, Ye Liu, Shan Liu, Junyan Li, Ping Ning. High-performance liquid-phase catalytic purification of phosphine in tail gas using Pd(II)/Cu(II) composite[J]. 中国化学工程学报, 2023, 57(5): 98-108.
[10]	Hu Chen, Ying Wang, Puyu Wang, Yongkang Lv. Assessing quinoline removal performances of an aerobic continuous moving bed biofilm reactor (MBBR) bioaugmented with Pseudomonas citronellolis LV1[J]. 中国化学工程学报, 2023, 57(5): 132-140.
[11]	Yaqiao Liu, Shuozhen Hu, Xinsheng Zhang, Shigang Sun. Investigation of photoelectrocatalytic degradation mechanism of methylene blue by α-Fe₂O₃ nanorods array[J]. 中国化学工程学报, 2023, 57(5): 162-172.
[12]	Xinyu Yang, Zezhi Chen, Huijuan Gong. Coking of Pt/γ-Al₂O₃ catalyst in landfill gas deoxygen and its effects on catalytic performance[J]. 中国化学工程学报, 2023, 57(5): 224-232.
[13]	Jixiang Liu, Xin Zhou, Gengfei Yang, Hui Zhao, Zhibo Zhang, Xiang Feng, Hao Yan, Yibin Liu, Xiaobo Chen, Chaohe Yang. Conceptual carbon-reduction process design and quantitative sustainable assessment for concentrating high purity ethylene from wasted refinery gas[J]. 中国化学工程学报, 2023, 57(5): 290-308.
[14]	Bingxiao Feng, Lining Hao, Chaoting Deng, Jiaqiang Wang, Hongbing Song, Meng Xiao, Tingting Huang, Quanhong Zhu, Hengjun Gai. A highly hydrothermal stable copper-based catalyst for catalytic wet air oxidation of m-cresol in coal chemical wastewater[J]. 中国化学工程学报, 2023, 57(5): 338-348.
[15]	Shengfeng Luo, Song Zhang, Yiping Zeng, Hui Zhang, Lili Zheng, Zhaopeng Xu. Study on oxygen transport and titanium oxidation in coating cracks under parallel gas flow based on LBM modelling[J]. 中国化学工程学报, 2023, 56(4): 15-24.