Novel cobalt-free tantalum-doped perovskite BaFe1-yTayO3-δ with high oxygen permeation

doi:10.1016/j.cjche.2015.11.003

Abstract

Abstract: Cobalt-free perovskite-type oxides BaFe_1-yTa_yO_3-δ(0≤y≤0.2) were synthesized via a simple solid state reaction. The cubic perovskite structure can be obtained when y is over 0.1.BaFe_0.9Ta_0.1O_3-δ(BFT0.1) membrane shows the highest oxygen permeation flux, which can reach 1.6 ml·min^-1·cm^-2 at 950℃ under the gradient of air/He.The O₂-TPD results reveal that BaFe_0.9Ta_0.1O_3-δ material shows an excellent reversibility and phase structure stability in air.The oxygen permeation flux is limited by the bulk diffusion when the membrane thickness is over 0.8 mm, and it is limited by both the bulk diffusion and the surface exchange when the membrane thickness is below 0.5 mm.Stable oxygen permeation fluxes are obtained during 180 h operation.

Key words: Cobalt-free, Perovskite-type, BaFe_1?yTa_yO_3-&delta, , Oxygen permeation, Stable

Qing Liao, Yanjie Wang, Yan Chen, Haihui Wang. Novel cobalt-free tantalum-doped perovskite BaFe_1-yTa_yO_3-δ with high oxygen permeation[J]. Chin.J.Chem.Eng., 2016, 24(3): 339-344.

Qing Liao, Yanjie Wang, Yan Chen, Haihui Wang. [J]. Chinese Journal of Chemical Engineering, 2016, 24(3): 339-344.

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Novel cobalt-free tantalum-doped perovskite BaFe_1-yTa_yO_3-δ with high oxygen permeation

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