SCI和EI收录∣中国化工学会会刊

Chinese Journal of Chemical Engineering ›› 2013, Vol. 21 ›› Issue (11): 1269-1283.DOI: 10.1016/S1004-9541(13)60624-2

• 催化、动力学与反应工程 • 上一篇    下一篇

Chemical Effects of CO2 Concentration on Soot Formation in Jet-stirred/Plug-flow Reactor

张引弟1,2, 娄春2, 刘德华1, 李勇3, 阮龙飞1   

  1. 1 Yangtze University Research for China National Petroleum Corporation Key Laboratory of Oil Gas Production, Yangtze University, Wuhan 430100, China;
    2 State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China;
    3 Gas Lift Technology Center of Tuha Oilfield of China National Petroleum Corporation, Hami 838202, China
  • 收稿日期:2012-10-28 修回日期:2013-05-08 出版日期:2013-11-28 发布日期:2013-11-26
  • 通讯作者: ZHANG Yindi
  • 基金资助:

    Supported by the Foundation of State Key Laboratory of Coal Combustion, the National Natural Science Foundation of China (51306022, 51176059) and the Natural Science Foundation of Hubei Province (2013CFB398).

Chemical Effects of CO2 Concentration on Soot Formation in Jet-stirred/Plug-flow Reactor

ZHANG Yindi1,2, LOU Chun2, LIU Dehua1, LI Yong3, RUAN Longfei1   

  1. 1 Yangtze University Research for China National Petroleum Corporation Key Laboratory of Oil Gas Production, Yangtze University, Wuhan 430100, China;
    2 State Key Laboratory of Coal Combustion, Huazhong University of Science and Technology, Wuhan 430074, China;
    3 Gas Lift Technology Center of Tuha Oilfield of China National Petroleum Corporation, Hami 838202, China
  • Received:2012-10-28 Revised:2013-05-08 Online:2013-11-28 Published:2013-11-26
  • Contact: ZHANG Yindi
  • Supported by:

    Supported by the Foundation of State Key Laboratory of Coal Combustion, the National Natural Science Foundation of China (51306022, 51176059) and the Natural Science Foundation of Hubei Province (2013CFB398).

摘要: Soot formation was investigated numerically with CO2 addition in a jet-stirred/plug-flow reactor (JSR/PFR) C2H4/O2/N2 reactor (C/O ratio of 2.2) at atmospheric pressure. An updated Kazakov mechanism emphasizes the effect of the O2/CO2 atmosphere instead of an O2/N2 one in the premixed flame. The soot formation was taken into account in the JSR/PFR for C2H4/O2/N2. The effects of CO2 addition on soot formation in different C2H4/O2/CO2/N2 atmospheres were studied, with special emphasis on the chemical effect. The simulation shows that the endothermic reaction CO2 + H1269CO + OH is responsible of the reduction of hydrocarbon intermediates in the CO2 added combustion through the supplementary formation of hydroxyl radicals. The competition of CO2 for H radical through the above forward reaction with the single most important chain branching reaction H + O21269O + OH reduces significantly the fuel burning rate. The chemical effects of CO2 cause a significant increase in residence time and mole fractions of CO and OH, significant decreases in some intermediates (H, C2H2), polycyclic aromatic hydrocarbons (PAHs, C6H6 and C16H10, etc.) and soot volume fraction. The CO2 addition will leads to a decrease by only about 5% to 20% of the maximum mole fractions of some C3 to C10 hydrocarbon intermediates. The sensitivity analysis and reaction-path analysis results show that C2H4 reaction path and products are altered due to the CO2 addition.

关键词: fuel enrichment, carbon dioxide, kinetics modeling, soot formation, jet-stirred/plug-flow reactor

Abstract: Soot formation was investigated numerically with CO2 addition in a jet-stirred/plug-flow reactor (JSR/PFR) C2H4/O2/N2 reactor (C/O ratio of 2.2) at atmospheric pressure. An updated Kazakov mechanism emphasizes the effect of the O2/CO2 atmosphere instead of an O2/N2 one in the premixed flame. The soot formation was taken into account in the JSR/PFR for C2H4/O2/N2. The effects of CO2 addition on soot formation in different C2H4/O2/CO2/N2 atmospheres were studied, with special emphasis on the chemical effect. The simulation shows that the endothermic reaction CO2 + H1269CO + OH is responsible of the reduction of hydrocarbon intermediates in the CO2 added combustion through the supplementary formation of hydroxyl radicals. The competition of CO2 for H radical through the above forward reaction with the single most important chain branching reaction H + O21269O + OH reduces significantly the fuel burning rate. The chemical effects of CO2 cause a significant increase in residence time and mole fractions of CO and OH, significant decreases in some intermediates (H, C2H2), polycyclic aromatic hydrocarbons (PAHs, C6H6 and C16H10, etc.) and soot volume fraction. The CO2 addition will leads to a decrease by only about 5% to 20% of the maximum mole fractions of some C3 to C10 hydrocarbon intermediates. The sensitivity analysis and reaction-path analysis results show that C2H4 reaction path and products are altered due to the CO2 addition.

Key words: fuel enrichment, carbon dioxide, kinetics modeling, soot formation, jet-stirred/plug-flow reactor